Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (07): 47-54.doi: 10.13475/j.fzxb.20210403408

• Textile Engineering • Previous Articles     Next Articles

Preparation of cotton/Ti3C2 conductive yarn and performance of pressure capacitance sensor

ZHAO Boyu, LI Luhong, CONG Honglian()   

  1. Engineering Research Center for Knitting Technology, Ministry of Education, Jiangnan University, Wuxi, Jiangsu 214122, China
  • Received:2021-04-12 Revised:2022-04-13 Online:2022-07-15 Published:2022-07-29
  • Contact: CONG Honglian E-mail:cong-wkrc@163.com

RichHTML

40

PDF (PC)

148

Abstract:

The paper aims to explore the combination effect of two-dimensional transition metal carbide/nitride(MXene) and natural fibers so as to devise capacitive flexible sensing fabric with a simplified preparation process by knitting. In the experiment, a new two-dimensional transition metal carbide Ti3C2 was used as the conductive material, and cotton yarn as matrix fiber to achieve the continuous preparation of conductive yarns. A cross structure capacitive pressure sensor was designed with a flat-knitting spacer fabric as dielectric layer and conductive yarns as electrodes. The effects of treatment time on the micro morphology, bonding effect and electrical conductivity of the yarns were studied, and the mechanical properties and capacitance characteristics of the pressure sensor were analyzed. The experimental results show that the conductivity of the composite yarn of Ti3C2 material and cotton yarn reach 0.872 S/cm. The prepared sensor has good compression recovery, and remarkable capacitance characteristics. The highest sensitivity is 0.028 kPa-1, the response time is less than 150 ms, demonstrating durability and stability of the sensor after 200 compression cycles.

Key words: two-dimensional transition metal carbide, conductive yarn, flat-knitted spacer fabric, capacitive sensor, flexible sensor

CLC Number: 

  • TS184.1

Fig.1

Preparation process of composite conductive yarn"

Fig.2

Knitting diagram of spacing structure"

Fig.3

Image of cross capacitor structure"

Fig.4

Compression test principle diagram of capacitive sensor"

Fig.5

SEM images of cotton and conductive yarns (×1 000). (a) Untreated cotton yarn;(b) Yarn treated for 1 min; (c) Yarn treated for 5 min;(d) Yarn treated for 10 min; (e) Yarn treated for 20 min;(f) Yarn treated for 30 min"

Fig.6

Effect of treatment time on weight gain rate of composite conductive yarn"

Fig.7

FT-IR spectra of Ti3C2, cotton and Ti3C2-CY yarns"

Fig.8

XRD patterns of Ti3C2, cotton and Ti3C2-CY yarns"

Fig.9

Effect of treatment time on resistance of conductive yarn"

Fig.10

Effect of treatment time on retention rate of electrical conductivity of conductive yarn"

Fig.11

Compression-recovery properties of fabric under different pressures"

Fig.12

Compression-recovery properties of fabric at 200 cycles strain"

Fig.13

Stress-capacitance variation characteristics of pressure capacitance sensor"

Fig.14

Response time of pressure capacitance sensors"

Fig.15

Capacitance behavior of sensor for loading and unloading of various pressures"

