Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (04): 93-100.doi: 10.13475/j.fzxb.20200400208

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and properties of succinic anhydride acylated gelatin sizing agent for wool yarn sizing

YANG Wenjing1, WU Hailiang1(), MA Jianhua2,3, YAO Yijun1, SHEN Yanqin1   

  1. 1. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    2. School of Materials Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    3. Shaoxing Keqiao West-Tex Textile Industry Innovative Institute, Shaoxing, Zhejiang 312030, China
  • Received:2020-04-01 Revised:2021-01-05 Online:2021-04-15 Published:2021-04-20
  • Contact: WU Hailiang E-mail:whl@xpu.edu.cn

RichHTML

4

PDF (PC)

70

Abstract:

To address the problems of gelatin gelling at room temperature and poor toughness of size film when gelatin is used to sizing wool yarns, the modified gelatin protein (Gel-C4H4O3) for sizing at room temperature was prepared by acylation of gelatin with succinic anhydride (C4H4O3). The structure and glass transition temperature of Gel-C4H4O3 sizing agent were tested and characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscope and differential scanning calorimeter. The relationship between the acylation degree and the size liquid and membrane properties of Gel-C4H4O3 was systematically studied. The results show that C4H4O3 can react with the amino groups on the gelatin molecular chain. Compared with the existing acrylic, acrylamide or acrylate monomers-grafted gelatin, Gel-C4H4O3 exhibited no gel at room temperature. When the acylation degree is 0.96, Gel-C4H4O3 size liquid showed excellent adhesion to wool yarn and the fracture strength and toughness of Gel-C4H4O3 size membrane are significantly increased. It provides an excellent sizing agent preparation method for wool yarn sizing at room temperature.

Key words: modified gelatin protein sizing agent, wool yarn sizing, acylation degree, size liquid property, size membrane property, succinic anhydride

CLC Number: 

  • TS103.846

Fig.1

Modification mechanism of Gel-C4H4O3 sizing agent"

Fig.2

Infrared spectroscopy of gelatin and Gel-C4H4O3 sizing agent"

Tab.1

Amino acid composition and content of gelatin and Gel-C4H4O3 sizing agent%"

氨基酸种类 氨基酸含量
明胶 Gel-C4H4O3浆料
天冬氨酸(Asp) 6.716 8.121
苏氨酸(Thr) 2.465 2.441
丝氨酸(Ser) 5.465 6.989
谷氨酸(Glu) 15.746 15.311
脯氨酸(Pro) 4.136 4.166
甘氨酸(Gly) 6.046 6.465
丙氨酸(Ala) 4.565 5.798
胱氨酸(Cys) 2.065 2.465
缬氨酸(Val) 6.444 6.426
甲硫氨酸(Met) 2.798 2.793
异亮氨酸(Ile) 3.313 3.465
亮氨酸(Leu) 5.265 7.465
酪氨酸(Tyr) 4.999 5.444
苯丙氨酸(Phe) 6.124 6.989
赖氨酸(Lys) 2.999 1.835
组氨酸(His) 2.466 2.311
精氨酸(Arg) 7.456 6.591

Fig.3

Effect of mass ratio of C4H4O3 and gelatin on acylation degree"

Fig.4

Rheological properties of gelatin and Gel-C4H4O3 size liquid with different acylation degrees. (a)Gelatin;(b) Acylation degree is 0.43; (c) Acylation degree is 0.81;(d) Acylation degree is 0.91; (e) Acylation degree is 0.93;(f) Acylation degree is 0.96"

Tab.2

Molecular weight of Gel-C4H4O3 size liquid with different acylation degrees"

酰化度 重均分子量 酰化度 重均分子量
0.43 92 934 0.93 105 436
0.81 93 652 0.96 116 253
0.91 95 943

Fig.5

Viscosity and temperature curves of gelatin and Gel-C4H4O3 size liquid with different acylation degrees"

Fig.6

Effect of acylation degree on adhesion of Gel-C4H4O3 size liquid"

Fig.7

Mechanical properties of gelatin and Gel-C4H4O3 size membrane with different acylation degrees"

Fig.8

DSC spectra of gelatin and Gel-C4H4O3 sizing agent"

Fig.9

X-ray diffraction spectra of gelatin and Gel-C4H4O3 sizing agent"

Fig.10

Cross section morphology of gelatin and Gel-C4H4O3 size membrane with different acylation degree (×5 000). (a) Gelatin; (b)Acylation degree is 0.43; (c) Acylation degree is 0.81; (d)Acylation degree is 0.91; (e)Acylation degree is 0.93; (f) Acylation degree is 0.96"

Fig.11

Contact angle and water soluble time of gelatin and Gel-C4H4O3 size membrane with different acylation degrees"

[1] 王婧, 王雪燕, 韩惠民. 一种明胶蛋白类毛用浆料的合成[J]. 毛纺科技, 2016,44(2):56-61.
WANG Jing, WANG Xueyan, HAN Huimin. Synjournal of gelatin protein for wool yarn[J]. Wool Textile Journal, 2016,44(2):56-61.
[2] LI M, JIN E, ZHANG L. Effects of graft modification on the water solubility apparent viscosity, and adhesion of feather keratin for warp sizing[J]. Journal of The Textile Institute, 2015,107(3):1-10.
doi: 10.1080/00405000.2014.999478
[3] YANG M, XU H, HOU X L, et al. Biodegradable sizing agents from soy protein via controlled hydrolysis and dis-entanglement for remediation of textile effluents[J]. Journal of Environmental Management, 2017,188:26-31.
doi: 10.1016/j.jenvman.2016.11.066 pmid: 27918924
[4] 李曼丽, 金恩琪, 连瑶瑶. 羽毛蛋白接枝共聚物对涤/棉经纱的上浆性能[J]. 纺织学报, 2017,38(5):75-79,85.
LI Manli, JIN Enqi, LIAN Yaoyao. Sizing properties of feather keratin-graft poly(acrylic acid-co-methyl arylate) for polyester/cotton warp yarns[J]. Journal of Textile Research, 2017,38(5):75-79,85.
[5] 刘玉森, 陈莉, 王绍斌. 明胶与丙烯酸、丙烯酸甲酯接枝浆料的制备[J]. 上海纺织科技, 2006,49(6):12-14,18.
LIU Yusen, CHEN Li, WANG Shaobin. Preparation of gelatin size grafted with methacrylate and acrylic acid[J]. Shanghai Textile Science & Technology, 2006,49(6):12-14,18.
[6] SHAD P, KARIZ S, JAVAN R, et al. Folate conjugated hyaluronic acid coated alginate nanogels encapsulated oxaliplatin enhance antitumor and apoptosis efficacy on colorectal cancer cells (HT29 cell line)[J]. Toxicology in Vitro, 2020,65:104756.
doi: 10.1016/j.tiv.2019.104756 pmid: 31884114
[7] ALIJANI H Q, SHAHRAM P. Bimetallic nickel-ferrite nanorod particles: greener synjournal using rosemary and its biomedical efficiency[J]. Artificial Cells Nanomedicine and Biotechnology, 2020,48(1):242-251.
[8] FARAG M M S, MOGHANNEM S A M, SHEHABELDINE A M, et al. Antitumor effect of exopolysaccharide produced by bacillus mycoides[J]. Microbial Pathogenesis, 2020,140:103947.
doi: 10.1016/j.micpath.2019.103947 pmid: 31874230
[9] TANG R, SUN D X, XIONG J, et al. Feasibility of synthesizing γ-[Glu](n≥1)-Gln using high solid concentrations and glutaminase from bacillus amyloliquefaciens as the catalyst[J]. Food Chemistry, 2020,310:125920.
doi: 10.1016/j.foodchem.2019.125920 pmid: 31841937
[10] YAO Q, LIN M T, LAN Q H, et al. In vitro and in vivo evaluation of didymincyclodextrin inclusion complexes: characterization and chemosensitization activity[J]. Drug Delivery, 2020,27(1):54-65.
doi: 10.1080/10717544.2019.1704941 pmid: 31858849
[11] 李承明. 明胶的降解与酰化改性及其产物的应用研究[D]. 北京:北京化工大学, 2006: 20-21.
LI Chengming. Degradation and acylation modification of gelatin and the application of its products[D]. Beijing:Beijing University of Chemical Technology, 2006: 20-21.
[12] 曹新伟, 宋秦杰, 朱博, 等. 冷水可溶性马铃薯淀粉的低温上浆性能[J]. 纺织学报, 2018,39(3):79-85.
CAO Xinwei, SONG Qinjie, ZHU Bo, et al. Sizing property of cold water soluble potato starch at low temperature[J]. Journal of Textile Research, 2018,39(3):79-85.
[13] 张朝辉, 徐珍珍, 徐文正, 等. 季铵阳离子型接枝淀粉浆料的浆膜性能[J]. 纺织学报, 2018,39(11):68-72.
ZHANG Zhaohui, XU Zhenzhen, XU Wenzheng, et al. Film properties of starch sizing grafted by quaternary ammonium cations[J]. Journal of Textile Research, 2018,39(11):68-72.
[14] AO S S, KHATAEE A, SAFARPOUR M, et al. Modification of polyethersulfone ultrafiltration membrane using ultrasonic-assisted functionalized MoS2 for treatment of oil refinery wastewater[J]. Separation and Purification Technology, 2020,238:116495.
[15] 柯晴瑾, 王飞镝, 奚红霞, 等. EDTAD-PEG-dial-明胶复合改性凝胶的制备与性能研究[J]. 材料导报, 2010,24(4):41-44.
KE Qingjin, WANG Feidi, XI Hongxia, et al. Research on preparation and properties of EDTAD-PEG-dial-gelatin compound modified gel[J]. Materials Reports, 2010,24(4):41-44.
[16] 陈红霞, 曹海建, 黄晓梅. 剪切增稠液流变性能的影响因素研究[J]. 化工新型材料, 2019,47(11):137-140.
CHEN Hongxia, CAO Haijian, HUANG Xiaomei. Influence factor of rheological property on STF[J]. New Chemical Materials, 2019,47(11):137-140.
[17] 王苏, 王强, 徐进, 等. 辣根过氧化物酶催化淀粉接枝丙烯酸甲酯浆料制备及其上浆性能[J]. 纺织学报, 2017,38(6):69-74.
WANG Su, WANG Qiang, XU Jin, et al. Preparation and its sizing properties of starch-poly(methyl acrylate)size catalyzed by horseradish peroxidase[J]. Journal of Textile Research, 2017,38(6):69-74.
[18] 沈艳琴, 武海良, 熊锐, 等. 中低温水溶季铵阳离子淀粉浆料的合成及其浆纱性能[J]. 纺织学报, 2017,38(11):73-78.
SHEN Yanqin, WU Hailiang, XIONG Rui, et al. Synjournal and properties of water soluble quaternary ammonium cationic starch sizing materials[J]. Textile Research, 2017,38(11):73-78.
[19] 沈艳琴, 张琳, 刘欢, 等. 咖啡碳长丝喷水织造聚丙烯酸酯浆料的制备及性能[J]. 现代化工, 2019,39(2):162-166.
SHEN Yanqin, ZHANG Lin, LIU Huan, et al. Preparation and performance of polyacrylate size for water jet weaving of coffee carbon filaments[J]. Modern Chemical Industry, 2019,39(2):162-166.
[20] TRIVEDI M K, NAYAK G, PATIL S, et al. Evaluation of the impact of biofield treatment on physical and thermal properties of casein enzyme hydrolysate and casein yeast peptone[J]. Social Science Electronic Publishing, 2018,4(12):1000138-1000144.
[21] 严霞波, 王飞镝, 奚红霞, 等. EDTAD酰化改性对明胶蛋白凝胶性能的影响[J]. 材料导报, 2009,23(6):25-28,31.
YAN Xiabo, WANG Feidi, XI Hongxia, et al. Effect of acylation with EDTAD on properties of gelatin protein gels[J]. Materials Reports, 2009,23(6):25-28,31.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd