Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (05): 115-121.doi: 10.13475/j.fzxb.20200505207

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and properties of cotton fabric modified by silver nanowires

ZHAO Yongfang, QIAN Jianhua(), SUN Liying, PENG Huimin, MEI Min   

  1. College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2020-05-26 Revised:2021-02-01 Online:2021-05-15 Published:2021-05-20
  • Contact: QIAN Jianhua E-mail:qianjianhua@zstu.edu.cn

RichHTML

21

PDF (PC)

227

Abstract:

In order to increase the added value of cotton fabrics and improve its adsorption to modifying components, sodium periodate was used for oxidation treatment to increase the adhesion of cotton fiber. Silver nanowires (AgNWs) were then prepared by one-step polyol reduction method at 160 ℃ and dispersed in anhydrous ethanol. With a cotton fabric as the substrate, AgNWs was finished on the surface of the fabric by the impregnation drying method. The finished cotton fabric was characterized, and its UV resistance, conductivity and washing resistance were tested. The results show that with the increase of AgNWs concentration, the electrical conductivity of the fabric increases by more than 80%. When the AgNWs concentration is 10 g/L, the UV protection factor (UPF) value reaches 55, and the UV transmittance is reduced to less than 2.5%. The washing resistance of the modified cotton fabric is improved by 20% after the oxidation treatment, and the UPF value of the modified fabric after three times of washing reaches 46.51. The flexible conductive cotton fabric can be applied to flexible electronic textiles and anti ultraviolet products.

Key words: silver nanowire, cotton fabric, oxidation treatment, UV resistance, conductivity, flexible conductive fabric

CLC Number: 

  • TS156

Fig.1

Color changes of solution during preparation of AgNWs"

Fig.2

SEM images of AgNWs"

Fig.3

Distribution of length (a) and diameter (b) of AgNWs"

Fig.4

XRD pattern of AgNWs"

Tab.1

Evaluation standards of UV resistance of samples"

UPF值范围 防护效果 紫外线透过率/% UPF等级
15~24 良好 6.7~4.2 15,20
25~39 很好 4.1~2.6 25,30,35
40~50,50 极佳 ≤2.5 40,45,50,50+

Fig.5

Relationship between AgNWs mass concentration and UPF"

Fig.6

Relationship between AgNWs mass concentration and UVA transmittance (a) or UVB transmittance(b)"

Tab.2

Sheet resistance of modified cotton fabric treated with different mass concentration of silver nanowires"

AgNWs质量浓度/
(g·L-1)		 方块电阻/
(Ω·□-1)		 AgNWs质量浓度/
(g·L-1)		 方块电阻/
(Ω·□-1)
10 87 30 60
20 75 40 15

Fig.7

SEM images of cotton fabric before(a) and after (b)oxidation treatment (×1 000)"

Fig.8

SEM image of AgNWs attached to cotton fabric(×1 000)"

Fig.9

Sheet resistance of fabric obtained by oxidation treatment at different times"

Fig.10

Breaking strength of cotton fabric with different oxidation treatment time"

Tab.3

UV resistance of cotton samples after washing for 3 times"

氧化处理时间/min UPF值 透过率平均值/%
UVA UVB
0 30.46 2.01 1.61
15 42.17 0.97 0.62
30 45.42 0.93 0.60
45 46.51 0.89 0.51

Fig.11

Effect of oxidation treatment time on washing weight loss of modified cotton fabric"

[1] NOUREDDINE A, LUIS C, ERIC H. Functionalization of a cotton fabric surface with titania nanosols: applications for self-cleaning and UV-protection properties[J]. ACS Applied Materials & Interfaces, 2009,1(10):2141-2146.
[2] 周扬州, 钱磊, 章婷. 银纳米线及其透明导电膜的研究进展[J]. 材料导报, 2020,34(21):21081-21092.
ZHOU Yangzhou, QIAN Lei, ZHANG Ting. Researchprogress of silver nanowires and transparent conductive films[J]. Materials Reports, 2020,34(21):21081-21092.
[3] FERRARO G, FRATINI E. A simple synthetic approach to prepare silver elongated nanostructures: from nanorods tonanowires[J]. Journal of Chemical Education, 2019,96(3):553-557.
doi: 10.1021/acs.jchemed.8b00628
[4] JIA L C, ZHANG G, XU L, et al. Robustly superhydrophobic conductive textile for efficient electromagnetic interference shielding[J]. ACS Applied Materials and Interfaces, 2019,11(1):1680-1688.
doi: 10.1021/acsami.8b18459
[5] 吴荣辉, 马丽芸, 张一帆, 等. 银纳米线涂层的编链结构纱线拉伸应变传感器[J]. 纺织学报, 2019,40(12):45-49,62.
WU Ronghui, MA Liyun, ZHANG Yifan, et al. Yarn tensile strain sensor with silver nanowire coating[J]. Journal of Textile Research, 2019,40(12):45-49, 62.
[6] 许红梅, 于肖. 高产率合成银纳米线及提升太阳电池银浆性能[J]. 中山大学学报(自然科学版), 2018,57(4):115-120.
XU Hongmei, YU Xiao. High yield synjournal of silver nanowires and improvement of silver paste performance of solar cells[J]. Journal of Sun Yat-Sen Universi-ty (Natural Science Edition), 2018,57(4):115-120.
[7] 卢健, 危韦, 杨光, 等. 银纳米线薄膜的制备及电磁屏蔽性能研究[J]. 化工新型材料, 2019,47(9):104-108,113.
LU Jian, WEI Wei, YANG Guang, et al. Preparation and electromagnetic shielding properties of silver nanowire films[J]. New Chemical Materials, 2019,47(9):104-108,113.
[8] 王博, 凡力华, 原韵, 等. 可拉伸聚吡咯/棉针织物的制备及其储电性能[J]. 纺织学报, 2020,41(10):101-106.
WANG Bo, FAN Lihua, YUAN Yun, et al. Preparation and electrical storage properties of stretchable polypyrrole/cotton knitted fabric[J]. Journal of Textile Research, 2020,41(10):101-106.
[9] 李婷, 焦晨璐, 张伟伟, 等. 改性TiO2纳米线对棉织物的抗紫外及自清洁整理[J]. 纺织导报, 2016(3):51-54.
LI Ting, JIAO Chenlu, ZHANG Weiwei, et al. UV resistance and self-cleaning finishing of cotton fabric with modified TiO2 nanowires[J]. China Textile Leader, 2016 (3):51-54.
[10] LU Y, JIANG J, PARK S, et al. Wet-spinning fabrication of flexible conductive composite fibers from silver nanowires and fibroin[J]. Bulletin of the Korean Chemical Society, 2020,41(2):162-169.
doi: 10.1002/bkcs.v41.2
[11] 朱金铭, 钱建华, 孙丽颖, 等. 用高长径比银纳米线制备功能性复合涤纶织物及其性能[J]. 纺织学报, 2019,40(11):113-118.
ZHU Jinming, QIAN Jianhua, SUN Liying, et al. Preparation and properties of functional composite polyester fabric with high aspect ratio silver nanowires[J]. Journal of Textile Research, 2019,40(11):113-118.
[12] 于湖生. 纳米抗紫外整理对棉织物服用性能的影响[J]. 纺织学报, 2003,24(4):54-55.
YU Husheng. The effect of nano UV resistant finishing on the wearability of cotton fabric[J]. Journal of Textile, 2003,24(4):54-55,3.
[13] 彭军, 李津, 李伟, 等. 银纳米线研究进展与应用[J]. 现代化工, 2019,39(4):31-35.
PENG Jun, LI Jin, LI Wei, et al. Research progress and application of silver nanowires[J]. Modern Chemical Industry, 2019,39(4):31-35.
[14] LIAO X, LI H, LAI X, et al. Facile fabrication of superhydrophobic conductive nanowires cotton fabric via dipping-thermal curing method[J]. Materials Letters, 2019,255(15):126511.1-126511. 4.
[15] PATRYCJA G, EWELINA M, ALICJA N, et al. Investigation on functionalization of cotton and viscose fabrics with AgNWs[J]. Cellulose, 2017,24(1):409-422.
doi: 10.1007/s10570-016-1107-7
[16] GIESZ P, MACKIEWICZ E, GROBELNY J, et al. Mu.pngunctional hybrid functionalization of cellulose fabrics with AgNWs and TiO2[J]. Carbohydrate Polymers, 2017,177:397-405.
doi: 10.1016/j.carbpol.2017.08.087
[17] MOHAMMAD R N, MOHAMMAD S K. Silver nanowire-functionalized cotton fabric[J]. Carbohydrate Polymers, 2015,117(1):160-168.
doi: 10.1016/j.carbpol.2014.09.057
[18] ZHANG Y, TIAN W, LIU L, et al. Eco-friendly flame retardant and electromagnetic interference shielding cotton fabrics with multi-layered coatings[J]. Chemical Engineering Journal, 2019,372:1077-1090.
doi: 10.1016/j.cej.2019.05.012
[19] CHEN Z, YU W, DY Z. Study of electrothermal properties of silver nanowire/polydopamine/cotton-based nanoco-mposities[J]. Cellulose, 2019,26(10):5995-6007.
doi: 10.1007/s10570-019-02506-w
[20] DAVID R W, AARON R C, PHILIPPE B, et al. New perspectives on silver nanowire formation from dynamic silver ion mass concentration monitoring and nitric oxide productionin the polyol process[J]. Crystal Growth & Design, 2016,16(4):1861-1868.
doi: 10.1021/acs.cgd.5b01289
[1] LIU Xiaoqian, CHEN Yu, ZHOU Huimin, YAN Yuan, XIA Xin. Preparation of polyacrylonitrile conductive nanofiber yarn grafted with acrylic acid using plasma technology [J]. Journal of Textile Research, 2021, 42(05): 109-114.
[2] MA Ya'nan, SHEN Junyan, LUO Xiaolei, ZHANG Cong, SHANG Xiaolei, LIU Lin, KRUCINSKA Izabella, YAO Juming. Preparation and properties of high efficiency halogen-free flame-retardant cotton fabrics [J]. Journal of Textile Research, 2021, 42(03): 122-129.
[3] WU Shouying, ZHANG Linping, XU Hong, ZHONG Yi, MAO Zhiping. Research progress of low-temperature bleaching of cotton fabrics catalyzed by metal complexes [J]. Journal of Textile Research, 2021, 42(03): 27-35.
[4] HAO Shang, XIE Yuan, WENG Jiali, ZHANG Wei, YAO Jiming. Construction of superhydrophobic surface of cotton fabrics via dissolving etching [J]. Journal of Textile Research, 2021, 42(02): 168-173.
[5] CAI Lu, KANG Jialiang, LÜ Cun, HE Xuemei. Preparation of self-crosslinking fluorinated polyacrylate emulsion and its application properties [J]. Journal of Textile Research, 2021, 42(02): 161-167.
[6] HOU Wenshuang, MIN Jie, JI Feng, ZHANG Jianxiang, SU Meng, HE Ruixian. Influence of fabric tightness and anti-crease finishing on wrinkle recovery of pure cotton woven fabrics [J]. Journal of Textile Research, 2021, 42(01): 118-124.
[7] YU Jia, XIN Binjie, ZHUO Tingting, ZHOU Xi. Preparation and characterization of Cu/polypyrrole-coated wool fabrics for high electrical conductivity [J]. Journal of Textile Research, 2021, 42(01): 112-117.
[8] ZENG Fanxin, QIN Zongyi, SHEN Yueying, CHEN Yuanyu, HU Shuo. Preparation and flame retardant properties of self-extinguishing cotton fabrics by spray-assisted layer-by-layer self-assembly technology [J]. Journal of Textile Research, 2021, 42(01): 103-111.
[9] WANG Liyuan, KANG Weimin, ZHUANG Xupin, JU Jingge, CHENG Bowen. Preparation and properties of composite proton exchange membranes based on sulfonated polyethersulfone nanofibers [J]. Journal of Textile Research, 2020, 41(11): 19-26.
[10] ZHANG Yanyan, ZHAN Luyao, WANG Pei, GENG Junzhao, FU Feiya, LIU Xiangdong. Research progress in preparation of durable antibacterial cotton fabrics with inorganic nanoparticles [J]. Journal of Textile Research, 2020, 41(11): 174-180.
[11] WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia. Preparation and electric storage performance of stretchable polypyrrole/cotton knitted fabric [J]. Journal of Textile Research, 2020, 41(10): 101-106.
[12] PANG Yali, MENG Jiayi, LI Xin, ZHANG Qun, CHEN Yankun. Preparation of graphene fibers by wet spinning and fiber characterization [J]. Journal of Textile Research, 2020, 41(09): 1-7.
[13] LIU Guojin, SHI Feng, CHEN Xinxiang, ZHANG Guoqing, ZHOU Lan. Preparation of polyurethane/phase change wax functional finishing agents for heat storage and temperature regulation and their applications on cotton fabrics [J]. Journal of Textile Research, 2020, 41(07): 129-134.
[14] CHENG Shijie, WANG Chenyang, ZHANG Hongwei, ZUO Danying. Effect of boron nitrogen doped carbon dots on ultraviolet-protection of cotton fabrics [J]. Journal of Textile Research, 2020, 41(06): 93-98.
[15] ZHOU Qingqing, CHEN Jiayi, QI Zhenming, CHEN Weijian, SHAO Jianzhong. Preparation and characterization of flame retardant and antibacterial cotton fabric [J]. Journal of Textile Research, 2020, 41(05): 112-120.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd