Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (05): 86-91.doi: 10.13475/j.fzxb.20210606406

• Textile Engineering • Previous Articles     Next Articles

Electrothermal properties of functionalization carbon nanotube composite films and films twisted yarns

YAO Mingyuan1, LIU Ningjuan1, WANG Jianing1, XU Fujun2, LIU Wei1()   

  1. 1. School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China
    2. College of Textiles, Donghua University, Shanghai 201620, China
  • Received:2021-06-23 Revised:2021-10-13 Online:2022-05-15 Published:2022-05-30
  • Contact: LIU Wei E-mail:wliu@sues.edu.cn

Abstract:

Carbon nanotubes(CNT) have excellent electrical properties. In order to better applied it's performance to electrothermal fabric, the CNT films twisted yarn was prepared by twisting CNT film. The electrothermal properties of the yarn was further optimized by pre-spraying poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS)solution. The influence of the solution concentration on the structure and conductivity of CNT film and its films twisted yarns were studied, as well as the temperature changes of CNT film and its films twisted yarns under different applied voltage. As the PEDOT:PSS mass fraction increased from 0.01% to 1.4%, the conductivity of the sprayed CNT film gradually increased from 344.2 S/cm to 668.9 S/cm. When the electric voltage was applied across it, the spinning temperature of PC films twisted yarns can reach 214 ℃ with a response time of 5 s, which is 1.6 times of its untwisted films. That's indicates the good application potential and development value of the PEDOT:PSS/CNT film twisted yarn.

Key words: carbon nanotubes film, film twisted yarns, poly(3, 4-ethylenedioxythiophene)/poly(styrenesulfonate), electrothermal property, electrothermal fabric

CLC Number: 

  • TS101.3

Fig.1

FESEM images of CNT film and PC composite film with different contents"

Fig.2

FESEM image of CNT film twisted yarn and 0.07% PC film twisted yarn. (a) CNT film twisted yarn; (b) PC film twisted yarn; (c) Flexibility of PC film twisted yarn"

Fig.3

Conductivity of PC films with different concentrations and 0.07% PC film twisted yarn with different twist. (a) PC films with different concentration;(b) PC film twisted yarn with different Yarn twist"

Fig.4

Resistance change of CNT material under 10% tensile strain cyclic stretching and mechanical property of PC film twisted yarn.(a) PC films with different concentrations; (b) Stress-strain curve of PC film twisted yarn"

Fig.5

Curve temperature over time of CNT material under constant voltage. (a)CNT film;(b) 0.07% PC film;(c) 0.07% PC film twisted yarn"

Fig.6

Heating performance of CNT materials under increasing voltage. (a) Heating performance; (b) Relationship between temperature and voltage"

Fig.7

Heating performance of CNT materials under increasing/decreasing cycling voltage. (a) CNT film; (b) 0.07% PC film; (c) 0.07% PC-400 film twisted yarn"

Fig.8

Heating temperature of electric heating fabric changes with voltage"

[1] 白洁. 智能纺织品的分类及其应用[J]. 毛纺科技, 2019, 47(4): 79-83.
BAI Jie. Classification and application of intelligent texti-les[J]. Wool Textile Journal, 2019, 47(4): 79-83.
[2] 李萍, 蒋晓文. 智能电加热服的研究进展[J]. 棉纺织技术, 2019, 47(9): 79-84.
LI Ping, JIANG Xiaowen. Research progress of intelligent electric heating clothing[J]. Cotton Textile Technology, 2019, 47(9): 79-84.
[3] 钱江瑞, 蔡彦, 杨允出, 等. 热疗纺织品热性能测试评价及传热机制研究进展[J]. 现代纺织技术, 2020, 28(3): 41-47.
QIAN Jiangrui, CAI Yan, YANG Yunchu, et al. Research progress on thermal performance evaluation and heat transfer mechanism of hyperthermia textiles[J]. Advanced Textile Technology, 2020, 28(3): 41-47.
[4] IM H, JANG E Y, CHOI A, et al. Enhancement of heating performance of carbon nanotube sheet with granular metal[J]. Acs Appl Mater Inter, 2012, 4(5): 2338-2342.
doi: 10.1021/am300477u
[5] SHIN K Y, HONG J Y, LEE S, et al. High electrothermal performance of expanded graphite nanoplatelet-based patch heater[J]. J Mater Chem, 2015, 22(44): 23404-23410.
doi: 10.1039/c2jm34196d
[6] WAN N, SUN L T, DING S N, et al. Synthesis of graphene-CNT hybrids via joule heating: structural characterization and electrical transport[J]. Carbon, 2013(53): 260-268.
[7] DEVOLDER M F, TAWFICK S H, BAUGHMAN R H, et al. Carbon nanotubes: present and future commercial applications[J]. Science, 2013, 339(6119): 535-539.
doi: 10.1126/science.1222453
[8] 贾可, 刘玮, 刘宁娟, 等. 碳纳米管纱线及其复合纤维与纺织品的制备研究现状[J]. 产业用纺织品, 2020, 38(9): 5-12.
JIA Ke, LIU Wei, LIU Ningjuan, et al. Research status of preparation of carbon nanotube yarn and its composite fiber and textiles[J]. Technical Textiles, 2020, 38(9): 5-12.
[9] LIU P, LIU L, JIANG K, et al. Carbon nanotube film microheater on a polyethylene terephthalate substrate and its application in thermochromic displays[J]. Small, 2011, 7(6): 732-736.
doi: 10.1002/smll.201001662
[10] LUO Jie, LU Huifen, ZHANG Qichong, et al. Flexible carbon nanotube/polyurethane electrothermal films[J]. Carbon, 2016(110): 343-349.
[11] POST E R, ORTH M, RUSSO P R, et al. E-broidery: design and fabrication of textile-based computing[J]. IBM Systems Journal, 2000, 39(3): 840-860.
doi: 10.1147/sj.393.0840
[12] LI Y, SHANG Y, HE X, et al. Overtwisted, resolvable carbon nanotube yarn entanglement as strain sensors and rotational actuators[J]. ACS Nano, 2013, 7(9): 8128-8135.
doi: 10.1021/nn403400c
[13] SHANG Y, LI Y, HE X, et al. Highly twisted double-helix carbon nanotube yarns[J]. ACS Nano, 2013, 7(2):1446-1453.
doi: 10.1021/nn305209h
[14] YAN J, JEONG Y G. Highly elastic and transparent multiwalled carbon nanotube/polydimethylsiloxane bilayer films as electric heating materials[J]. Materials & Design, 2015, 36(86): 72-9.
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