Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (08): 194-201.doi: 10.13475/j.fzxb.20200707008

• Comprehensive Review • Previous Articles     Next Articles

Research progress in superfine dispersion of disperse dyes and its effect on particle-size

QIU Jingsi1, LIU Yue1,2()   

  1. 1. College of Textile and Garment, Shaoxing University, Shaoxing, Zhejiang 312000, China
    2. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing, Zhejiang 312000, China
  • Received:2020-07-27 Revised:2021-05-08 Online:2021-08-15 Published:2021-08-24
  • Contact: LIU Yue E-mail:liuyue846@163.com

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Abstract:

Large particle size and uneven particle-size distribution of dyes during the commercial processing of disperse dyes significantly affect the dyeing quality. To improve the dyeing performance of disperse dyes, based on the analysis of physical ultrafine pulverization technologies such as high-pressure homogenization and ultrasonic pulverization in the superfine and dispersion of disperse dyes, this article reviews and analyzes factors having important influences on the regulation of the particle-size and its distribution in the dye in detail. It includes pre-grinding, structure and crystal form of dyes, dispersant, grinding medium, slurry concentration, and other factors. It is pointed out that speeding up the popularization and application of new grinding technology, equipment configuration and the selection and optimization of grinding process technology are all conducive to the high-quality, uniform, and ultrafine preparation of disperse dyes. The differential processing of different types of disperse dyes is also an important research direction worthy of enterprises' attention.

Key words: disperse dye, superfine dispersion, particle-size, dispersant, grinding media, crystalline transformation

CLC Number: 

  • TS190.2

Tab.1

Preparation process of disperse dyes in powder and liquid form"

流程 技术要点
粉体染料 液体染料
原染料 含固率、纯度、杂质 含固率、纯度、杂质
打浆 预粉碎 预粉碎
砂磨 粒径及PDI、分散性、扩散性 粒径及PDI、盐浓度
过滤 — —
拼混、标准化 强度、悬浮液分散性 强度、Zeta电位、流变性、黏度
喷雾干燥 热稳定性 —
成品包装 粉尘飞扬性 贮存稳定性

Fig.1

Ultrafine grinding process"

Tab.2

Influencing factors and key points of disperse dyes superfine dispersion"

因素 要点
预粉碎(预分散) 提高研磨效率,粒径分布更均匀
染料种类(结构) 分子结构的刚性和共平面性大的染料有更好的研磨效果;相同条件下研磨细度:蒽醌类<偶氮类
染料晶型 同种染料晶型稳定、晶粒小时,细化粉碎难度小
分散剂 复合分散剂的研磨分散效果优于单一分散剂。分散剂用量要适当,过多时染料包围层加厚,过少时保护层不完全
研磨介质 介质的硬度和密度适当,过密易造成介质沉底多而减少有效研磨。选择不同直径的介质按比例混合研磨的效果要优于仅使用单一直径介质的,且在染料与介质的用量相近时,质量比越小所得染料粒径越小
研磨浆的浓度、黏度和pH值 浓度过低,染料工作量少,降低工作效率;浓度过高则染料易聚集,且体系黏度增加,流动性差,摩擦碰撞弱。调节pH值可避免染料结构被破坏
研磨温度
和时间		 染料表面能增加和物料碰撞均产热,体系降温可减少染料团聚、体系浓度和黏度等的变化。研磨时染料的团聚和粉碎会达到动态平衡,选择当染料粒径达到产品要求时的研磨时间即可
其他设备设置 如研磨机转速,提高则利于物料的碰撞;若过高染料易过细或团聚。高压均质机的压力,普通分散染料生产时控制在60~80 MPa,喷墨用液体分散染料生产时则为100~120 MPa

Tab.3

Relevant literature data for disperse dyes superfine and dispersion"

