Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (12): 15-20.doi: 10.13475/j.fzxb.20210204706

• Fiber Materials • Previous Articles     Next Articles

Preparation and properties of cellulose/calcium alginate blend fiber

CHEN Zihan1, YAO Yongbo2(), SHENG Junlu2, YAN Zhiyong2, ZHANG Yumei3, WANG Huaping3   

  1. 1. Fashion Design Academy, Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China
    2. Key Laboratory of Yarn Materials Forming and Composite Processing Technology of Zhejiang Province, Jiaxing University, Jiaxing, Zhejiang 314001, China
    3. State Key Laboratory of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
  • Received:2021-02-20 Revised:2021-09-13 Online:2021-12-15 Published:2021-12-29
  • Contact: YAO Yongbo E-mail:yaoyongbo@foxmail.com

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Abstract:

In order to reduce the flammability of cellulose fibers, ionic liquid 1-allyl-3-methylimidazole chloride ([AMIM]Cl) was used as co-solvent for cellulose and alginic acid. Then, the cellulose/calcium alginate blend fiber was prepared with calcium chloride solution as the coagulation bath by dry-jet wet spinning. The effect of cellulose/calcium alginate blend ratio on the structure and properties of the fibers were studied. The results show that the cross-section of the blend fibers is dense, and the hydrogen bond interactions exist between cellulose and calcium alginate molecules. Despite the fact of the mechanical strength of the blend fibers decreases with the increase of calcium alginate content, the tensile strength reaches 123 MPa when the content of calcium alginate is 30%, and the self-extinguishing time from fire of this fiber is only 1.1 s, indicating excellent self-extinguishing property. In addition, the moisture regain of cellulose/calcium alginate blend fibers is 7.33%-7.75%, representing good hygrophilic property and wearability for regenerated cellulose fibers.

Key words: cellulose, calcium alginate, dry-jet wet spinning, flame retardant fiber, ionic liquid

CLC Number: 

  • TQ341.5

Tab.1

Spinning conditions for cellulose/calcium alginate blend fibers"

样品
编号		 海藻酸钙质量
分数/%		 凝固浴组成 牵伸
倍数
1# 0 水 4
2# 10 5%氯化钙溶液 4
3# 20 5%氯化钙溶液 4
4# 30 5%氯化钙溶液 4

Fig.1

Spinning schematic diagram of cellulose/calcium alginate blend fibers"

Fig.2

FT-IR spectra of cellulose/calcium alginate blend fiber fibers"

Fig.3

XRD pattern of cellulose/calcium alginate blend fibers"

Fig.4

Cross-section SEM images of cellulose/calcium alginate blend fibers"

Fig.5

Thermogravimetric curves of cellulose/calcium alginate blend fibers"

Tab.2

Mechanical properties of cellulose/calcium alginate blend fibers"

样品
编号		 直径/
μm		 断裂强
度/MPa		 初始模
量/GPa		 断裂伸
长率/%
1# 73.2±4.3 195±22.9 3.41±0.48 14.7±2.3
2# 69.1±5.2 189±31.8 3.14±0.68 15.9±3.1
3# 63.4±6.7 139±34.7 3.01±0.54 10.4±1.9
4# 65.9±4.9 123±35.9 2.58±0.73 8.7±1.1

Fig.6

Combustion properties of cellulose/calcium alginate blend fibers. (a)1# before combustion; (b)1# after combustion;(c)2# before combustion; (d)2# after combustion;(e)3# before combustion; (f)3# after combustion;(g)4# before combustion; (h)4# after combustion"

Fig.7

Hygroscopic properties of cellulose/calcium alginate blend fibers"

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