Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (03): 14-20.doi: 10.13475/j.fzxb.20200905907

• Invited Column:Full-process Open Width Printing and Dyeing Technology for Knitted Fabric • Previous Articles     Next Articles

Durable fluoride-free water-repellent finishing of polyamide/cotton blended fabric

LU Xue1, LIU Xiuming1(), FANG Kuanjun1,2, LI Hanyu3, LI Xiang4, GAO Chuang1   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. School of Textiles and Clothing, Qingdao University, Qingdao, Shandong 266071, China
    3. China Textile Academy, Beijing 100025, China
    4. Beijing CTA Textile Chemicals Co., Ltd., Beijing 100176, China
  • Received:2020-09-22 Revised:2020-12-21 Online:2021-03-15 Published:2021-03-17
  • Contact: LIU Xiuming E-mail:liuxiuming@tiangong.edu.cn

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Abstract:

In order to meet the special requirements of polyamide/cotton blended fabrics for outdoor sports end-uses, the blended fabrics were coated with fluorine-free water-repellent agent (CWR-9A), and an adhesive was added to further improve the adhesion fastness between the water-repellent and the fabric. The effect of water-repellent mass concentration, baking time, baking temperature, adhesive type, different volume ratios of adhesives and CWR-9A, washing times were studied on water-repellent treated fabrics. For the polyamide/cotton blended fabrics, the optimal water-repellent finishing process is 120 g/L CWR-9A, temperature at 170 ℃, baking time duration 90 s, and the volume ratio of BD-01 to CWR-9A is 1∶20. The surface structure and morphology of the water-repellent agent and treated fabric were characterized, and the contact angle and water-repellent grade of the treated fabric were measured. The results indicate that adhesion fastness between polyamide/cotton blended fabrics treated with adhesive BD-01 and water repellent CWR-9A is significantly improved. The maximum contact angle is 138°, and the water-repellent grade reaches level 5.

Key words: fluorine-free water-repellent agent, polyamide/cotton blended fabric, adhesive, water repellent finishing, adhesion fastness

CLC Number: 

  • TS195.2

Fig.1

Particle size distribution of fluorine-free water-repellent CWR-9A"

Fig.2

Effect of fluorine-free water-repellent CWR-9A mass concentration on contact angle of polyamide/cotton blended fabric"

Fig.3

Effect of baking temperature on contact angle of polyamide/cotton blended fabric finished by CWR-9A"

Fig.4

Effect of baking time on contact angle of polyamide/cotton blended fabric finished by CWR-9A"

Tab.1

Water-repellency of polyamide/cotton blended fabric finished by CWR-9A before and after washing"

织物 接触角/(°) 拒水等级/级
洗涤前 135 4
洗涤1次后 129 0

Tab.2

Effect of adhesive type on contact angle of polyamide/cotton blended fabric finished by CWR-9A"

黏合剂种类 接触角/(°)
468 129
468B 127
1901R 132
3602 131
FK-C —
DF-891B 136
BD-01 138
TF-313E —

Fig.5

Effect of volume ratio of BD-01 and CWR-9A on contact angle of polyamide/cotton blended fabric"

Tab.3

Effect of washing times on contact angle of polyamide/cotton blended fabric finished by BD-01 and CWR-9A"

水洗次数 水洗时间/min 接触角/(°)
1 30 137
2 60 135
3 90 133
4 120 132
5 150 130

Tab.4

Water repellency level of polyamide/cotton blended fabric under different finishing conditions"

织物类型 拒水等级/级
原布 0
CWR-9A整理 4
CWR-9A整理后水洗 0
BD-01与CWR-9A整理 5
BD-01与CWR-9A整理后水洗 4~5

Fig.6

SEM images of polyamide/cotton blended fabrics(×1 000). (a)Untreated fabric; (b)Treated fabric with CWR-9A; (c)Treated fabric with CWR-9A after washing;(d)Treated fabric with BD-01 and CWR-9A; (e)Treated fabric with BD-01 and CWR-9A after washing"

