Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (06): 120-127.doi: 10.13475/j.fzxb.20200805608

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Cotton knitted fabrics treated with two-dimensional transitional metal carbide Ti3C2Tx and property analysis

LI Yifei, ZHENG Min(), CHANGZHU Ningzi, LI Liyan, CAO Yuanming, ZHAI Wangyi   

  1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215006, China
  • Received:2020-08-12 Revised:2021-03-18 Online:2021-06-15 Published:2021-06-28
  • Contact: ZHENG Min E-mail:zhengmin@suda.edu.cn

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Abstract:

To study the application of textiles, a two-dimensional nanomaterial Ti3C2Tx was prepared using Ti3AlC2 as the precursor based on the selective etching of LiF/HCl. Transmission electron microscope, scanning electron microscope, X-ray energy spectrum diffraction, ultraviolet-visible absorption spectrum were used to characterize the surface morphology, structure, chemical composition of Ti3C2Tx, which was used to treat cotton knitted fabrics using the pad-dry-cure technique with optimised finishing technic parameters. The results show that under the condition that the concentration of Ti3C2Tx was 8 g/L, the liquid ratio was 100%, the dipping time was 40 min, the baking temperature was 150 ℃, baking time was 3 min and repeated 4 times, the fabric had the best conductivity with 1.25% Ti3C2Tx loading. Ti3C2Tx is uniformly distributed on the surface of the fabric, and the surface resistance is significantly reduced to 600 Ω/□. The fabric after several finishing has excellent UV resistance, and the ultraviolet protection value reaches 500. The finished fabric presents good breathability, and the surface resistance of the finished fabric is lower than 5 kΩ/□ after 5 times of finishing under 20 times of washing.

Key words: Ti3C2Tx(MXene), conductive fabric, UV resistance, electric conductivity, functional finishing, cotton knitted fabric, smart clothing

CLC Number: 

  • TS195.2

Fig.1

XRD pattern of Ti3C2Tx with different time in etching "

Fig.2

SEM images of Ti3C2Tx at different phase of etching and Ti3C2Tx treated fabric.(a) Ti3C2Tx before etching; (b) Ti3C2Tx etching for 6 h; (c) Ti3C2Tx etching for 24 h; (d) Ti3C2Tx treated fabric "

Fig.3

TEM images of Ti3C2Tx flakes.(a) Multi-layered Ti3C2Tx; (b) Single layered Ti3C2Tx "

Fig.4

EDX-SEM analysis of Ti3C2Tx treated fabric.(a) EDS spectrum; (b) EDS-SEM image; (c) Mapping images of Ti; (d) Mapping images of C; (e) Mapping images of F "

Fig.5

Influence of Ti3C2Tx concentration on surface resistance of fabric "

Fig.6

Influence of pick-up on surface resistance of fabric"

Fig.7

Influence of dipping time on surface resistance of fabric"

Fig.8

Influence of baking temperature on surface resistance of fabric"

Fig.9

Influence of baking time on surface resistance of fabric"

Fig.10

Influence of finishing times on Ti3C2Tx loading(a) and surface resistance of fabric(b) "

Tab.1

UV resistance of fabric finished by Ti3C2Tx "

整理次数 UPF值 透过率/%
UVA UVB
0(原织物) 32.97 2.08 2.87
1 354.20 0.31 0.29
2 500.00 0.16 0.16
3 500.00 0.09 0.08
4 500.00 0.09 0.08
5 500.00 0.08 0.08

图12

UV transmittance of Ti3C2Tx with different finishing times "

Fig.12

UV-vis spectrum of Ti3C2Tx "

Tab.2

Breathability of fabric finished by Ti3C2Tx "

整理次数 透气率/(mm·s-1)
0(原织物)
1
2
3
4
5 		302.12
231.02
210.64
202.46
200.18
189.20

Tab.3

Washing fastness of fabric finished by Ti3C2Tx "

整理次数 表面电阻/(kΩ·□-1)
未水洗 水洗5次 水洗10次 水洗20次
1 2.46 8.84 15.69 37.45
3 0.95 1.82 3.77 8.68
5 0.59 1.10 2.16 4.62

Tab.4

Rubbing fastness test of fabric finished by Ti3C2Tx "

整理次数 耐摩擦色牢度/级
干摩 湿摩
1 4 3
3 3~4 2~3
5 3 2
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