Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (07): 104-110.doi: 10.13475/j.fzxb.20210603407

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Application of antibacterial and antibacterial adhesion finishing agents in cotton fabric modification

YANG Yao, CHENG Wei, YU Yuanyuan(), WANG Qiang, WANG Ping, ZHOU Man   

  1. Key Laboratory of Eco-Textiles (Jiangnan University ), Ministry of Education, Wuxi, Jiangsu 214122, China
  • Received:2021-06-10 Revised:2022-04-14 Online:2022-07-15 Published:2022-07-29
  • Contact: YU Yuanyuan E-mail:jnyyy@jiangnan.edu.cn

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Abstract:

In order to prepare cotton fabrics with both antibacterial and antibacterial adhesion functions, free radical polymerization of [2-(methacryloyloxy)ethyl] dimethyl-(3-sulfopropyl) (SBMA) or 2-(dimethylamino) ethyl methacrylate (DMAEMA) with 3-(trimethoxysilyl)propyl methacry-late (TMSPMA) was produced utilizing a light-controlled glucose oxidase system to obtain antibacterial adhesive polymer P(TMSPMA-co-SBMA) or antibacterial polymer P(TMSPMA-co-DMAEMA). The two polymers were individually or jointly applied to the cotton fabric using the impregnation-baking method. The chemical structure, element composition, antibacterial properties and anti-dead/live bacteria adhesion properties of the finished fabrics were measured. The results show successful adhesion of two polymers on the cotton fabric. The antibacterial agent finished cotton fabric has a bacteriostatic rate of 99.9% with many dead bacteria on the surface, and the antibacterial adhesion agent finished cotton fabric shows a bacteriostatic rate of more than 85% but with less dead/live bacteria adhering to the fabric surface. The antibacterial and antibacterial adhesion rates of cotton fabrics exceed 98% and 81%, and the surface of the fabric can prevent dead bacteria from adhering.

Key words: glucose oxidase, enzymatic polymerization, antibacterial agent, antibacterial adhesive agent, cotton fabric, antibacterial textiles

CLC Number: 

  • TS195.5

Fig.1

Infrared spectra of unmodified cotton fabric and different finished cotton fabrics. (a) Unmodified cotton fabric, TMSPMA finishing cotton and anti-bacterial finished cotton fabrics;(b) Unmodified cotton fabric, TMSPMA finishing cotton and antibacterial finished cotton fabrics"

Tab.1

Proportion of various elements on surface of different cotton fabrics"

样品 质量分数/%
C N O Si S
未改性棉织物 46.41 0.36 51.98 0.04 1.21
4# 46.15 2.33 48.11 0.60 2.82
8# 45.82 0.54 52.47 0.39 0.79
10# 45.58 2.08 50.14 0.56 1.64

Fig.2

SEM images of different cotton fabrics(×3 000).(a) Unmodified cotton fabric; (b)P(TMSPMA-co-SBMA) finishing cotton fabric; (c)P(TMSPMA-co-DMAEMA) finishing cotton fabric"

Fig.3

Test chart of inhibition zone of different cotton fabrics on S.aureus (a) and E.coli (b)"

Tab.2

Bacteriostatic rate of different modified fabrics against S.aureus and E.coli"

样品类别 编号 抑菌率/%
对金黄色葡萄球菌 对大肠杆菌
未改性棉织物 — 0 0
P(TMSPMA-co-SBMA)
整理棉织物		 3# 88.33 85.00
4# 87.30 89.75
P(TMSPMA-co-DMAEMA)
整理棉织物		 5# 95.07 99.56
6# 99.98 99.79
7# 99.94 99.97
8# 99.99 99.90

Tab.3

Adhesion rate of anti live bacteria of modified fabrics with different feed ratios to S.aureus and E.coli"

样品类别 编号 防活细菌黏附率/%
对金黄色葡萄球菌 对大肠杆菌
未改性棉织物 0 0
P(TMSPMA-co-DMAEMA)
整理棉织物		 7# 96.06 94.87
8# 98.03 91.81
P(TMSPMA-co-SBMA)
整理棉织物		 1# 80.31 79.26
2# 94.48 65.08
3# 91.34 94.39
4# 97.63 93.36

Tab.4

Adhesion rate of anti live bacteria and inhibition rate of different cotton fabrics to S.aureus and E.coli"

样品种类 防活细菌黏附率/% 抑菌率/%
对金黄色葡萄球菌 对大肠杆菌 对金黄色葡萄球菌 对大肠杆菌
未改性棉织物 0 0 0 0
9# 33.67 44.67 99.78 99.92
10# 41.70 68.18 99.15 99.70
11# 81.90 81.06 98.72 99.60

Fig.4

Fluorescent staining patterns of S.aureus (a) and E.coli (b) on different fabrics"

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