[1] 王栋, 卿星, 蒋海青, 等. 纤维材料与可穿戴技术的融合与创新[J]. 纺织学报, 2018, 39(5): 150-154.
WANG Dong, QING Xing, JIANG Haiqing, et al. Integration and innovation of fiber materials and wearable technology[J]. Journal of Textile Research, 2018, 39(5): 150-154.
[2] LI Y H, ZHOU B, ZHENG G Q, et al. Continuously prepared highly conductive and stretchable SWNT/MWNT synergistically composited electrospun thermoplastic polyurethane yarns for wearable sensing[J]. Journal of Materials Chemistry C, 2018, 6(9): 2258-2269.
doi: 10.1039/C7TC04959E
[3] 田明伟, 李增庆, 卢韵静, 等. 纺织基柔性力学传感器研究进展[J]. 纺织学报, 2018, 39(5): 170-176.
TIAN Mingwei, LI Zengqing, LU Yunjing, et al. Recent progress of textile-based flexible mechanical sensors[J]. Journal of Textile Research, 2018, 39(5): 170-176.
[4] 杨晨啸, 李鹂. 柔性智能纺织品与功能纤维的融合[J]. 纺织学报, 2018, 39(5): 160-169.
YANG Chenxiao, LI Li. Integration of soft intelligent textile and functional fiber[J]. Journal of Textile Research, 2018, 39(5): 160-169.
[5] ZHANG X, XUE M, YANG X, et al. Preparation and tribological properties of Ti3C2(OH)2 nanosheets as additives in base oil[J]. RSC Advances, 2014, 5(4): 56-63.
[6] 张建峰, 曹惠杨, 王红兵. 新型二维材料 MXene 的研究进展[J]. 无机材料学报, 2017, 32(6): 561-570.
ZHANG Jianfeng, CAO Huiyang, WANG Hongbing. Research progress of novel two-dimensional material MXene[J]. Journal of Inorganic Materials, 2017, 32(6): 561-570.
doi: 10.15541/jim20160479
[7] CHEN L, LIU Y, ZHAO Y, et al. Graphene-based fibers for supercapacitor applications[J]. Nanotechnology, 2016, 27: 1-19.
[8] UZUN S, SEYEDIN S, STOLTZFUS A L, et al. Knittable and washable multifunctional MXene-coated cellulose yarns[J]. Advanced Functional Materials, 2019, 29(45): 1-13.
[9] 张恒宇, 张宪胜, 肖红, 等. 二维碳化物在柔性电磁吸波领域的研究进展[J]. 纺织学报, 2020, 41(3): 182-187.
ZHANG Hengyu, ZHANG Xiansheng, XIAO Hong, et al. Research progress of two-dimensional carbide in field of flexible electromagnetic absorbing[J]. Journal of Textile Research, 2020, 41(3): 182-187.
doi: 10.1177/004051757104100216
[10] HU M M, ZHANG H, HU T, et al. Emerging 2D MXenes for supercapacitors: status, challenges and prospects[J]. Chemical Society Reviews, 2020, 49(18): 6666-6693.
doi: 10.1039/D0CS00175A
[11] VAGHASIYA J V, MAYORGA-MARTINEZ C C, VYSKOCIL J, et al. Integrated biomonitoring sensing with wearable asymmetric supercapacitors based on Ti3C2 MXene and 1T-phase WS2 nanosheets[J]. Advanced Functional Materials, 2020, 30(39): 1-10.
[12] 党阿磊, 方成林, 赵曌, 等. 新型二维纳米材料MXene的制备及在储能领域的应用进展[J]. 材料工程, 2020, 48(4): 1-14.
DANG Alei, FANG Chenglin, ZHAO Zhao, et al. Preparation of a new two-dimensional nanomaterial MXene and its application progress in energy storage[J]. Journal of Materials Engineering, 2020, 48(4): 1-14.
[13] SEYEDIN S, UZUN S, LEVITT A, et al. MXene composite and coaxial fibers with high stretchability and conductivity for wearable strain sensing textiles[J]. Advanced Functional Materials, 2020, 30(12): 1-11.
[14] 杨以娜, 王冉冉, 孙静. MXenes在柔性力敏传感器中的应用研究进展[J]. 无机材料学报, 2020, 35(1): 8-18.
YANG Yina, WANG Ranran, SUN Jing. MXenes in flexible force sensitive sensors: a review[J]. Journal of Inorganic Materials, 2020, 35(1): 8-18.
[15] PARK T H, YU S, KOO M, et al. Shape-adaptable 2D titanium carbide (MXene) heater[J]. ACS Nano, 2019, 13(6): 6835-6844.
doi: 10.1021/acsnano.9b01602
[16] ZHAO B Y, CONG H L, DONG Z J. Highly stretchable and sensitive strain sensor based on Ti3C2-coated electrospinning TPU film for human motion detection[J]. Smart Materials and Structures, 2021, 30(9): 1-9.
[17] 李一飞, 郑敏, 常朱宁子, 等. 二维过渡金属碳化物(Ti3C2Tx)对棉针织物的功能整理及其性能分析[J]. 纺织学报, 2021, 42(6): 120-127.
LI Yifei, ZHENG Min, CHANG Zhuningzi, et al. Cotton knitted fabrics treated with two-dimensional transitional metal carbide Ti3C2Tx and property analysis[J]. Journal of Textile Research, 2021, 42(6): 120-127.
[18] 张浩, 刘影. 基于FTIR与XRD的改性脱硫灰取代部分炭黑制备复合橡胶的补强机理研究[J]. 光谱学与光谱分析, 2019 (7): 2067-2072.
ZHANG Hao, LIU Ying. Study on reinforcement mechanism of composite rubber using modified desulfurization ash replacing partial carbon black by FTIR and XRD[J]. Spectroscopy and Spectral Analysis, 2019 (7): 2067-2072.
[19] 于伟东. 纺织材料学[M]. 北京: 中国纺织出版社, 2006: 209.
YU Weidong. Textile materials[M]. Beijing: China Textile & Apparel Press, 2006: 209.
[20] 洪剑寒, 潘志娟, 张小英, 等. 应用原位聚合法的PTT/毛/聚苯胺复合导电纱制备与性能[J]. 纺织学报, 2014, 35(10): 30-35.
HONG Jianhan, PAN Zhijuan, ZHANG Xiaoying, et al. Preparation and properties of PTT/wool/PANI composite conductive yarns based on in-situ polymerization[J]. Journal of Textile Research, 2014, 35(10): 30-35.
[21] ASAYESH A, AMINI M. The effect of fabric structure on the compression behavior of weft-knitted spacer fabrics for cushioning applications[J]. Journal of The Textile Institute, 2020, 112 (10): 1568-1579.
doi: 10.1080/00405000.2020.1829330
[1] RONG Kai, FAN Wei, WANG Qi, ZHANG Cong, YU Yang. Application progress of two-dimensional transitional metal carbon/nitrogen compound composite in field of intelligent wearable textiles [J]. Journal of Textile Research, 2021, 42(09): 10-16.
[2] XIAO Yuan, LI Hongying, LI Qian, ZHANG Wei, YANG Pengcheng. Preparation of flexible sensor with composite dielectric layer of cotton fabric/polydimethylsiloxane [J]. Journal of Textile Research, 2021, 42(05): 79-83.
[3] ZHANG Lin, LI Zhicheng, ZHENG Qinyuan, DONG Jun, ZHANG Yin. Preparation and performance of flexible and anisotropic strain sensor based on electrospinning [J]. Journal of Textile Research, 2021, 42(05): 38-45.
[4] ZHANG Yike, JIA Fan, GUI Cheng, JIN Rui, LI Rong. Preparation and piezoelectric properties of carbon nanotubes/polyvinylidene fluoride nanofiber membrane [J]. Journal of Textile Research, 2021, 42(03): 44-49.
[5] YU Jia, XIN Binjie, ZHUO Tingting, ZHOU Xi. Preparation and characterization of Cu/polypyrrole-coated wool fabrics for high electrical conductivity [J]. Journal of Textile Research, 2021, 42(01): 112-117.
[6] ZHANG Yike, JIA Fan, GUI Cheng, JIN Rui, LI Rong. Preparation and performance of flexible sensor made from polyvinylidene fluoride/FeCl3 composite fibrous membranes [J]. Journal of Textile Research, 2020, 41(12): 13-20.
[7] HU Chengye, MIAO Runwu, HAN Xiao, HONG Jianhan, GIL Ignacio. Effect of polyvinyl alcohol on durability of polyaniline conductive layer on poly(p-phenylene terephthamide) yarn surface [J]. Journal of Textile Research, 2020, 41(04): 91-97.
[8] ZHANG Hengyu, ZHANG Xiansheng, XIAO Hong, SHI Meiwu. Research progress of two-dimensional carbide in field of flexible electromagnetic absorbing [J]. Journal of Textile Research, 2020, 41(03): 182-187.
[9] ZHAO Yaru, XIAO Hong, CHEN Jianying. Elastic and electrical properties of stainless steel fiber/cotton blended spandex wrap yarn [J]. Journal of Textile Research, 2020, 41(03): 45-50.
[10] SUN Wan, MIAO Xuhong, WANG Xiaolei, JIANG Gaoming. Characteristics of capacitive pressure sensor based on warp-knitted spacer fabric [J]. Journal of Textile Research, 2019, 40(02): 94-99.
[11] . Research progress of wearable technology in textiles and apparels [J]. Journal of Textile Research, 2018, 39(12): 131-138.
[12] . Recent progress of textile-based flexible mechanical sensors [J]. JOURNAL OF TEXTILE RESEARCH, 2018, 39(05): 170-176.
[13] . Compression property of curved three-dimensional flat-knitted spacer fabric composites [J]. JOURNAL OF TEXTILE RESEARCH, 2018, 39(01): 62-65.
[14] . Structures and electrical properties of weft-knitted flexible sensors [J]. JOURNAL OF TEXTILE RESEARCH, 2016, 37(06): 48-53.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 33 -34 .
[2] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 35 -36 .
[3] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 107 .
[4] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 109 -620 .
[5] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(01): 1 -9 .
[6] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 101 -102 .
[7] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 103 -104 .
[8] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 105 -107 .
[9] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 108 -110 .
[10] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 111 -113 .
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd