Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (09): 143-148.doi: 10.13475/j.fzxb.20210405906

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Comparison of test methods for permethrin content in polyamide fabrics

CHENG Lüzhu1, WANG Zongqian1(), SHENG Hongmei2, ZHONG Hui2, XIA Liping3   

  1. 1. School of Textiles and Garment, Anhui Polytechnic University, Wuhu, Anhui 241000, China
    2. Xuancheng K & O Textile Co., Ltd., Xuancheng, Anhui 242000, China
    3. Chemical Test Center of Transfar Zhilian Co., Ltd., Hangzhou, Zhejiang 311215, China
  • Received:2021-04-21 Revised:2022-06-20 Online:2022-09-15 Published:2022-09-26
  • Contact: WANG Zongqian E-mail:wzqian@ahpu.edu.cn

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Abstract:

In order to study the characteristics of different methods for testing and characterization of permethrin content in textiles, and to explore rapid test methods, permethrin mosquito repellent was used to finish polyamide fabrics by spraying. The polyamide fabrics treated with different concentrations of permethrin were characterized by digital microsystem, scanning electron microscope, Fourier infrared spectrometer, gas chromatography, X-ray photoelectron spectrometer and ultraviolet (UV)/visible/near infrared spectrometer. The results show that the use of optical, scanning electron microscope images and infrared spectroscopy is able to quickly characterize the surface characteristics of polyamide fabrics after permethrin treatment, but it is difficult to achieve accurate quantitative analysis. Gas chromatography and X-ray photoelectron spectroscopy can be used for quantitative analysis, but they are time-consuming with high cost. UV absorption spectrum can meet the rapid quantitative analysis of permethrin content in polyamide fabric, and the test results have a high agreement with the test results of X-ray photoelectron spectroscopy, with a fitting coefficient of 0.985.

Key words: permethrin, polyamide fabric, ultraviolet absorption spectrum, X-ray photoelectron spectroscopy, quantitative analysis

CLC Number: 

  • TS195.5

Fig.1

Schematic diagram of permethrin finished polyamide fabric by spray method"

Fig.2

Optical images of polyamide fabric(×500). (a) Original polyamide fabric; (b) 1 g/L; (c) 2 g/L; (d)3 g/L; (e)4 g/L; (f)5 g/L"

Fig.3

SEM images of polyamide fabric. (a) Original polyamide fabric; (b) 1 g/L; (c) 2 g/L; (d) 3 g/L; (e)4 g/L; (f) 5 g/L"

Fig.4

Infrared spectra of polyamide fabric"

Fig.5

Analysis of permethrin peak area and its content in different polyamide fabrics"

Fig.6

X-ray photoelectron spectoscopy of polyamide fabric"

Fig.7

Percentage of chlorine atoms on surface of permethrin finished polyamide fabric"

Fig.8

UV absorption spectra of polyamide fabric finished with different concentrations of permethrin"

Fig.9

Fitting curve of chlorine atom content and UV absorbance value of finished polyamide fabric"

Tab.1

Comparison of test results of permethrin content by different test methods"

测试方法 原理 定性 定量 方差/% 单样测试耗时 单次测试所需样品 测试成本
图像法 表面形貌 × ? — 短 极少 高
红外光谱法 红外特征吸收 √ ? — 短 少 适中
气相色谱法 特征吸收和峰面积 √ √ 1.14 长 多 高
X射线光电子能谱法 氯元素特征吸收 √ √ 2.07 长 少 高
紫外光谱法 特征吸收 √ √ 2.25 短 少,对样品无损伤 低
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