热塑性聚合物阻燃抗熔滴研究现状

doi:10.13475/j.fzxb.20200601909

Abstract

Abstract:

Targetting at the droplet phenomenon of flame retardant polymers and fabrics when burning to achieve high-quality flame-retardant thermoplastic polymers and expand the application range of flame retardant fibers and products, this article reviewed the current research advances and latest findings in the flame retardant and anti-dripping behavior of thermoplastic polymers, and described the commonly used current methods for flame retardant and anti-dripping modification. The common methods of flame retardant and anti-dripping modification including copolymerization, blending and construction of flame retardant and droplet resistant coatings on the fabric surface were described. The main mechanisms of flame-retardant and anti-dripping are analyzed, i.e., increasing the viscosity of polymer melt and forming a dense and stable carbon layer. The flame retardant and anti-dripping applications of different thermoplastic polymer systems are summarized. It is pointed out that the design and synthesis of the multi-element compound anti-dripping system, and the optimization of the interaction mode between the anti-dripping system and the matrix material are the main development trends of flame retardant and anti-dripping.

Key words: thermoplastic polymer, flame retardant, anti-dripping, anti-dripping mechanism, anti-dripping application

CLC Number:

TQ372.4

SUN Chenying, WANG Wenqing, JIN Gaoling, WANG Rui. Research advances in thermoplastic polymers for flame retardant and anti-dripping behavior[J].Journal of Textile Research, 2021, 42(06): 171-179.

Figures/Tables 1

Tab.1

References 67

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类别	具体方法	实施路线
化学改性	共聚法	在聚合物反应过程中添加反应型抗熔滴单体,将其接入聚合物主链或侧链中
化学改性	纤维表面接枝	在聚合物织物的纤维表面接枝反应型抗熔滴剂
物理改性	共混法	将普通聚合物与单一/多元复配抗熔滴剂进行熔融或溶液混合
	复合纺丝	将具备阻燃抗熔滴功能聚合物与普通聚合物分别输入同一纺丝组件,汇合后挤出固化成纤
	织物表面整理	通过浸渍等方法在织物表面形成阻燃抗熔滴涂层

Research advances in thermoplastic polymers for flame retardant and anti-dripping behavior

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