Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (10): 83-88.doi: 10.13475/j.fzxb.20210206706

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of ozone plasma pretreatment on dyeing properties of aramid fibers

GUO Yafei, LIANG Gaoyong, WANG Meihui, HAO Xinmin()   

  1. Systems Engineering Institute, Academy of Military Sciences, Beijing 100010, China
  • Received:2021-02-26 Revised:2022-07-18 Online:2022-10-15 Published:2022-10-28
  • Contact: HAO Xinmin E-mail:xminhao@126.com

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Abstract:

In order to solve the problem that aramid fiber is difficult to dye and print by conventional process, the aramid fabric was pretreated by ozone plasma and then modified by resin. The influence of plasma pretreatment on the surface elements and morphology of resin modified aramid fiber was studied, and the dyeing effect of modified aramid fabric with disperse dyes was explored. It was found that ozone plasma pretreatment introduced abundant active groups and constructed rough interface, which significantly improved the uniform dispersion of resin, and the bonding strength between resin and fabric increased by 104%. At the same time, the dye uptake (98.6%) and apparent dyeing depth (2.7) of aramid fabric were greatly improved. The color fastness of the dyed fabric has been effectively improved, and the color fastness to friction can meet the requirements of clothing fabrics. The modification of aramid fiber with resin pretreated by ozone plasma has certain reference significance for improving the dyeing properties of aramid fibers.

Key words: aramid fiber, dyeing, plasma, pretreatment, resin modification

CLC Number: 

  • TS193

Fig.1

Dyeing process curve"

Fig.2

SEM images of aramid fabric. (a)Fabric before pretreatment(×500); (b)Fabric after pretreatment(×500); (c)Fabric before pretreatment(×5 000); (d)Fabric after pretreatment(×5 000)"

Tab.1

Content of elements on surface of aramid fabric%"

试样 C N O
预处理前 75.13 3.38 21.49
预处理后 59.57 5.15 35.28

Fig.3

Electronic energy spectra of aramid fiber sample. (a) Full spectra; (b) N1s spectra;(c) C1s spectra; (d) O1s spectra"

Fig.4

Effect of ozone plasma treatment time on quality (a) and capillary effect (b)of aramid fabric"

Fig.5

SEM images of fabrics modified by polyurethane resin. (a)Aramid fabric before pretreatment(×3 000);(b) Aramid fabric after pretreatment(×2 000)"

Tab.2

Dyeing properties of different fabrics before and after modification"

试样 上染率/% 反射率/% K/S值 耐摩擦色牢度/级 耐皂洗色
牢度/级		 耐光色
牢度/级
干摩 湿摩 变色 棉沾
未处理 52.1 43.3 0.4 3 4 4 3~4 3
臭氧等离子体预处理 55.6 41.4 0.6 4 4~5 4 3~4 3
臭氧等离子体预处理+环氧树脂改性 98.3 22.0 2.7 5 4~5 4 3~4 3
臭氧等离子体预处理+聚氨酯改性 98.6 21.5 2.4 5 4~5 4 3~4 3~4
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