Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (12): 26-30.doi: 10.13475/j.fzxb.20200407406

• Fiber Materials • Previous Articles     Next Articles

Effect of atomic layer deposition technology on functionalization of cellulose membrane

LI Junyu1, JIANG Peiqing2, ZHANG Wenqi3, LI Wenbin1()   

  1. 1. State Key Laboratory of Textile New Materials and Advanced Processing Technology in Hubei Province, Wuhan Textile University, Wuhan, Hubei 430200, China
    2. Glorious Sun Guangdong School of Fashion, Huizhou University, Huizhou, Guangdong 516007, China
    3. Hubei Sanjiang Boats Science & Technology Co., Ltd., Xiaogan, Hubei 432000, China
  • Received:2020-04-28 Revised:2020-09-16 Online:2020-12-15 Published:2020-12-23
  • Contact: LI Wenbin E-mail:li780713@hotmail.com

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Abstract:

In order to expand the use of cellulose membranes into medical, construction and other fields, with the characteristics of ultraviolet shielding, antibacterial of nano-zinc oxide, atomic layer depos-ition technology (ALD) were used to deposit nano-zinc oxide on the surface of cellulose membrane. The cellulose membrane was prepared to offer UV-blocking and antibacterial functions, and the effects of different temperatures and cycle numbers on the membrane properties were discussed. The structure and performance of the cellulose membranes treated with ALD were analyzed using ultraviolet spectrophotometer, scanning electron microscopy, X-ray diffraction, thermogravimetric analysis and other analytical tools. The results show that as the temperature and the number of cycles increase, the UV transmittance of the cellulose membrane treated with ALD is reduced from 74.50% to 1.46%, and the antibacterial rate of ALD functionalized cellulose membrane against Staphylococcus aureus reaches 99.9%. In addition, on the surface of the treated cellulose membrane with nano-zinc oxide with hexagonal wurtzite structure, the residual carbon rate increases from 16.61% to 31.20%.

Key words: cellulose membrane, atomic layer deposition technology, nano-zinc oxide, UV-blocking, antibacterial property

CLC Number: 

  • TS101

Tab.1

Temperatures and cycle numbers setting of experiment"

样品
编号		 温度/
℃		 循环
次数		 样品
编号		 温度/
℃		 循环
次数
A0 25 0 A18 110 40
A1 60 10 A19 110 50
A2 60 20 A20 110 100
A3 60 30 A21 110 200
A4 60 40 A22 130 10
A5 60 50 A23 130 20
A6 60 100 A24 130 30
A7 60 200 A25 130 40
A8 90 10 A26 130 50
A9 90 20 A27 130 100
A10 90 30 A28 130 200
A11 90 40 A29 160 10
A12 90 50 A30 160 20
A13 90 100 A31 160 30
A14 90 200 A32 160 40
A15 110 10 A33 160 50
A16 110 20 A34 160 100
A17 110 30 A35 160 200

Fig.1

UV transmittance of cellulose membranes treated with different cycles (a) and temperatures (b)"

Fig.2

Antibacterial images of cellulose membranes treated with different cycles and temperatures"

Tab.2

Antibacterial rate to Staphylococcus aureus of cellulose membranes treated with different temperatures and cycle"

样品
编号		 温度/
℃		 循环
次数		 稀释
倍数		 菌落
数		 抑菌
率/%
A0 25 0 1 000 401 —
A1 60 10 100 161 96.0
A15 110 10 100 134 96.7
A5 60 50 10 12 99.9
A19 110 50 10 19 99.9

Fig.3

SEM images of cellulose membranes treated with different cycles and temperatures"

Fig.4

XRD spectra of cellulose membranes"

Fig.5

Thermal stability curves of cellulose membranes treated with different temperatures and cycles"

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