Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (02): 162-170.doi: 10.13475/j.fzxb.20210606609

• Dyeing and Finshing & Chemicals • Previous Articles     Next Articles

Preparation of superhydrophobic polyester fabric modified by tea polyphenols for oil-water separation

XIE Ailing1,2, YUE Yuhan1,2, AI Xin1,2, WANG Yahui1,2, WANG Yirong1,2, CHEN Xinpeng1,2, CHEN Guoqiang1,2, XING Tieling1,2()   

  1. 1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215021, China
    2. Jiangsu Engineering Research Center of Textile Dyeing and Printing for Energy Conservation, Discharge Reduction and Cleaner Production(ERC), Suzhou, Jiangsu 215021, China
  • Received:2021-06-23 Revised:2021-12-01 Online:2022-02-15 Published:2022-03-15
  • Contact: XING Tieling E-mail:xingtieling@suda.edu.cn

RichHTML

14

PDF (PC)

63

Abstract:

In order to improve the durability of superhydrophobic fabrics, a polyester (PET) fabric was treated with strong adhesion substances including tea polyphenols (Tps), Hexadecyltrimethoxysilane (HDS) and FeSO4·7H2O. Surface morphology, chemical composition, superhydrophobic stability and oil-water separation performance of the prepared PET fabric were tested and characterized. The results show that when Tps is 2 g/L, HDS is 150 μL/L and FeSO4·7H2O is 6 g/L, the prepared PET fabric showed good superhydrophobic property with water contact angle of 163.1° and the scrolling angle of 3.5°. The treated fabric shows good stability under the conditions of water washing, mechanical wear, mechanical friction, UV irradiation, simulated seawater, acid-alkaline and organic reagents. In the cyclic test for oil-water separation, the separation efficiency remains above 95%. The preparation process of superhydrophobic PET fabric is simple and has good stability, which has broad application prospects in the field of oil-water separation.

Key words: polyester fabric, tea polyphenols, superhydrophobic property, hexadecyltrimethoxysilane, oil-water separation

CLC Number: 

  • TS193

Fig.1

Preparation schematic of superhydrophoboic PET fabric"

Tab.1

Surface element content of PET fabrics"

样品 表面元素含量/%
C N O Fe Si
原涤纶织物 68.34 0 31.66 0 0
HDS整理涤纶织物 79.28 0 15.11 0 5.61
Tps/Fe整理涤纶织物 72.96 1.19 24.65 1.20 0
Tps/HDS整理涤纶织物 75.64 0.78 16.46 0 7.12
Tps/Fe/HDS整理涤纶织物 76.67 0.65 15.02 0.80 6.86

Fig.2

WCA and SEM images (×10 000) of original PET (a), HDS PET(b), Tps/HDS PET(c), Tps/Fe PET (d), Tps/Fe/HDS PET(e), and WCA and SEM images (×50 000) of Tps/Fe/HDS PET (f)"

Fig.3

FT-IR spectra(a) and XPS wide spectra(b) of polyester fabrics"

Fig.4

C1s spectra of original PET(a) and Tps/Fe/HDS PET(b)"

Fig.5

Si2p spectra(a) and Fe2p spectra(b) of Tps/Fe/HDS PET fabric"

Tab.2

Mechanical properties of original PET and Tps/Fe/HDS PET fabrics"

织物 断裂强力/N 断裂伸长率/%
经向 纬向 经向 纬向
原涤纶
织物		 660.54±12.68 412.51±16.53 19.91±0.25 19.12±0.57
Tps/Fe/HDS整理涤纶织物 638.01±12.24 391.87±10.39 18.05±0.49 17.99±0.60

Fig.6

Thermogravimetric curve of original PET and Tps/Fe/HDS PET fabric"

Fig.7

Stability of Tps/Fe/HDS PET fabrics. (a) Washing resistance stability;(b) Abrasion resistance; (c) UV irradiation stability;(d) Simulated seawater stability;(e) pH stability ;(f)Organic solvents stability"

Fig.8

Self-cleaning and antifouling properties of PET fabric. (a) Self-cleaning property of original PET; (b)Self-cleaning property of Tps/Fe/HDS PET fabrics; (c)Wettability of liquid on surface of original PET; (d)Wetlability of liquid on surfose of Tps/Fe/HDS PET fabrics"

Fig.9

Photos of oil-water separation test. (a)Photos of Gravity driven oil-water separation test;(b) Photos of oil-water separation test of oil suction bag"

Fig.10

Oil-water separation performance. (a) Separation efficiency of superhydrophobic PET fabric under gravity drive for different organic reagents and adsorption capacity;(b) Separation efficiency test of n-hexane/water of oil absorption package"

[1] LI J, CHEN C F, YANG H, et al. Tea polyphenols regulate gut microbiota dysbiosis induced by antibiotic in mice[J]. Food Research International, 2021, 141(3): 110153.
doi: 10.1016/j.foodres.2021.110153
[2] AKHAVAN O, KALAEE M, ALAVI Z S, et al. Increasing the antioxidant activity of green tea polyphenols in the presence of iron for the reduction of graphene oxide[J]. Carbon, 2012, 50(8): 3015-3025.
doi: 10.1016/j.carbon.2012.02.087
[3] YI Z, CUI X X, CHEN G C, et al. Biocompatible, antioxidant nanoparticles prepared from natural renewable tea polyphenols and human hair keratins for cell protection and anti-inflammation[J]. ACS Biomaterials Science & Engineering, 2021, 7(3): 1046-1057.
[4] CHEN D, ZHU X, LLAVSKY J, et al. Polyphenols weaken pea protein gel by formation of large aggregates with diminished noncovalent interactions[J]. Biomacromolecules, 2021, 22(2): 1001-1014.
doi: 10.1021/acs.biomac.0c01753
[5] FAN Z. Interactions between starch and phenolic compound[J]. Trends in Food Science & Technology, 2015, 43(2): 129-143.
[6] OU J F, WANG F J, LI W, et al. Methyltrimethoxysilane as a multipurpose chemical for durable superhydrophobic cotton fabric[J]. Progress in Organic Coatings, 2020, 146:105700.
doi: 10.1016/j.porgcoat.2020.105700
[7] TUDU B K, SINHAMAHAPATRA A, KUMAR A. Surface modification of cotton fabric using tio2 nanoparticles for self-cleaning, oil-water separation, antistain, anti-water absorption, and antibacterial properties[J]. ACS Omega, 2020, 5(14): 7850-7860.
doi: 10.1021/acsomega.9b04067
[8] WU J J, LI H Q, LAI X J, et al. Conductive and superhydrophobic F-rGO@CNTs/chitosan aerogel for piezoresistive pressure sensor[J]. Chemical Engineering Journal, 2019, 386:123998.
doi: 10.1016/j.cej.2019.123998
[9] CHENG D S, ZHANG Y L, BAI X, et al. Mussel-inspired fabrication of superhydrophobic cotton fabric for oil/water separation and visible light photocatalytic[J]. Cellulose, 2020, 27(9): 5421-5433.
doi: 10.1007/s10570-020-03149-y
[10] 徐林, 任煜, 张红阳, 等. 涤纶织物表面TiO2/氟硅烷超疏水层构筑及其性能[J]. 纺织学报, 2019, 40(12): 86-92.
XU Lin, REN Yu, ZHANG Hongyang, et al. Construction and properties of superhydrophobic layer of titania/fluorosilane on polyester fabric surface[J]. Journal of Textile Research, 2019, 40(12): 86-92.
[11] GU H H, LI G Q, LI P P, et al. Superhydrophobic and breathable SiO2/polyurethane porous membrane for durable water repellent application and oil-water separation[J]. Applied Surface Science, 2019, 512:144837.
doi: 10.1016/j.apsusc.2019.144837
[12] 郝尚, 谢源, 翁佳丽, 等. 溶解刻蚀辅助构建棉织物超疏水表面[J]. 纺织学报, 2021, 42(2): 168-173,179.
HAO Shang, XIE Yuan, WENG Jiali, et al. Construction of superhydrophobic surface of cotton fabrics via dissolving etching[J]. Journal of Textile Research, 2021, 42(2): 168-173,179.
[13] ZHOU F, ZHANG Y F, ZHANG D S, et al. Fabrication of robust and self-healing superhydrophobic PET fabrics based on profiled fiber structure[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 609:125680.
doi: 10.1016/j.colsurfa.2020.125680
[14] LAMBERT J D, ELIAS R J. The antioxidant and pro-oxidant activities of green tea polyphenols: a role in cancer prevention[J]. Archives of Biochemistry & Biophysics, 2010, 501(1): 65-72.
[15] RYAN P, HYNES M J. The kinetics and mechanisms of the complex formation and antioxidant behaviour of the polyphenols EGCg and ECG with iron(III)[J]. Journal of Inorganic Biochemistry, 2007, 101(4): 585-593.
doi: 10.1016/j.jinorgbio.2006.12.001
[16] 王旭捷, 陈春凤, 杨慧, 等. 茶多酚金属络合物的制备及其抑菌活性[J]. 食品工业科技, 2020, 41(24): 113-117, 124.
WANG Xujie, CHEN Chunfeng, YANG Hui, et al. Preparation and bacteriostatic activity of tea polyphenol-metal complexes[J]. Science and Technology of Food Industry, 2020, 41(24): 113-117, 124.
[17] RAHMAN M A, LEE S, PARK C H. A facile and non-toxic approach to develop superhydrophobic cotton fabric using octadecylamine and hexadecyltrimethoxysilane in aqueous system[J]. Fibers and Polymers, 2021, 22(1): 131-140.
doi: 10.1007/s12221-021-9645-5
[18] ZHANG Z Y, LIU H, QIAO W C. Reduced graphene-based superhydrophobic sponges modified by hexadecyltrimethoxysilane for oil adsorption[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 589:124433.
doi: 10.1016/j.colsurfa.2020.124433
[19] LIU X L, GU Y C, MI T F, et al. Dip-coating approach to fabricate durable PDMS/STA/SiO2superhydrophobic polyester fabrics[J]. Coatings, 2021, 11(3): 326.
doi: 10.3390/coatings11030326
[20] FAN L, LI B C, ZHANG J P. Antibioadhesive superhydrophobic syringe needles inspired by mussels and lotus leafs[J]. Advanced Materials Interfaces, 2015, 2(8): 1500019.
doi: 10.1002/admi.201500019
[21] ZHANG C, OU Y, LEI W X, et al. CuSO4/H2O2‐induced rapid deposition of polydopamine coatings with high uniformity and enhanced stability[J]. Angewandte Chemie International Edition, 2016, 55(9): 3054-3057.
doi: 10.1002/anie.201510724
[22] FU S D, ZHOU H, WANG H X, et al. Magnet-responsive, superhydrophobic fabrics from waterborne, fluoride-free coatings[J]. Rsc Advances, 2018, 8(2): 717-723.
doi: 10.1039/C7RA10941E
[1] YANG Tengxiang, SHEN Guodong, QIAN Lijiang, HU Huajun, MAO Xue, SUN Runjun. External electric field polarized Ag-BaTiO3/polyester fabric and its photocatalytic properties [J]. Journal of Textile Research, 2022, 43(02): 189-195.
[2] GAO Qiang, WANG Xiao, GUO Yajie, CHEN Ru, WEI Ju. Preparation and performance of cotton based Ti3C2Tx oil-water separation membrane [J]. Journal of Textile Research, 2022, 43(01): 172-177.
[3] ZHU Lanfang, BAI Jie, ZHOU Yincheng, HOU Chengwei. Effect of ultrasonic treatment on 4,4'-diaminodiphenylmethane in polyurethane coating of polyester fabric [J]. Journal of Textile Research, 2021, 42(11): 124-128.
[4] PU Dandan, FU Yaqin. Preparation and sound insulation performance of polyester fabric/polyvinyl chloride-hollow glass microspheres composites [J]. Journal of Textile Research, 2021, 42(11): 77-83.
[5] LI Weibin, ZHANG Cheng, LIU Jun. Preparation of superhydrophobic coated cotton fabrics for oil-water separation [J]. Journal of Textile Research, 2021, 42(08): 109-114.
[6] YU Yucong, SHI Xiaolong, LIU Lin, YAO Juming. Recent progress in super wettable textiles for oil-water separation [J]. Journal of Textile Research, 2020, 41(11): 189-196.
[7] LI Liang, LIU Jingfang, HU Zedong, GENG Changjun, LIU Rangtong. Graphene oxide loading on polyester fabrics and antistatic properties [J]. Journal of Textile Research, 2020, 41(09): 102-107.
[8] LIU Guojin, HAN Pengshuai, CHAI Liqin, WU Yu, LI Hui, GAO Yafang, ZHOU Lan. Preparation and stability of self-crosslinking P(St-NMA) photonic crystals with structural colors on polyester fabrics [J]. Journal of Textile Research, 2020, 41(05): 99-104.
[9] WANG Xiaofei, WAN Ailan. Preparation of polypyrrole/silver conductive polyester fabric by ultraviolet exposure [J]. Journal of Textile Research, 2020, 41(04): 112-116.
[10] DING Fang, REN Xuehong. Flame-retardant finishing of polyester fabrics by grafting phosphorus-nitrogen compounds [J]. Journal of Textile Research, 2020, 41(03): 100-105.
[11] CHEN Ying, ZHOU Shuang, WEI Tianjing, FANG Haoxia, LI Yufei. Preparation and properties of polypyrrole composite fabric by soft template process [J]. Journal of Textile Research, 2019, 40(12): 93-97.
[12] XU Lin, REN Yu, ZHANG Hongyang, WU Shuangquan, LI Ya, DING Zhirong, JIANG Wenwen, XU Sijun, ZANG Chuanfeng. Construction and properties of superhydrophobic layer of titania/fluorosilane on polyester fabric surface [J]. Journal of Textile Research, 2019, 40(12): 86-92.
[13] DAI Yue, ZHANG Ruiping, WANG Qiuping, HU Ya'nan, ZHANG Xianguo. Deodorizing effect of polyester fabric treated by citric acid/β-cyclodextrin [J]. Journal of Textile Research, 2019, 40(12): 104-108.
[14] ZHU Jinming, QIAN Jianhua, SUN Liying, LI Zhengping, PENG Huimin. Properties of functionalized composite polyester fabric prepared from silver nanowires of high aspect ratio [J]. Journal of Textile Research, 2019, 40(11): 113-118.
[15] WANG Fanghe, WANG Rui, WEI Lifei, WANG Zhaoying, ZHANG Anying, WANG Deyi. Preparation and properties of layer-by-layer self-assembled flame retardant modified polyester fabrics [J]. Journal of Textile Research, 2019, 40(11): 106-112.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] LUO Xiaolei, LIU Lin, YAO Juming. Preparation and study of pure biomass cellulose aerogels for flame retardancy[J]. Journal of Textile Research, 2022, 43(01): 1 -8 .
[2] LI Longlong, WEI Peng, WU Cuixia, YAN Jinfei, LOU Hejuan, ZHANG Yifeng, XIA Yumin, WANG Yanping, WANG Yimin. Synthesis and properties of bio-based liquid crystal copolyester fiber based on p-hydroxyphenyl propionic acid[J]. Journal of Textile Research, 2022, 43(01): 9 -14 .
[3] . [J]. Journal of Textile Research, 2022, 43(01): 217 .
[4] . [J]. Journal of Textile Research, 2022, 43(01): 218 .
[5] . [J]. Journal of Textile Research, 2021, 42(11): 207 .
[6] WEI Na'na, LIU Die, MA Zheng, JIAO Chenlu. Adsorption performance of cellulose/chitosan magnetic aerogel prepared by freeze-thawing method[J]. Journal of Textile Research, 2022, 43(02): 53 -60 .
[7] WANG Rui, LIU Yanlin, LIU Yunyu, GU Weiwen, LIU Ziling, WEI Jianfei. Preparation and application of carbon dots with polyethylene terephthalate as precursor[J]. Journal of Textile Research, 2022, 43(02): 10 -18 .
[8] SHI Sheng, WANG Yan, LI Fei, TANG Jiandong, GAO Xiangyu, HOU Wensheng, GUO Hong, WANG Shuhua, JI Jiaqi. Efficient separation of polyester and cotton from waste blended fabrics with dilute oxalic acid solution[J]. Journal of Textile Research, 2022, 43(02): 140 -148 .
[9] CHEN Yong, WU Jing, WANG Chaosheng, PAN Xiaohu, LI Naixiang, DAI Junming, WANG Huaping. Preparation and environmental degradation behavior of biodegradable poly (butylene adipate-co-terephthalate) fiber[J]. Journal of Textile Research, 2022, 43(02): 37 -43 .
[10] DONG Han, ZHENG Sensen, GUO Tao, DONG Jie, ZHAO Xin, WANG Shihua, ZHANG Qinghua. Preparation and properties of high heat-resistant polyimide fiber[J]. Journal of Textile Research, 2022, 43(02): 19 -23 .
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd