Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (04): 16-25.doi: 10.13475/j.fzxb.20201000610

• Invited Column: Bio-based Polyester and Polyamide Fiber • Previous Articles     Next Articles

Research progress on manufacturing technique of bio-based polytrimethylene terephthalate fibers

WANG Shaobo1,2(), XIAO Yang1,2, HUANG Xin1,2, LI Zengbei1,2   

  1. 1. College of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China
    2. Henan Key Laboratory of Textile Materials, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China
  • Received:2020-10-06 Revised:2021-01-12 Online:2021-04-15 Published:2021-04-20

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Abstract:

The manufacturing techniques for bio-based polytrimethylene terephthalate fiber involves many disciplines, including microbial fermentation, fermentation product purification, polyester polymerization and spinning processing. In order to provide a relatively comprehensive and clear development in this area, the progress of the technology related to the preparation of bio-based polytrimethylene terephthalate fiber was systematically reviewed and analyzed based on the sequence of production process from raw materials to products, including the preparation of bio-based 1,3-propanediol, the synthesis of bio-based polytrimethylene terephthalate and its spinning processing. The future development trends of this technology were also proposed, including low-cost purification and polymerization by using low-purity bio-based raw materials, differentiated development of high-quality fibers, preparation technology of bio-based terephthalic acid, and the establishment of product environmental footprint evaluation system.

Key words: bio-based synthetic fiber, manufacturing technique for fiber, bio-based 1,3-propanediol, bio-based polytrimethylene terephthalate, fermentation technology, catalytic system

CLC Number: 

  • TQ342

Fig.1

Pathway of 1,3-propanediol production from petro-based material. (a)Catalytic hydroformylation of ethylene oxide; (b)Catytic hydroformylation of acrolein"

Fig.2

Core pathway of 1,3-propanediol production by microbial fermentation"

Fig.3

Synthetic pathway of bio-based PTT"

Tab.1

Spinning parameters comparision of SDY and SAY of bio-based PTT"

纺丝
工艺		 纺丝温度/
℃		 冷却
方式		 温度/℃ 线速度/(m·min-1) 卷绕张力/
(cN·dtex-1)
一辊 二辊 三辊 卷绕辊 一辊 二辊 三辊 卷绕辊
SDY 245~285 风冷 85~160 125~195 15~35 15~35 2 600~4 000 4 000~5 200 4 000~5 000 4 000~5 000 0.036~0.110
SAY 245~285 风冷 90~165 15~35 — 15~35 3 500~4 000 3 800~4 200 — 3 800~4 200 0.045~0.073
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