Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (09): 97-103.doi: 10.13475/j.fzxb.20201001307

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Application of catalytic oxidative soaping for polyester/cotton fabric dyeing in one bath

ZHANG Fan1, ZHANG Guobo1, ZHAO Yuxin1, ZHANG Ru1, YANG Hai1, WANG Shihao2, WANG Nanfang1()   

  1. 1. Hunan Provincial Key Laboratory of Environmental Catalysis & Waste Recycling, Hunan Institute of Engineering, Xiangtan, Hunan 411104, China
    2. Peolpe's Government of Wutan Town in Taojiang County, Yiyang, Hunan 413407, China
  • Received:2020-10-07 Revised:2021-06-02 Online:2021-09-15 Published:2021-09-27
  • Contact: WANG Nanfang E-mail:cdwnf@126.com

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Abstract:

In order to increase color fastnesses of the polyester/cotton fabrics dyed by one bath method and promote energy conservation and emission reduction, a novel method of catalytic oxidation based on a metal complex/H2O2 system was introduced into the soaping process of the one bath dyeing of the polyester/cotton fabrics. The complex catalytic activities of Fe(II) citrate and Mn(II) citrate were investigated by using theoretical calculation and soaping experiment. The influence of soaping process parameters on properties of decolorization and K/S value was studied. The comparative experiment was used for valuating the catalytic oxidative soaping and the reduction free cleaning. The optimal catalytic oxidative soaping process was found to be 1.0% Fe(II) citrate complex with 1.0 g/L concentration, and 30% H2O2 with 3.3 g/L concentration, and soaping at 85 ℃ for 25 min. The results show that the catalytic activity soaping performance of Fe(II) citrate complex is higher than that of Mn(II) citrate complex. Compared to the reduction free cleaning, the catalytic oxidative soaping has better wet color fastnesses (over grade 4) with an outstanding ability of decolorizing the dyeing effluent and reducing its toxicity and a prominent potential of energy conservation and emission reduction. The study is helpful for promoting cleaner dyeing production of polyester/cotton fabrics.

Key words: polyester/cotton fabrics, one-bath dyeing, metal complex, hydrogen peroxide, catalytic oxidation, soaping

CLC Number: 

  • TS193.5

Tab.1

Calculated Gibbs energy difference and mulliken charge of complexes in catalyzed reaction systems"

催化剂 配合物 G/(kJ·mol-1) q ΔG/(kJ·mol-1)
PM6 B3LYP/Lanl2dz PM6 B3LYP/Lanl2dz PM6 B3LYP/Lanl2dz
1# [Fe(II)Cit(H2O)3]- -2 088.589 7 -2 914 043.730 3 +1.059 +1.329 394.190 8 157.904 0
[Fe(III)Cit(H2O)3] -1 694.398 9 -2 913 885.826 3 +1.353 +1.392
2# [Mn(II)Cit(H2O)3]- -2 125.059 7 -2 863 251.108 4 +0.672 +1.251 411.859 2 512.794 5
[Mn(III)Cit(H2O)3] -1 713.200 5 -2 862 738.313 9 +1.245 +1.213

Tab.2

Effect of various catalysts on K/S value and effluent decolorization"

组别 催化剂编号 K/S值 脱色率/%
黄组 1# 12.016 0 25.9
2# 12.304 0 13.6
红组 1# 9.542 6 25.0
2# 9.779 2 14.3
蓝组 1# 21.925 27.0
2# 18.675 11.0

Fig.1

Effect of catalyst concentration on decolorization and K/S value"

Fig.2

Effect of H2O2 concentration on decolorization and K/S value"

Fig.3

Effect of soaping temperature on decolorization and K/S value"

Fig.4

Effect of heating rate on decolorization and K/S value"

Fig.5

Effect of soaping time on decolorization and K/S value"

Tab.3

Orthogonal experimental factors level table for catalytic oxidation soaping in yellow group"

水平 A/(g·L-1) B/(g·L-1) C/℃ D/min
1 0.90 2.5 80 25
2 0.95 2.7 85 30
3 1.00 3.0 90 35
4 1.05 3.3 95 40

Tab.4

Orthogonal test results for catalytic oxidation soaping in yellow group"

试验序号 A B C D 织物
K/S值		 残液脱
色率/%
1 1 1 1 1 9.163 85.5
2 1 2 2 2 9.109 86.3
3 1 3 3 3 9.075 86.6
4 1 4 4 4 9.007 87.0
5 2 1 2 3 9.143 85.7
6 2 2 1 4 9.125 86.3
7 2 3 4 1 9.084 86.7
8 2 4 3 2 9.032 87.1
9 3 1 3 4 9.132 86.0
10 3 2 4 3 9.121 86.4
11 3 3 1 2 9.118 86.8
12 3 4 2 1 9.083 87.5
13 4 1 4 2 9.145 86.1
14 4 2 3 1 9.130 86.3
15 4 3 2 4 9.113 87.2
16 4 4 1 3 9.051 87.3
残液
脱色率		 K1 86.350 85.825 86.475 86.525
K2 86.450 86.325 86.700 86.575
K3 86.700 86.825 86.500 86.500
K4 86.725 87.250 86.550 86.625
R 0.375 1.425 0.225 0.125
织物
K/S值		 K1 9.088 50 9.145 75 9.114 25 9.115 00
K2 9.096 00 9.121 25 9.112 00 9.101 00
K3 9.113 50 9.097 5 9.092 25 9.097 50
K4 9.109 75 9.043 25 9.089 25 9.094 25
R 0.025 0.102 5 0.025 0.020 75

Tab.5

Effect of catalytic oxidation system and conventional soaping process on polyester-cotton fabric dyeing properties"

聚酯 组别 K/S值 顶破强力/N 耐摩擦色牢度/级 耐皂洗色牢度/级
干 湿 变色 沾色
棉
催化氧化皂洗 黄组 8.452 3 527.8 5 4 5 4 4
红组 9.216 1 546.8 5 4~5 5 4~5 4~5
蓝组 18.696 3 562.3 5 4 5 4~5 4~5
免还原清洗 黄组 8.515 4 538.9 4 3~4 4 3 3~4
红组 9.301 1 559.2 4 4 4 3~4 3~4
蓝组 18.804 2 574.8 4 3 4 3 3

Tab.6

Toxicity Comparison"

