Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (12): 21-27.doi: 10.13475/j.fzxb.20210201908

• Fiber Materials • Previous Articles     Next Articles

Preparation and properties of polyester/silica/orange active ingredient fiber

HUANG Xiaohua1, ZHOU Jialiang2(), CHI Shan1, LIU Yanming1, FU Guangwei3, HU Zexu2, XIANG Hengxue2, ZHU Meifang2   

  1. 1. Bestee Material (Qingdao) Co., Ltd., Qingdao, Shandong 266001, China
    2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
    3. China Textile Engineering Society, Beijing 100025, China
  • Received:2021-02-07 Revised:2021-09-02 Online:2021-12-15 Published:2021-12-29
  • Contact: ZHOU Jialiang E-mail:zhoujialiang@dhu.edu.cn

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Abstract:

In order to solve the problem of functional degradation caused by the loss of natural active ingredients in the production process of polyester fibers, the molecular-nesting technology was independently developed. The orange active ingredients obtained by supercritical CO2 extraction was loaded into mesoporous silica nanoparticles (MSNs) carrier to obtain the polyester/silica/orange active ingre-dient (PET/SiO2/O) fiber with good antibacterial and antiviral effects. The morphology, chemical structure, mechanical properties, active ingredient content, antibacterial and antiviral properties of the modified fiber were characterized and analyzed. The results show that the size, specific surface area and average pore diameter of the achieved MSNs are (100±5) nm, 729.7 m2/g and 2.55 nm, respectively, and the fracture strength of PET/SiO2/O fiber is 3.22 cN/dtex. The content of orange active ingredient naringin in PET/SiO2/O fiber is (0.41±0.05) mg/kg, the antibacterial rate is above 91%, and the antiviral rate is above 99%, which are significantly better than that of the common polyester fibers (p<0.01).

Key words: polyester, silica, orange active ingredient, molecular-nesting technology, supercritical fluent CO2 extraction, antibacterial fiber, antiviral property

CLC Number: 

  • TQ342.8

Fig.1

SEM (a) and TEM (b) image of SiO2 nanoparticles"

Fig.2

N2 adsorption-desorption isotherms (a) and pore size distribution (b) of SiO2 nanoparticles"

Fig.3

SEM images of PET/SiO2/O and PET/O fibers. (a)Surface image of PET/SiO2/O fiber; (b) Section image of PET/SiO2/O fiber; (c) Surface image of PET/O fiber; (d) Section image of PET/O fiber"

Fig.4

High performance liquid chromatograms of naringin standard, PET/SiO2/O and PET/O fiber"

Fig.5

Mechanical properties curves of PET/SiO2/O, PET/O and PET fibers"

Tab.1

Mechanical strength of different polyester fibers"

样品名称 断裂伸
长率/%		 线密度/
dtex		 断裂强度/
(cN·dtex-1)
PET纤维 10.21±0.51 144.00 4.15±0.06
PET/SiO2/O纤维 8.43±0.83 144.00 3.22±0.05
PET/O纤维 8.32±0.62 144.00 2.71±0.04

Tab.2

Antibacterial properties of modified polyester fiber against different strains"

菌种名称 PET纤维活菌
浓度平均值/
(CFU·mL-1)		 PET/SiO2/O纤维 PET/O纤维 PET/SiO2纤维
活菌浓度平均
值/(CFU·mL-1)		 平均抑
菌率/%		 活菌浓度平均
值/(CFU·mL-1)		 平均抑
菌率/%		 活菌浓度平均
值/(CFU·mL-1)		 平均抑
菌率/%
金黄色葡萄球菌 (1.56±0.07)×107 (1.53±0.09)×105 99.01±0.06 (2.01±0.07)×106 87.12±0.46 (1.53±0.06)×107 —
大肠杆菌 (1.81±0.08)×106 (1.44±0.05)×104 99.02±0.26 (3.07±0.11)×105 83.04±0.63 (1.80±0.12)×106 —
白色念珠菌 (2.51±0.05)×105 (2.07±0.09)×104 91.86±0.45 (4.67±0.09)×104 81.41±0.34 (2.46±0.12)×105 —

Tab.3

Antiviral properties to H1N1 of modified polyester fiber"

纤维名称 病毒滴度的对数
平均值 lgTCID50/(20 mL)		 TCID50/(20 mL) 抗病毒活性值 抗病毒率/%
PET纤维 7.45±0.05 (2.81±0.31)×107 — —
PET/SiO2/O纤维 5.08±0.03 (1.21±0.08)×105 2.37±0.03 99.57±0.04
PET/O纤维 5.41±0.05 (2.57±0.33)×105 2.04±0.05 99.09±0.19
PET/SiO2纤维 5.80±0.03 (6.27±0.44)×105 1.65±0.03 —

Tab.4

Antiviral properties to SARS-CoV-2 of PET/SiO2/O fiber"

纤维名称 病毒滴度的对数平均值
lgTCID50/(20 mL)		 TCID50/(20 mL) 抗病毒活性值 抗病毒率/%
PET纤维 6.54 (3.49±0.21)×106 — —
PET/SiO2/O纤维 4.37 (2.36±0.06)×104 2.17±0.01 99.32±0.06
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