分散染料 结构 晶型
(尺寸)		 分散剂 染料含
量/%		 染料与分散
剂质量比		 介质
(尺寸)		 介质质
量比		 时间/h 平均粒
径/nm		 PDI 文献
自制染料 靛吩咛 — MF — 1∶2 氧化锆
(0.2 nm)		 — 12 184 — [25]
分散蓝291 偶氮 333
分散蓝56 蒽醌 184
分散红54 偶氮 原 (28.5 nm) PX 4701丙烯
酸嵌段共聚物
活性分散剂		 — 5∶2 氧化锆
(0.6 nm)		 — 8 369.7 0.344 [26]
α(17.5 nm) 5 360.5 0.370
β(10.4 nm) 2 369.2 0.355
自制染料 偶氮 — MF — 1.3∶0.8 石英砂 — 8 278.8 0.259 [27]
85A 331.1 0.296
MF-85A 243.1 0.212
分散红60 蒽醌 — CBOS-4 — 1∶1 氧化锆
(2、1、0.5 nm)		 1∶3∶1 48 159 — [28]
2∶5∶3 166
3∶4∶3 197
分散橙30 偶氮 — 自制
SPG-1型		 5 1∶2 氧化锆 — 14 289.3 — [29]
10 1∶1 216.4
20 2∶1 411.3
[1] 陈荣圻. 再论染料工业如何由大做强[J]. 染料与染色, 2019, 56(1):12-22.
CHEN Rongqi. Further on how to push our large dye industries to grow stronger[J]. Dyestuffs and Coloration, 2019, 56(1):12-22.
[2] GHARANJIG H, GHARANJIG K, TAFAGHODI S. Stability of dye dispersions in the presence of some eco-friendly dispersing agents[J]. Journal of Surfactants and Detergents, 2013, 16(6):849-856.
doi: 10.1007/s11743-013-1493-x
[3] 梁静, 钟毅, 毛志平, 等. 晶型对分散染料染色性能的影响[J]. 纺织学报, 2018, 39(7):69-73.
LIANG Jing, ZHONG Yi, MAO Zhiping, et al. Effect of crystal form on dyeing behavior of disperse dyes[J]. Journal of Textile Research, 2018, 39(7):69-73.
[4] 周乃锋, 傅伟松, 唐智勇, 等. 基于粒径分析的分散染料黑浆聚集沉淀[J]. 纺织学报, 2016, 37(4):80-85.
ZHOU Naifeng, FU Weisong, TANG Zhiyong, et al. Precipitation of disperse dye black slurry based on diameter analysis[J]. Journal of Textile Research, 2016, 37(4):80-85.
[5] 刘越, 程玲, 郝昆玥, 等. 分散剂对分散紫B原染料的分散及染色性能影响[J]. 纺织高校基础科学学报, 2019, 32(2):204-211.
LIU Yue, CHENG Ling, HAO Kunyue, et al. The effect of dispersant on the dispersibility and dyeing properties of Disperse Purple B raw dyes[J]. Basic Sciences Journal of Textile Universities, 2019, 32(2):204-211.
[6] EL-WAHAB A H, NASSER A M, ELBARY H, et al. Effect of the modified dispersing agent and milling time on the properties and particle size distribution of inkjet ink formulation for textile printing[J]. Pigment & Resin Technology, 2020. DOI: 10.1108/PRJ-07-2020-0069.
doi: 10.1108/PRJ-07-2020-0069
[7] 何瑾馨. 染料化学[M]. 2版. 北京: 中国纺织出版社, 2016: 216-217.
HE Jinxin. Dye chemistry[M]. 2nd ed. Beijing: China Textile & Apparel Press, 2016:216-217.
[8] DING Y, YE M, HAN A, et al. Preparation and characterization of encapsulated C.I. Pigment Yellow 12 via ball-milling and mini-emulsion polymerization[J]. Progress in Organic Coatings, 2018, 117:69-75.
doi: 10.1016/j.porgcoat.2018.01.009
[9] YIN X, XU W F, PU Y, et al. Preparation of aqueous nanodispersions of disperse dye by high-gravity technology and spray drying[J]. Chemical Engineering & Technology, 2020, 43(10):2118-2125.
[10] ELSHEMY N S, EL-SAYAD H S, EL-RAHMAN A, et al. Optimization and characterization of prepared nano-disperse dyes via a sonication process and their application in textile dyeing and printing[J]. Fibers and Polymers, 2019, 20(12):2540-2549.