工艺 发光菌存活数
皂洗前 皂洗后
催化氧化皂洗 35 21
免还原清洗 44 650
[1] 王小艳, 杜金梅, 彭铃淇, 等. 涤纶针织物碱减量和染色一浴一步法工艺[J]. 纺织学报, 2020, 41(1):80-87.
WANG Xiaoyan, DU Jinmei, PENG Lingqi, et al. Alkali reduction and one-bath-one-step process for dyeing polyester knitted fabric[J]. Journal of Textile Research, 2020, 41(1):80-87.
[2] 彭志忠. 高效节能型涤纶/棉混纺针织物染色实践[J]. 染整技术, 2017, 39(8):24-26,42.
PENG Zhizhong. High energy efficient dyeing of polyester/cotton blended knitted fabric[J]. Textile Dyeing and Finishing Journal, 2017, 39(8):24-26,42.
[3] 宋勇, 李旭, 刘涛, 等. 涤纶/棉针织物HA型高耐碱分散染料染色[J]. 印染, 2013, 39(23):25-28.
SONG Yong, LI Xu, LIU Tao, et al. Dyeing of polyester/cotton knits with HA type alkali-resistant disperse dyes[J]. China Dyeing & Finishing, 2013, 39(23):25-28.
[4] 袁洁, 文卓, 贺江平. 涤纶/棉混纺针织物短流程染色工艺的应用研究[J]. 针织工业, 2019(1):46-50.
YUAN Jie, WEN Zhuo, HE Jiangping. Application study of short process dyeing of polyester/cotton blended knitwear[J]. Knitting Industries, 2019(1):46-50.
[5] 王建庆, 吴婵娟, 刘海林. 涤纶/棉织物分散/活性染料染色的免还原净洗技术[J]. 纺织学报, 2013, 34(4):70-74.
WANG Jianqing, WU Chanjuan, LIU Hailin. Reduction clearing-free dyeing of polyester/cotton fabrics with disperse/reactive dyes[J]. Journal of Textile Research, 2013, 34(4):70-74.
[6] 王小艳, 杜金梅, 荆丽丽, 等. 耐碱分散染料上染涤纶织物免还原清洗工艺[J]. 丝绸, 2019, 56(6):19-25.
WANG Xiaoyan, DU Jinmei, JING Lili, et al. Reduction cleaning free process of polyester fabrics with alkali-resistant disperse dyes[J]. Journal of Silk, 2019, 56(6):19-25.
[7] 文水平, 薛桂萍. 涤纶/棉一浴皂洗剂RCW免还原清洗工艺[J]. 印染, 2014, 40(2):31-33.
WEN Shuiping, XUE Guiping. One-bath soaping agent RCW for T/C blends dyeing[J]. China Dyeing & Finishing, 2014, 40(2):31-33.
[8] 刘志军. 涤纶/棉针织物免还原清洗染色工艺[J]. 针织工业, 2018(4):32-35.
LIU Zhijun. Reduction cleaning free dyeing process for polyester and cotton blended knitted fabrics[J]. Knitting Industries, 2018(4):32-35.
[9] SHAIKH I A, AHMAD N, UROOJ F. Improved deep shade reactive dyeingcolorfastness using ozone during wash-off[J]. AATCC Review, 2010, 10(6):73-77.
[10] MAO Y H, GUAN Y, LUO D H, et al. Investigation of ahomogeneous activating ozonation method in the rinsing procedure of cottonfabric dyed with reactive dye[J]. Coloration Technology, 2011, 127(4):256-267.
doi: 10.1111/cote.2011.127.issue-4
[11] 王海峰, 管永华, 朱国华, 等. 活性黄3RS氧化皂洗工艺探讨[J]. 印染助剂, 2012, 29(11):33-35.
WANG Haifeng, GUAN Yonghua, ZHU Guohua, et al. Discussion on oxidation soaping process of Reactive Yellow 3RS[J]. Textile Auxiliaries, 2012, 29(11):33-35.
[12] LUO D H, ZHENG Q K, CHEN S, et al. Decolorization and degradation of reactive dye during the dyed cotton fabric rinsing process[J]. Water Science and Technology, 2010, 62(4):766-775.
doi: 10.2166/wst.2010.307
[13] 张健, 柳荣展, 朱平, 等. 皂洗酶A在活性染色中的应用[J]. 印染, 2008, 34(17):22-24.
ZHANG Jian, LIU Rongzhan, ZHU Ping, et al. Bio-soaping of the reactive dyeings[J]. China Dyeing & Finishing, 2008, 34(17):22-24.
[14] 王世豪, 汪南方, 张帆, 等. 金属配合物-H2O2体系在活性染料消色皂洗中的应用[J]. 印染, 2018, 44(13):36-40.
WANG Shihao, WANG Nanfang, ZHANG Fan, et al. Application of metal complex-H2O2 system to decolorization of the reactive dyeings[J]. China Dyeing & Finishing, 2018, 44(13):36-40.
[15] 崔桂新, 董永春, 王鹏. 羊毛/铁配合物非均相芬顿反应光催化剂的制备及其应用性能[J]. 纺织学报, 2019, 40(12):68-73.
CUI Guixin, DONG Yongchun, WANG Peng. Preparation and application properties of wool-Fe complex-based heterogeneous Fenton photocatalysts[J]. Journal of Textile Research, 2019, 40(12):68-73.
doi: 10.1177/004051757004000110
[16] 夏云, 吕汪洋, 陈文兴. 模拟太阳光下金属酞菁/ 多壁碳纳米管催化降解染料[J]. 纺织学报, 2020, 41(12):94-101.
XIA Yun, LÜ Wangyang, CHEN Wenxing. Catalytic degradation of dye by metal phthalocyanine/multi-walled carbon nanotubes under simulated solar light[J]. Journal of Textile Research, 2020, 41(12):94-101.
[17] 邢建伟, 沈兰萍, 徐成书, 等. 羊毛毛条活性染料原位矿化染色新技术[J]. 毛纺科技, 2015, 43(10):1-4.
XING Jianwei, SHEN Lanping, XU Chengshu, et al. Dyeing of wool top in the in situ mineralization processes[J]. Wool Textile Journal, 2015, 43(10):1-4.
[18] 张宏伟, 徐成书, 邢建伟, 等. 腈纶的原位矿化染色工艺[J]. 印染, 2017, 43(15):20-23,26.
ZHANG Hongwei, XU Chengshu, XING Jianwei, et al. In-situ mineralization and dyeing of acrylic fiber[J]. China Dyeing and Finishing, 2017, 43(15):20-23,26.
[19] 郑文婷, 邢建伟, 徐成书, 等. 锦纶织物原位矿化染色新技术[J]. 合成纤维, 2017, 46(10):34-37.
ZHENG Wenting, XING Jianwei, XU Chengshu, et al. New technology of in-situ mineralized dyeing of polyamide fabric[J]. Synthetic Fiber in China, 2017, 46(10):34-37.
[20] FLORENCE T M. The production of hydroxyl radical from hydrogen peroxide[J]. Journal of Inorganic Biochemistry, 1984, 22(4), 221-230.
doi: 10.1016/0162-0134(84)85007-2
[21] MIgNON P, PERA T M, CHERMETTE H. Oxo iron(Ⅳ) as an oxidative active intermediate of p-chlorophenol in the Fenton reaction: a DFT study[J]. Physical Chemistry Chemical Physics, 2012, 14(11):3766-3774.
doi: 10.1039/c2cp23231f
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