Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (08): 132-139.doi: 10.13475/j.fzxb.20210600808

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Adsorption and decolorization of Reactive Blue 4 by polyurethane foam-immobilized biosystem

YANG Wenbo, ZHANG Aojie, LIU Youyan, LI Qingyun()   

  1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, China
  • Received:2021-06-01 Revised:2022-05-27 Online:2022-08-15 Published:2022-08-24
  • Contact: LI Qingyun E-mail:qyli@gxu.edu.cn

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Abstract:

In order to construct a long-time effect of decolorization system, the biological adsorbent of Aspergillus flavus A5p1 was immobilized on the polyurethane foam (PUF) to decolorize the anthraquinone dye of Reactive Blue 4 (RB4). The adsorption kinetics, different concentrations of RB4, different concentrations of NaCl and repeated batches decolorization by Aspergillus flavus A5p1 before and after immobilization were investigated and compared. Results showed that the decolorization of RB4 was significantly enhanced after Aspergillus flavus A5p1 immobilization. Approximately 77.8％ adsorption of the 200 mg/L RB4 was achieved by the PUF–immobilized biological system within 20 min, while 62.8％ was achieved by the free cell system within 90 min. The biological decolorization process of RB4 could be described by the kinetics model of intraparticle diffusion. It was found that the PUF–immobilized biosystem adsorbed around 2.5 times more RB4 than that of the free cell system when RB4 concentration was 2 000 mg/L. Moreover, the PUF–immobilized biosystem exhibited good tolerance to the salinity of 50 g/L NaCl. In the repeated batches experiment, the decolorization efficiency of PUF–immobilized biological system could be maintained at 89％ after 7 batches, whereas the free cell system was decreased to 74.3％. These results show the effectiveness and reliability of the PUF–immobilized biosystem.

Key words: biological decolorization, Aspergillus flavus, anthraquinone dye, reactive dye, polyurethane, adsorption

CLC Number: 

  • TQ610.9

Fig.1

Adsorption isotherm of RB4 by PUF"

Tab.1

Fitting parameters of adsorption isotherm model"

Langmuir Freundlich
KL/(L·mg–1) Qm/(mg·g–1) R2 KF/(L·g–1) n R2
0.010 3.96 0.973 0.425 3.03 0.912

Fig.2

Adsorption time curve of RB4"

Fig.3

Intraparticle diffusion model of RB4"

Tab.2

Fitting parameters of intraparticle diffusion model for RB4 adsorption"

细胞种类 第1阶段 第2阶段 第3阶段
Ki1/
(mg·(g·min1/2)–1)		 Ci1 R2 Ki2/
(mg·(g·min1/2)–1)		 Ci2 R2 Ki3/
(mg·(g·min1/2)–1)		 Ci3 R2
PUF–固定化细胞 60.7 –132.1 0.994 0.901 61.5 0.867 0.041 68.1 0.336
游离细胞 15.3 –30.7 0.995 5.094 6.66 0.975 0.070 48.6 0.724

Fig.4

Decolorization of RB4 at different concentrations by biological systems"

Fig.5

Decolorization of RB4 by biological systems at different concentrations of NaCl"

Fig.6

Repeated batches decolorization of RB4 by biological systems"

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