[1] 张华, 秦雅伟, 周永凯. 锦纶/棉混纺织物的热湿舒适性研究[J]. 棉纺织技术, 2016,44(8):27-30.
ZHANG Hua, QIN Yawei, ZHOU Yongkai. Research on thermal and wet comfort of nylon-cotton blended fabrics[J]. Cotton Textile Technology, 2016,44(8):27-30.
[2] 李昌龄, 王文聪, 华东, 等. 锦纶基磁性纤维的制备及其性能[J]. 纺织学报, 2019,40(11):26-31,37.
LI Changling, WANG Wencong, HUA Dong, et al. Preparation and properties of nylon-based magnetic fiber[J]. Journal of Textile Research, 2019,40(11):26-31,37.
[3] 颜东, 邓继勇, 汪南方, 等. 有机硅改性聚氨酯/丙烯酸酯共聚乳液对棉织物的抗皱整理[J]. 纺织学报, 2018,39(1):89-93.
YAN Dong, DENG Jiyong, WANG Nanfang, et al. Anti-wrinkle finishing of cotton fabric by silicone modified polyurethane/acrylate copolymer emulsion[J]. Journal of Textile Research, 2018,39(1):89-93.
[4] 欧卫国, 杨小玲, 蔡云芸, 等. 纯棉织物的拒水拒油易去污整理[J]. 纺织科技进展, 2019(5):17-19.
OU Weiguo, YANG Xiaoling, CAI Yunyun, et al. Water and oil repellent and easy stain removal finishing of cotton fabrics[J]. Progress in Textile Science and Technology, 2019 (5):17-19.
[5] 秦雅伟, 周永凯, 张华. 涤/棉、锦/棉混纺纱线的性能优化研究[J]. 纺织导报, 2015(10):88-90,92.
QIN Yawei, ZHOU Yongkai, ZHANG Hua. Study on the performance optimization of polyester/cotton, nylon/cotton blended yarns[J]. China Textile Leader, 2015(10):88-90,92.
[6] DU J, ZHANG L, DONG J, et al. Preparation of hydrophobic nylon fabric[J]. Journal of Engineered Fibers & Fabrics, 2016,11(1):31-37.
[7] 张阳, 王瑄, 沈兰萍, 等. 锦棉户外织物的拒水拒油整理[J]. 合成纤维, 2016,45(6):42-44,48.
ZHANG Yang, WANG Xuan, SHEN Lanping, et al. Water and oil repellent finishing of nylon cotton outdoor fabric[J]. Synthetic Fiber in China, 2016,45(6):42-44,48.
[8] 赵晓明, 刘宝成, 王锡晨, 等. 混纺拒水拒油织物的开发[J]. 纺织科学与工程学报, 2018,35(2):26-29.
ZHAO Xiaoming, LIU Baocheng, WANG Xichen, et al. Development of water- and oil-repellent blended fabrics[J]. Journal of Textile Science and Engineering, 2018,35(2):26-29.
[9] 赵汇生, 狄剑锋. 织物的拒水拒油透气整理[J]. 中国个体防护装备, 2001(3):17-19.
ZHAO Huisheng, DI Jianfeng. Water and oil repellent breathable finishing of fabrics[J]. China Personal Protective Equipment, 2001(3):17-19.
[10] 陆妙停. 织物拒水拒油整理综述[J]. 上海丝绸, 2001(3):14-19.
LU Miaoting. Summary of water and oil repellent finishing of fabrics[J]. Shanghai Silk, 2001 (3):14-19.
[11] 张建国, 陈晓妹, 卢霜, 等. 无氟防水剂DM-3696在化纤面料上的应用[J]. 印染助剂, 2019,36(8):55-57.
ZHANG Jianguo, CHEN Xiaomei, LU Shuang, et al. Application of fluorine-free waterproofing agent DM-3696 on chemical fiber fabrics[J]. Textile Auxiliaries, 2019,36(8):55-57.
[12] 顾浩, 韩杰, 杨皓, 等. 防水整理剂的发展与应用现状[J]. 纺织导报, 2019(4):20-22,24-26.
GU Hao, HAN Jie, YANG Hao, et al. Development and application status of waterproof finishing agent[J]. China Textile Leader, 2019(4):20-22,24-26.
[13] 陈荣圻. PFOS的禁用及相关产品的替代[J]. 印染, 2008(18):41-44.
