Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (10): 126-131.doi: 10.13475/j.fzxb.20201101506

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Electrical heating properties of fabrics coated by reduced graphene oxide

YU Rufang1,2, HONG Xinghua1,2(), ZHU Chengyan1,2, JIN Zimin1, WAN Junmin1,2   

  1. 1. College of Textiles Science and Engineering(International Institute of Silk), Zhejiang Sci-Tech University,Hangzhou, Zhejiang 310018, China
    2. Zhejiang Sci-Tech University Tongxiang Research Institute, Jiaxing, Zhejiang 314599, China
  • Received:2020-11-09 Revised:2021-07-18 Online:2021-10-15 Published:2021-10-29
  • Contact: HONG Xinghua E-mail:xinghuahong@zstu.edu.cn

RichHTML

19

PDF (PC)

121

Abstract:

In order to study the electrical heating properties of wearable fabrics and the influence of washing on their properties, a reduced graphene oxide (RGO) coated fabric heater was prepared through a simple, safe and industrial-scale liquid phase immersion deposition method that by depositing RGO on polyester knitted fabrics and for reduction in situ. The morphology and chemical structure of RGO coated polyester fabric were characterized by scanning electron microscopy and Fourier transform infrared spectrometer. The electrical conductivity, mechanical and electric heating properties of RGO coated polyester fabrics were also measured. The results show that the electrical conductivity of the RGO coated polyester fabric is 430.94 mS/cm. In addition, the RGO coated polyester fabric can reach a stable-state temperature of 65.58 ℃ under a voltage of 10 V, and the maximum heating rate of 3.14 ℃/s. After two cycles of washing, the RGO coated polyester fabric can reach 43 ℃ under 10 V applied voltage. This paper shows that the RGO coated polyester fabric has remarkable electrical heating properties with great application potentials in medical electrothermal, athletic rehabilitation and other fields.

Key words: electric heater, reduced graphene oxide, dip-coating, knitted fabric, electrical heating property, smart wearable

CLC Number: 

  • TS186

Fig.1

Schematic illustration of fabrication process of RGO coated polyester fabric"

Fig.2

SEM images of RGO coated polyester fabric. (a) NO washing; (b) Washing two cycles; (c) Washing four cycles; (d) Washing eight cycles"

Fig.3

Infrared spectra of polyester fabric, GO coated polyester fabric and RGO coated polyester fabric"

Tab.1

Electrical conductivity of RGO coated polyester fabric before and after washing"

试样名称 电导率/(mS·cm-1)
RGO涂层涤纶织物 430.94
2次水洗后的RGO涂层涤纶织物 175.55
4次水洗后的RGO涂层涤纶织物 106.80
8次水洗后的RGO涂层涤纶织物 59.48

Fig.4

Strain-stress curves of polyester fabric and the RGO coated polyester fabric before and after washing"

Fig.5

Infrared thermal images of RGO coated polyester fabric heating and cooling in 60 s under 10 V"

Fig.6

Temperature versus time curves of RGO coated polyester fabric under different applied voltages"

Fig.7

Heating(cooling) rate curves of RGO coated polyester fabric with different applied voltages"

Tab.2

Comparation of applied voltage, average heating rate and maximum temperature of various fabric heaters in literatures"

外加电压/V 平均加热速率/(℃·s-1) 最高温度/℃ 参考文献
12 2.11 126.6 [2]
4.5 2.8 56 [3]
1.6 0.84 63 [4]
6 16.67 50 [12]
7 0.28 134 [13]
6 0.84 100.9 [20]
10 0.88 65.58 本文

Fig.8

Temperature curve of RGO coated polyester fabric at 10 V before and after washing"

[1] SUI D, HUANG Y, HUANG L, et al. Flexible and transparent electrothermal film heaters based on graphene materials[J]. Small, 2011, 7(22):3186-3192.
doi: 10.1002/smll.v7.22
[2] TIAN M, HAO Y, QU L, et al. Enhanced electrothermal efficiency of flexible graphene fabric Joule heaters with the aid of graphene oxide[J]. Materials Letters, 2019, 234:101-104.
doi: 10.1016/j.matlet.2018.09.078
[3] ZHANG L, BAIMA M, ANDREW T L. Transforming commercial textiles and threads into sewable and weavable electric heaters[J]. ACS Applied Materials & Interfaces, 2017, 9(37):32299-32307.
[4] CHEN Z, YU W, DU Z. Study of electrothermal properties of silver nanowire/polydopamine/cotton-based nanocomposites[J]. Cellulose, 2019, 26(10):5995-6007.
doi: 10.1007/s10570-019-02506-w
[5] 李育洲, 张雨凡, 周青青, 等. 二氧化锰/石墨烯/棉织物复合电极的制备及其电化学性能[J]. 纺织学报, 2020, 41(1):96-101.
LI Yuzhou, ZHANG Yufan, ZHOU Qingqing, et al. Preparation and electrochemical properties of MnO2/graphene/cotton fabric composite electrode[J]. Journal of Textile Research, 2020, 41(1):96-101.
[6] 庞雅莉, 孟佳意, 李昕, 等. 石墨烯纤维的湿法纺丝制备及其性能[J]. 纺织学报, 2020, 41(9):1-7.
PANG Yali, MENG Jiayi, LI Xin, et al. Preparation of graphene fibers by wet spinning and fiber characterization[J]. Journal of Textile Research, 2020, 41(9):1-7.
doi: 10.1177/004051757104100101
[7] 曹机良, 王潮霞. 石墨烯整理蚕丝织物的导电性能[J]. 纺织学报, 2018, 39(12):84-88.
CAO Jiliang, WANG Chaoxia. Electrical conductivity of silk fabrics finished with graphene[J]. Journal of Textile Research, 2018, 39(12):84-88.
[8] 高硕, 孙润军. 电加热织物的研究与开发[J]. 合成纤维, 2021, 50(2):29-32, 42.
GAO Shuo, SUN Runjun. Research and development of electric heating fabrics[J]. Synthetic Fiber in China, 2021, 50(2):29-32, 42.
[9] CAI G, YANG M, XU Z, et al. Flexible and wearable strain sensing fabrics[J]. Chemical Engineering Journal, 2017, 325:396-403.
doi: 10.1016/j.cej.2017.05.091
[10] SHAO F, BIAN S W, ZHU Q, et al. Fabrication of polyaniline/graphene/polyester textile electrode materials for flexible supercapacitors with high capacitance and cycling stability[J]. Chemistry: An Asian Journal, 2016, 11(13):1906-1912.
doi: 10.1002/asia.v11.13
[11] YU R, ZHU C, WAN J, et al. Review of graphene-based textile strain sensors, with emphasis on structure activity relationship[J]. Polymers, 2021, 13(1):151.
doi: 10.3390/polym13010151
[12] WANG D, LI Di, ZHAO M, et al. Multifunctional wearable smart device based on conductive reduced graphene oxide/polyester fabric[J]. Applied Surface Science, 2018, 454:218-226.
doi: 10.1016/j.apsusc.2018.05.127
[13] TIAN M, DU M, QU L, et al. Electromagnetic interference shielding cotton fabrics with high electrical conductivity and electrical heating behavior via layer-by-layer self-assembly route[J]. RSC Advances, 2017, 7(68):42641-42652.
doi: 10.1039/C7RA08224J
[14] HONG X, YU W, WANG A, et al. Graphite oxide paper as a polarizable electrical conductor in the through-thickness direction[J]. Carbon, 2016, 109:874-882.
doi: 10.1016/j.carbon.2016.08.083
[15] HUMMERS J W S, OFFEMAN R E. Preparation of graphitic oxide[J]. Journal of the American Chemical Society, 1958, 80(6):1339.
doi: 10.1021/ja01539a017
[16] HONG X, YU W, CHUNG D. Significant effect of sorbed water on the electrical and dielectric behavior of graphite oxide[J]. Carbon, 2017, 119:403-418.
doi: 10.1016/j.carbon.2017.04.012
[17] 赵静, 张红. 氧化石墨烯的可控还原及表征[J]. 化工进展, 2015, 34(9):3383-3387.
ZHAO Jing, ZHANG Hong. Controllable reduction and characterization of graphene oxide[J]. Chemical Industry and Engineering Progress, 2015, 34(9):3383-3387.
[18] SZABO T, BERKESI O, FORGO P, et al. Evolution of surface functional groups in a series of progressively oxidized graphite oxides[J]. Chemistry of Materials, 2006, 18(11):2740-2749.
doi: 10.1021/cm060258+
[19] BABAAHMADI V, MONTAZER M. Reduced graphene oxide/SnO2 nanocomposite on PET surface: synjournal, characterization and application as an electro-conductive and ultraviolet blocking textile[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 506:507-513.
doi: 10.1016/j.colsurfa.2016.07.025
[20] SADI M S, YANG M, LUO L, et al. Direct screen printing of single-faced conductive cotton fabrics for strain sensing, electrical heating and color changing[J]. Cellulose, 2019, 26(10):6179-6188.
doi: 10.1007/s10570-019-02526-6
[1] . Electrical heating properties of fabric coated by reduced graphene oxide [J]. , 2021, 42(10): 0-0.
[2] CHEN Ke, ZHANG Di, JI Yijun, LE Rongqing, SU Xuzhong. Effect of combed polyester top content on properties of polyester knitted fabrics [J]. Journal of Textile Research, 2021, 42(09): 66-69.
[3] YUAN Luning, WANG Jianping, ZHANG Bingjie, ZHANG Yuting, YAO Xiaofeng. Topological optimization design of dynamic moisture and temperature control for three dimensional knitted fabrics [J]. Journal of Textile Research, 2021, 42(09): 70-75.
[4] YAN Tao, PAN Zhijuan. Strain sensing performance for thin and aligned carbon nanofiber membrane [J]. Journal of Textile Research, 2021, 42(07): 62-68.
[5] LI Yifei, ZHENG Min, CHANGZHU Ningzi, LI Liyan, CAO Yuanming, ZHAI Wangyi. Cotton knitted fabrics treated with two-dimensional transitional metal carbide Ti3C2Tx and property analysis [J]. Journal of Textile Research, 2021, 42(06): 120-127.
[6] WANG Li, ZHANG Bingjie, WANG Jianping, LIU Li, YANG Yalan, YAO Xiaofeng, LI Qianwen, LU You. Development and performance evaluation of bionic knitted winter sports fabrics [J]. Journal of Textile Research, 2021, 42(05): 66-72.
[7] HU Xudong, SONG Yanfeng, RU Xin, PENG Laihu. Modeling and loop length reverse design for reducing diameter tubular weft knitted fabrics [J]. Journal of Textile Research, 2021, 42(04): 80-84.
[8] ZHANG Chentian, ZHAO Lianying, GU Xuefeng. Wearability of hollow coffee carbon polyester/cotton blended weft plain knitted fabric [J]. Journal of Textile Research, 2021, 42(03): 102-109.
[9] YANG Yang, YU Xin, ZHANG Weijing, ZHANG Peihua. Evaluation method and prediction model establishment of cooling performance of knitted fabrics [J]. Journal of Textile Research, 2021, 42(03): 95-101.
[10] LÜ Changliang, HAO Zhiyuan, CHEN Huimin, ZHANG Huile, YUE Xiaoli. Finite element analysis of loop shape in weft knitted fabrics with small deformation based on homogenization theory [J]. Journal of Textile Research, 2021, 42(03): 21-26.
[11] DING Zihan, QIU Hua. Preparation and performance of nano-silica modified water-based polyurethane waterproof and moisture-permeable coated fabrics [J]. Journal of Textile Research, 2021, 42(03): 130-135.
[12] LIU Lidong, LI Xinrong, LIU Hanbang, LI Dandan. Electrostatic adsorption model based on characteristics of weft knitted fabrics [J]. Journal of Textile Research, 2021, 42(03): 161-168.
[13] LIU Libin, LÜ Wangyang, CHEN Wenxing. Catalytic degradation of lignin and lignin model compound by copper complexes in bleaching cotton knitted fabrics [J]. Journal of Textile Research, 2021, 42(03): 1-8.
[14] ZHANG Tengjialu, WU Wei, ZHONG Yi, MAO Zhiping, XU Hong. Effect of open width pretreatment on dyeing property of cotton knitted fabrics [J]. Journal of Textile Research, 2021, 42(03): 9-13.
[15] SUN Yabo, LI Lijun, MA Chongqi, WU Zhaonan, QIN Yu. Simulation on tensile properties of tubular weft knitted fabrics based on ABAQUS [J]. Journal of Textile Research, 2021, 42(02): 107-112.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd