Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (08): 126-131.doi: 10.13475/j.fzxb.20210401806

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and decolorization of iron-based metal\|organic framework/activated carbon fiber composites

WANG Jing, LOU Yaya, WANG Chunmei()   

  1. School of Textile and Clothing, Nantong University, Nantong, Jiangsu 226019, China
  • Received:2021-04-07 Revised:2022-05-26 Online:2022-08-15 Published:2022-08-24
  • Contact: WANG Chunmei E-mail:w.cmei@ntu.edu.cn

RichHTML

13

PDF (PC)

122

Abstract:

In order to improve the reusability of iron-based metal\|organic framework (MOF(Fe)), MOF(Fe)/activated carbon fiber composites (MOF(Fe)/ACF) were prepared by in-situ growth at room temperature using pyromellitic acid, ferrous sulfate and activated carbon fiber (ACF). The structure, morphology and elemental composition of the composites were characterized by Fourier transform infrared spectrometer, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. The decolorization of composites on 50 mg/L Reactive Black KN–B was tested under different conditions, and the mechanism of photocatalytic degradation of dye was discussed. The results showed that the decolorization ratio of composite material on Reactive Black KN–B was 64.7％ after 60 min reaction without hydrogen peroxide and 80.2％ with 0.12 mL/L hydrogen peroxide. Under the condition of 1 000 W xenon lamp illumination, adding 0.12 mL/L hydrogen peroxide and reacting for 60 min, the decolorization ratio of MOF(Fe)/ACF for Reactive Black KN–B became 95.7％, 52.2％ higher than that of the ACF. After five times reuse, the decolorization ratio of MOF(Fe)/ACF could still reach 86.0％.

Key words: metal-organic framework, activated carbon fiber, dye decolorization, photo catalysis, dyeing wastewater, wastewater treatment

CLC Number: 

  • X703.1

Fig.1

FT-IR spectra of ACF, MOF(Fe) and MOF(Fe)/ACF"

Fig.2

SEM images of ACF and MOF(Fe)/ACF (×5 000)"

Fig.3

EDS spectra of ACF and MOF(Fe)/ACF"

Fig.4

XRD patterns of ACF and MOF(Fe)/ACF"

Fig.5

Decolorization ratio of ACF and MOF(Fe)/ACF under dark condition"

Fig.6

Decolorization ratio of ACF and MOFC(Fe)/ACF with hydrogen peroxide added to dye solution under dark condition"

Fig.7

Decolorization ratio of ACF and MOF(Fe)/AFC with hydrogen peroxide added to dye solution under light condition"

Fig.8

Reuse decolorization ratio of MOF(Fe)/ACF"

Fig.9

Effect of different trapping agents on decolorization ratio under light condition"

[1] 李庆, 陈灵辉, 李丹, 等. 金属-有机骨架光催化降解染料的研究进展[J]. 纺织学报, 2021, 42(12):188-195.
LI Qing, CHEN Linghui, LI Dan, et al. Research progress in photocatalytic degradation of dyes using metal-organic frameworks[J]. Journal of Textile Research, 2021, 42(12): 188-195.
[2] WANG J Y, WANG R Z, WANG L W. Water vapor sorption performance of ACF-CaCl2 and silica gel-CaCl2 composite adsorbents[J]. Applied Thermal Engineering, 2016, 100(5): 893-901.
doi: 10.1016/j.applthermaleng.2016.02.100
[3] LIU L F, ZHANG P H, YANG F L. Adsorptive removal of 2,4-DCP from water by fresh or regenerated chitosan/ACF/TiO2 membrane[J]. Separation and Purification Technology, 2010, 70(3): 354-361.
doi: 10.1016/j.seppur.2009.10.022
[4] CHEN M X, BAO C Z, HU D W, et al. Facile and low-cost fabrication of ZnO/biochar nanocomposites from jute fibers for efficient and stable photodegradation of methylene blue dye[J]. Journal of Analytical and Applied Pyrolysis, 2019, 139(2): 319-332.
doi: 10.1016/j.jaap.2019.03.009
[5] CHEN H Y, LV K L, DU Y, et al. Microwave-assisted rapid synthesis of Fe2O3/ACF hybrid for high efficient As(V) removal[J]. Journal of Alloys and Compounds, 2016, 674: 399-405.
doi: 10.1016/j.jallcom.2016.03.024
[6] 邓杨, 石现兵, 王涛, 等. 负载MIL-53(Fe) 的改性聚丙烯腈纤维光催化剂的制备及其性能[J]. 纺织学报, 2022, 43(3):58-63.
DENG Yang, SHI Xianbing, WANG Tao, et al. Preparation and performance of modified polyacrylonitrile fibers photocatalyst with MIL-53(Fe)[J]. Journal of Textile Research, 2022, 43(3): 58-63.
[7] HE Y Y, DONG W B, LI X P, et al. Modified MIL-100(Fe) for enhanced photocatalytic degradation of tetracycline under visible-light irradiation[J]. Journal of Colloid and Interface Science, 2020, 574(8): 364-376.
doi: 10.1016/j.jcis.2020.04.075
[8] LIU B B, WANG X Y, LIU H Q, et al. 2D MOF with electrochemical exfoliated graphene for nonenzymatic glucose sensing: central metal sites and oxidation potentials[J]. Analytica Chimica Acta, 2020, 1122: 9-19.
doi: 10.1016/j.aca.2020.04.075
[9] HUANG K, GUO S, WANG R Y, et al. Two-dimensional MOF/MOF derivative arrays on nickel foam as efficient bifunctional coupled oxygen electrodes[J]. Chinese Journal of Catalysis, 2020, 41(11): 1754-1760.
doi: 10.1016/S1872-2067(20)63613-0
[10] 娄娅娅, 王静, 董燕超, 等. 粘胶基沸石咪唑骨架材料的制备及其对染料的脱色[J]. 纺织学报, 2021, 42(2):142-147.
LOU Yaya, WANG Jing, DONG Yanchao, et al. Preparation and decolorization of rayon based zeoliticimidazolate framework functional material[J]. Journal of Textile Research, 2021, 42(2): 142-147.
[11] HAN Q, WANG Z M, CHEN X Y, et al. Facile synthesis of Fe-based MOFs (Fe-BTC) as efficient adsorbent for water purifications[J]. Chemical Research in Chinese Universities, 2019, 35(4):564-569.
doi: 10.1007/s40242-019-8415-z
[12] AHMAD M, CHEN S, YE F, et al. Efficient photo-Fenton activity in mesoporous MIL-100(Fe) decorated with ZnO nanosphere for pollutants degradation[J]. Applied Catalysis B: Environmental, 2019, 245(10): 428-438.
doi: 10.1016/j.apcatb.2018.12.057
[13] 岳琳, 张迎, 徐东升, 等. MOF(Fe)材料用于光-芬顿催化降解酸性大红3R废水[J]. 现代化工, 2019, 39(9):119-123.
YUE Lin, ZHANG Ying, XU Dongsheng, et al. Degradation of acidic red 3R wastewater by a new photo-Fenton system using MOF(Fe) as catalyst[J]. Modern Chemical Industry, 2019, 39(9):119-123.
[14] 庄金亮, 刘湘粤, 张宇, 等. 室温水相制备MIL-100(Fe)纳米材料及其光降解有机染料性能研究[J]. 化工新型材料, 2019, 47(1):259-263.
ZHUANG Jinliang, LIU Xiangyue, ZHANG Yu, et al. Synthesis of MIL-100(Fe) nanoparticle at room temperature and its photocatalytic activity for organic dye[J]. New Chemical Materials, 2019, 47(1): 259-263.
[15] MOHAMMAD N M, ABDI J, OVEISI M, et al. Metal-organic framework (MIL-100 (Fe)): synthesis, detailed photocatalytic dye degradation ability in colored textile wastewater and recycling[J]. Materials Research Bulletin, 2018, 100: 357-366.
doi: 10.1016/j.materresbull.2017.12.033
[16] HASANZADEH M, SIMCHI A, SHAHRIYARIFAR H. Nanoporous composites of activated carbon-metal organic frameworks for organic dye adsorption: synthesis, adsorption mechanism and kinetics studies[J]. Journal of Industrial and Engineering Chemistry, 2020, 81: 405-414.
doi: 10.1016/j.jiec.2019.09.031
[17] SIBNATH K, ANUTOSH C. Activated carbon (type Maxsorb-III) and MIL-101(Cr) metal organic framework based composite adsorbent for higher CH4 storage and CO2 capture[J]. Chemical Engineering Journal, 2018, 334: 780-788.
doi: 10.1016/j.cej.2017.10.080
[18] 袁彬钦. 常温合成的MIL-100(Fe)的吸附性能和新型TED@Cu-BTC水稳定性增强机理[D]. 广州: 华南理工大学, 2019:30.
YUAN Binqin. Room temperature synthesis of MIL-100(Fe) and its adsorption performances and enhanced water stability of TED@Cu-BTC[D]. Guangzhou: South China University of Technology, 2019: 30.
[19] MOHAMMADIFARD Z, SABOORI R, MIRBAGHERI N S, et al. Heterogeneous photo-Fenton degradation of formaldehyde using MIL-100(Fe) under visible light irradiation[J]. Environmental Pollution, 2019, 251(8): 783-791.
doi: 10.1016/j.envpol.2019.04.143
[20] FAN X W, HU H X, QIN J Q, et al. Mechanism study on NO removal over the CQDs@MIL-100(Fe) composite photocatalyst[J]. Environmental Techno-logy & Innovation, 2021. DOI: org/10.1016/j.eti.2021.101809.
doi: org/10.1016/j.eti.2021.101809
[1] ZHANG Yaning, ZHANG Hui, SONG Yueyue, LI Wenming, LI Wenjun, YAO Jiale. Preparation of discarded mask-based ZIF-8/Ag/TiO2 composite and its photocatalytic property for dye degradation [J]. Journal of Textile Research, 2022, 43(07): 111-120.
[2] GAO Luxi, LÜ Xuechuan, ZHANG Chi, SONG Hanlin, GAO Xiaohan. Synthesis and decolorizing performance of modified flocculant for treating dyeing wastewater [J]. Journal of Textile Research, 2022, 43(07): 121-128.
[3] XIE Mengyu, HU Xiaolin, LI Xing, QU Jian'gang. Fabrication and interfacial evaporation properties of reduced graphene oxide/viscose multi-layer composite [J]. Journal of Textile Research, 2022, 43(04): 117-123.
[4] YU Fan, ZHENG Tao, TANG Tao, JIN Mengting, ZHU Hailin, YU Bin. Preparation of nonwoven composites based on metal-organic frame compounds and removal of hexavalent chromium from wastewater [J]. Journal of Textile Research, 2022, 43(03): 139-145.
[5] DENG Yang, SHI Xianbing, WANG Tao, LIU Liwei, HAN Zhenbang. Preparation and performance of modified polyacrylonitrile fibers photocatalyst with MIL-53(Fe) [J]. Journal of Textile Research, 2022, 43(03): 58-63.
[6] WEI Na'na, LIU Die, MA Zheng, JIAO Chenlu. Adsorption performance of cellulose/chitosan magnetic aerogel prepared by freeze-thawing method [J]. Journal of Textile Research, 2022, 43(02): 53-60.
[7] ZHANG Mengdi, ZHANG Wei, YAO Jiming. Application of natural clay minerals in electrocoagulation of indigo dyeing wastewater [J]. Journal of Textile Research, 2022, 43(02): 196-201.
[8] SHI Minhui, LI Bingrui, WANG Ting, WU Liguang. Mechanism and performance of TiO2 composite photocatalysts for photo-degradation of methyl-orange in highly saline wastewater [J]. Journal of Textile Research, 2021, 42(12): 103-110.
[9] LI Qing, CHEN Linghui, LI Dan, WU Zhiqiang, ZHU Wei, FAN Zenglu. Research progress in photocatalytic degradation of dyes using metal-organic frameworks [J]. Journal of Textile Research, 2021, 42(12): 188-195.
[10] LAI Xing, WANG Chun, XIAO Changfa, WANG Liming, XIN Binjie. Progress in preparation and application of aromatic polyamide separation membrane [J]. Journal of Textile Research, 2021, 42(10): 172-179.
[11] CHEN Yali, ZHAO Guomeng, REN Lipei, PAN Luqi, CHEN Bei, XIAO Xingfang, XU Weilin. Preparation and performance of aramid fabric-based interfacial photothermal evaporation materials [J]. Journal of Textile Research, 2021, 42(08): 115-121.
[12] LIU Suo, WU Dingsheng, LI Man, ZHAO Lingling, FENG Quan. Preparation of spunlaced viscose/polyaniline composite fiber membrane and its adsorption performance [J]. Journal of Textile Research, 2021, 42(08): 122-127.
[13] ZHANG Yuhan, SHEN Guodong, FAN Wei, SUN Runjun. Preparation of aramid fiber supported BiOBr composite materials and its photocatalytic degradation of dyeing wastewater [J]. Journal of Textile Research, 2021, 42(08): 128-134.
[14] ZHANG Tingting, XU Kexin, JIN Mengtian, GE Shijie, GAO Guohong, CAI Yixiao, WANG Huaping. Recent progress in preparation of cellulose-based organic-inorganic photocatalysts nanohybrids and it's application in water treatment [J]. Journal of Textile Research, 2021, 42(07): 175-183.
[15] CHEN Junliang, WU Jing, WANG Huaping, YANG Jianping. Research prospect of fibrous microplastics removal in aquatic environment [J]. Journal of Textile Research, 2021, 42(06): 18-25.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd