Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (03): 64-70.doi: 10.13475/j.fzxb.20210205807

• Fiber Materials • Previous Articles     Next Articles

Preparation and selective adsorption of calixarene/reduced graphene oxide fibers

TAO Xuchen(), LI Lin, XU Zhenzhen   

  1. College of Textiles and Clothing, Anhui Polytechnic University, Wuhu, Anhui 241000, China
  • Received:2021-02-23 Revised:2021-10-07 Online:2022-03-15 Published:2022-03-29

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Abstract:

In order to enhance the equilibrium adsorption capacity of calixarene fibers for Pt (Ⅱ), calixarene/reduced graphene oxide (CrGO) fibers were prepared through amidation, reduction and electrospinning. CrGO fibers were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, Raman spectrograph and thermogravimetric analyzer. The adsorption selectivity, adsorption kinetics and adsorption isotherm model of CrGO fibers were investigated. The results indicate that CrGO fibers with diameter of (2±0.5) μm possess some wrinkled morphology, low level of microstructure defects and a high thermal stability. In the presence of Na(I) and Hg (Ⅱ), CrGO fibers exhibit selective adsorption for Pt (Ⅱ), which fits with the pseudo second order adsorption kinetic model and Langmuir adsorption isothermal model. The adsorption behavior of CrGO fibers is mainly attributed to monolayer, chemical, endothermic and preferential adsorption. The equilibrium adsorption capacity of CrGO fibers reaches 113 mg/g at the temperature of 293 K for 240 min, which demonstrates an enhancement by 303% compared with calixarene polyimide fibers.

Key words: calixarene, reduced graphene oxide, graphene fiber, selective adsorption, adsorption kinetics, electrospinning

CLC Number: 

  • TQ342.86

Fig.1

Preparation method of CrGO fibers"

Fig.2

SEM images of CrGO fibers at different magnification"

Fig.3

FT-IR spectra of GO, thioether calixarene and CrGO fibers"

Fig.4

Raman spectra of GO, thioether calixarene and CrGO fibers"

Fig.5

TG curves of GO and CrGO fibers"

Tab.1

Equilibrium adsorption uptake of GO and CrGO fibers for various metal ions"

纤维名称 金属离子平衡吸附量平均值/ (mg·g-1)
Na(Ⅰ) Pt(Ⅱ) Hg(Ⅱ)
GO纤维 115.58 20.33 18.34
CrGO纤维 10.21 108.65 40.42

Fig.6

Putative model of coordination"

Fig.7

Adsorption kinetics curve of Pt (Ⅱ) on CrGO fibers"

Tab.2

Parameters of adsorption isotherm models"

温度/
K		 Langmuir模型 Freundlich模型
qm/
(mg·g-1)		 KL/
(L·mg-1)		 相关系数
R2		 n KF/
(mg·g-1)		 相关系数
R2
283 97.08 0.173 9 0.988 7 3.26 20.91 0.908 4
293 120.48 0.137 2 0.997 6 3.37 25.08 0.838 3
303 129.87 0.130 1 0.976 1 2.84 23.39 0.821 1
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