doi: 10.1007/s12221-019-9135-1
[11] 申盛伟, 汪洋, 朱兵兵, 等. 超细粉体制备技术研究进展[J]. 环境工程, 2014, 32(9):102-105,124.
SHEN Shengwei, WANG Yang, ZHU Bingbing, et al. Developments of ultrafine powder preparation techni-ques[J]. Environmental Engineering, 2014, 32(9):102-105, 124.
[12] 艾丽, 朱亚伟. 液体分散染料的技术进步及应用[J]. 印染, 2019, 45(24):47-52.
AI Li, ZHU Yawei. The development of liquid disperse dye and its application[J]. China Dyeing & Finishing, 2019, 45(24):47-52.
[13] GAO W, CHEN F, WANG X, et al. Recent advances in processing food powders by using superfine grinding techniques: a review[J]. Comprehensive Reviews in Food Science and Food Safety, 2020, 19(4):2222-2225.
doi: 10.1111/crf3.v19.4
[14] OGI T, ZULHIJAH R, IWAKI T, et al. Recent progress in nanoparticle dispersion using bead mill[J]. KONA Powder and Particle Journal, 2017, 34:3-23.
doi: 10.14356/kona.2017004
[15] DUMAY E, CHEVALIER-LUCIA D, PICART-PALMADE L, et al. Technological aspects and potential applications of (ultra) high-pressure homogenisa-tion[J]. Trends in Food Science and Technology, 2013, 31(1):13-26.
doi: 10.1016/j.tifs.2012.03.005
[16] 夏红波. 湿法染料后处理砂磨工艺设备优化[J]. 石油和化工设备, 2013, 16(9):27-31.
XIA Hongbo. Optimization of sand milling process equipment for wet dye post-treatment[J]. Petro & Chemical Equipment, 2013, 16(9):27-31.
[17] 章建新, 杨军浩, 任再新. 超高压均质机在还原染料生产中的应用[J]. 上海染料, 2017, 45(1):30-33.
ZHANG Jianxin, YANG Junhao, REN Zaixin. The application of ultra-high pressure homogenizer in the production of vat dyes[J]. Shanghai Dyestuffs, 2017, 45(1):30-33.
[18] BAIGEREYEV S, GURYANO V, GEORGI Y. New method for increase in product fineness in stirred mills[J]. Archives of Civil and Mechanical Engineering, 2019, 19(3):768-778.
doi: 10.1016/j.acme.2019.03.003
[19] 贾建洪, 俞冬萍, 许萌, 等. 超细分散蓝291的制备[J]. 浙江工业大学学报, 2012, 40(5):477-480.
JIA Jianhong, YU Dongping, XU Meng, et al. The preparation of ultrafine Disperse Blue 291[J]. Journal of Zhejiang University of Technology, 2012, 40(5):477-480.
[20] BABAEI G A S, YAZDANSHENAS M E, KHAJAVI R, et al. Ultrasound-assisted of poly(trimethylene terephthalate) dyeing with nano-Disperse Blue 79: isotherms, kinetics, and thermodynamics insights[J]. Journal of The Textile Institute, 2020. DOI: 10.1080/00405000.2020.1816669.
doi: 10.1080/00405000.2020.1816669
[21] MÜLLER F. Wet classification in the fines range<10 μm[J]. Chemical Engineering & Technology, 2010, 33(9):1419-1426.
[22] 高建荣. 染料化学工艺学[M]. 北京: 化学工业出版社, 2015: 134-135.
GAO Jianrong. Dye chemical technology[M]. Beijing: Chemical Industry Press, 2015:134-135.
[23] KIM G Y, PERUMAL S, KIM S C, et al. Design and prediction of dye dispersibility stabilized by polymeric dispersants using a dye-monomer interaction force measurement[J]. Dyes and Pigments, 2020, 172:107791.
doi: 10.1016/j.dyepig.2019.107791
[24] 艾丽, 曹红梅, 朱亚伟, 等. 基于液体分散染料的微量印花技术[J]. 纺织学报, 2018, 39(9):77-83.
AI Li, CAO Hongmei, ZHU Yawei, et al. Ultralow pollution micro-printing method based on liquid disperse dyes[J]. Journal of Textile Research, 2018, 39(9):77-83.
[25] 胡倩, 江华, 刘俊英, 等. 靛吩咛染料的分散性及其对染色性能的影响[J]. 印染, 2019, 45(19):1-7.
HU Qian, JIANG Hua, LIU Junying, et al. Dispersion of indophenine dyes and their effects on dyeing performance[J]. China Dyeing & Finishing, 2019, 45(19):1-7.
[26] 梁静. 分散染料晶型与稳定性研究[D]. 上海: 东华大学, 2018: 26-28, 33-34.
LIANG Jing. The effect of crystal modification on dyeing behavior of disperse dyes[D]. Shanghai: Donghua University, 2018: 26-28, 33-34.
[27] 吴凌霜, 傅丹娜, 侯爱芹, 等. 含氰基分散染料墨水的制备及喷墨印花性能[J]. 印染, 2016, 42(5):1-7.
WU Lingshuang, FU Danna, HOU Aiqin, et al. Preparation of cyano-disperse dye inks and their ink-jet printing properties[J]. China Dyeing & Finishing, 2016, 42(5):1-7.
[28] 石磊, 黄庆鑫, 朱谱新. 球磨法制备分散红60微纳米分散液的研究[J]. 印染助剂, 2015, 32(1):15-18.
SHI Lei, HUANG Qingxin, ZHU Puxin. Preparation of micro-nano-sized C.I. Disperse Red 60 by ball milling[J]. Textile Auxiliaries, 2015, 32(1):15-18.
[29] 刘媛媛, 钟毅, 徐红, 等. 液体分散染料的超细化制备工艺[J]. 印染, 2021, 47(1):6-10.
LIU Yuanyuan, ZHONG Yi, XU Hong, et al. Ultrafine preparation of liquid disperse dyestuff[J]. China Dyeing & Finishing, 2021, 47(1):6-10.
[30] 江华, 蔡金芳, 郑天依, 等. 醌式噻吩染料的分散性及其对染色性能的影响[J]. 浙江理工大学学报(自然科学版), 2018, 39(6):673-679.
JIANG Hua, CAI Jinfang, ZHENG Tianyi, et al. Dispersion property of quinoidal thiophene dyes and their effect on dyeing performence[J]. Journal of Zhejiang Sci-Tech University (Natural Sciences Edition), 2018, 39(6):673-679.
[31] QIAN H F, WANG Y G, CHEN X C, et al. Structural and spectral characterizations of C.I. Disperse Blue 148 having a new crystalline form[J]. Dyes and Pigments, 2013, 99(2):489-495.
doi: 10.1016/j.dyepig.2013.06.002
[32] 何旭斌, 欧其, 高怀庆, 等. 一种制备稳定晶型偶氮分散染料的方法: 201310045497.4 [P]. 2016-08-17.
HE Xubin, OU Qi, GAO Huaiqing, et al. Method for preparing stable crystalline azo disperse dye: 201310045497.4 [P]. 2016-08-17.
[33] 何玉宏. 高温分散剂的合成及其对分散染料的染色应用[D]. 上海: 东华大学, 2018: 2-6.
HE Yuhong. Synthesis of high temperature dispersants and their application to dyeing dyes[D]. Shanghai: Donghua University, 2018: 2-6.
[34] 张志鸣. 羧甲基化木质素磺酸盐染料分散剂的制备与表征[D]. 广州: 华南理工大学, 2015: 63-64.
ZHANG Zhiming. Preparation and characterization of carboxymethylated lignosulfonate dye dispersant[D]. Guangzhou: South China University of Technology, 2015: 63-64.
[35] QIN Y, YUAN M, HU Y, et al. Preparation and interaction mechanism of nano disperse dye using hydroxypropyl sulfonated lignin[J]. International Journal of Biological Macromolecules, 2020, 152:280-287.
doi: 10.1016/j.ijbiomac.2020.02.261
[36] QIAN T, ZHONG Y, MAO Z, et al. The comb-like modified styrene-maleic anhydride copolymer dispersant for disperse dyes[J]. Journal of Applied Polymer Science, 2019, 136(16):47330.
doi: 10.1002/app.v136.16
[37] 张泽慧, 郝昆玥, 莫林祥, 等. 阴离子分散剂对分散橙SE-RFL原染料的分散及其染色性能影响[J]. 纺织科学与工程学报, 2018, 35(4):71-75.
ZHANG Zehui, HAO Kunyue, MO Linxiang, et al. Effects of anionic dispersant on the dispersion and dyeing properties of Disperse Orange SE-RFL raw dyes[J]. Journal of Textile Science and Engineering, 2018, 35(4):71-75.
[38] GHARANJIG K, DADRAS F S, SADEGHI-KIAKHANI M, et al. Stability of dye dispersions in the presence of various surface active agents and additives[J]. Journal of Dispersion Science and Technology, 2013, 34(3):381-388.
doi: 10.1080/01932691.2012.660777
[39] GAO C, XING T, CHEN G. Effect of polyol molecular structure on fluidity, surface tension, and printed pattern sharpness of disperse dye inks[J]. Langmuir: the ACS Journal of Surfaces and Colloids, 2020, 36(46):14130-14144.
doi: 10.1021/acs.langmuir.0c02812
[40] CHU R, ZHANG Y, XING T, et al. The stability of disperse red/reactive-red dye inks[J]. RSC Advances, 2020, 10(70):42633-42643.
doi: 10.1039/D0RA07333D
[41] FLACH F, KONNERTH C, PEPPERSACK C, et al. Impact of formulation and operating parameters on particle size and grinding media wear in wet media milling of organic compounds :a case study for pyrene[J]. Advanced Powder Technology, 2016, 27(6):2507-2519.
doi: 10.1016/j.apt.2016.09.026
[42] 卜广玖, 仇兆波, 王震, 等. 高悬浮液状分散染料[J]. 印染, 2015, 41(15):20-23.
BU Guangjiu, QIU Zhaobo, WANG Zhen, et al. High suspended liquid disperse dyes[J]. China Dyeing & Finishing, 2015, 41(15):20-23.
[43] LI M, LU Q, LIU A, et al. Benzyl-containing azobenzene-based disperse dyes: relationship between molecular packing and alkali-resistant stability[J]. Journal of Molecular Liquids, 2020, 317:114270.
doi: 10.1016/j.molliq.2020.114270
[44] 郭志明. 从分散蓝54号喷雾干燥谈后处理喷雾干燥操作优化[C]// 第19届全国印染技术交流会论文集. 青岛: 全国印染科技信息中心, 2017: 39-43.
GUO Zhiming. Discussing the optimization of post-treatment spray drying operation from the spray drying of Disperse Blue 54[C]// Proceedings of the 19th National Printing and Dyeing Technology Exchange Conference. Qingdao: National Printing and Dyeing Technology Information Center, 2017: 39-43.
[45] 冯欢. 高含固量超细液状分散染料的制备及其应用研究[D]. 苏州: 苏州大学, 2016: 30-32.
FENG Huan. Study of preparation and application of ultra-fine liquid disperse dyes with high solid con-tent[D]. Suzhou: Soochow University, 2016: 30-32.
[46] 沈卫庆, 项斌, 高建荣, 等. 高压均质工艺制备超细分散染料的研究[J]. 染料与染色, 2007, 44(2):43-45.
SHEN Weiqing, XIANG Bin, GAO Jianrong, et al. A study on the preparation of ultra-fine particle size of disperse dyes by high pressure homogenization technology[J]. Dyestuffs and Coloration, 2007, 44(2):43-45.
[47] 杨军浩, 钱伟. 颜料染料超细、纳米级粉碎技术进展[J]. 上海染料, 2014, 42(5):69-75.
YANG Junhao, QIAN Wei. Progress in ultrafine, nano level grinding technique of pigments and dyes[J]. Shanghai Dyestuffs, 2014, 42(5):69-75.
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