CHEN Rongqi. Prohibition of PFOS and replacement of related products[J]. China Dyeing & Finishing, 2008 (18):41-44.
[14] 宋泽华, 李翔. 无氟防水剂对织物与粘合衬剥离强度的影响[J]. 纺织科学研究, 2019(5):77-79.
SONG Zehua, LI Xiang. Effects of fluorine-free waterproofing agents on the peel strength of fabrics and adhesive backings[J]. Textile Science Research, 2019 (5):77-79.
[15] 王宝敬, 冼润媚, 王铁群. 无氟防水剂HIT-FM WFF在棉梭织布防水整理中的应用[J]. 印染助剂, 2016,33(7):53-56.
WANG Baojing, XIAN Runmei, WANG Tiequn. Application of fluorine-free waterproofing agent HIT-FM WFF in waterproof finishing of cotton woven fabrics[J]. Textile Auxiliaries, 2016,33(7):53-56.
[16] 黄晨, 柯勤飞, 李祖安, 等. 纯棉水刺非织造材料的单向导水无氟整理[J]. 纺织学报, 2019,40(7):119-127.
HUANG Chen, KE Qinfei, LI Zu'an, et al. One-way water-free fluorine-free finishing of pure cotton spunlacenon wovens[J]. Journal of Textile Research, 2019,40(7):119-127.
[17] 艾丽, 朱亚伟. 黏合剂的合成及其在分散蓝79微水印花中的应用[J]. 纺织学报, 2019,40(6):50-57.
AI Li, ZHU Yawei. The synjournal of adhesive and its application in disperse blue 79 micro-water printing[J]. Journal of Textile Research, 2019,40(6):50-57.
[18] 孟令川. 环保型无氟无硅拒水剂DM-3616在纯棉机织物上的应用研究[D]. 上海:东华大学, 2014: 21-24.
MENG Lingchuan. Study on the application of environmentally friendly fluoride-free and silicon-freewater repellent DM-3616 on cotton woven fabrics[D]. Shanghai: Donghua University, 2014: 21-24.
[19] 钱海洪. 短链含氟丙烯酸酯拒水拒油整理剂的制备及其应用研究[D]. 无锡:江南大学, 2018: 18-32.
QIAN Haihong. Preparation and application of water-repellent and oil-repellent finishing agents for short-chain fluorine-containing acrylates[D]. Wuxi: Jiangnan University, 2018: 18-32.
[20] LIU X, ZOU X, GE Z, et al. Novel waterborne polyurethanes containing long-chain alkanes: their synjournal and application to water repellency[J]. RSC Advances, 2019,9(54):31357-31369.
[21] 董永春. 纺织品整理剂的性能与应用[M]. 北京: 中国纺织出版社, 1999: 80-100.
DONG Yongchun. Performance and application of textile finishing agent[M]. Beijing: China Textile & Apparel Press, 1999: 80-100.
[22] LUO X, WENG Y, WANG S, et al. Superhydrophobic and oleophobic textiles with hierarchical micro-nano structure constructed by sol-gel method[J]. Journal of Sol-Gel Science and Technology, 2019,89(3):820-829.
[23] 钱海洪, 杜金梅, 傅佳佳, 等. 短链含氟丙烯酸酯拒水拒油剂的合成及应用[J]. 高分子材料科学与工程, 2019,35(2):22-28.
QIAN Haihong, DU Jinmei, FU Jiajia, et al. Synjournal and application of water-repellent and oil-repellent agents for short-chain fluorine-containing acrylates[J]. Polymer Materials Science and Engineering, 2019,35(2):22-28.
[24] ZENG T C, ZHANG P F, LI X X, et al. Facile fabrication of durable superhydrophobic and oleophobic surface on cellulose substrate via thiol-ene click modification[J]. Applied Surface Science, 2019,493:1004-1012.
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