Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (10): 192-199.doi: 10.13475/j.fzxb.20210608108

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Application progress of fiber materials in flexible wearable zinc batteries

WANG Jin1,2, HU Kairui2, ZHANG Liufei3, CHEN Lei2()   

  1. 1. School of Arts, Tiangong University, Tianjin 300387, China
    2. School of Textile Science and Engineering,Tiangong University, Tianjin 300387, China
    3. Jiangyin Customs District P.R. China, Wuxi, Jiangsu 214400, China
  • Received:2021-06-30 Revised:2022-05-07 Online:2022-10-15 Published:2022-10-28
  • Contact: CHEN Lei E-mail:chenlei@tiangong.edu.cn

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Abstract:

In order to promote the application of zinc ion batteries with high safety and low cost in flexible energy storage devices, the paper takes fiber-based zinc ion batteries as the object and firstly clarifies the mechanism of zinc anode oxidation and transition metal oxide or oxygen positive cathode reduction in the process of charge and discharge proccess. Secondly, fibers such as carbon fiber, carbon nanofiber, carbon nanotube yarn, metal fiber and other inorganic fiber in the cathode, anode and electrolyte of flexible zinc battery are reviewed. The effects of different preparation processes, microstructure and modification strategies on the electrochemical characteristics of fiber-based flexible batteries are analyzed and compared, and the main parameters affecting its performance are defined. At last, it is proposed that the structural ordered design of fibers has a significant effect on improving the electrochemical performance of batteries, and the broad development prospect of natural fiber based electrode materials is emphasized. This paper has a positive significance for accelerating the industrial application of intelligent clothing and helping to realize the vision of "carbon peak and carbon neutralization" as soon as possible.

Key words: fiber-based material, flexible zinc battery, microstructure, electrochemical property

CLC Number: 

  • TQ028.2

Tab.1

Comparison of electrochemical characteristics of zinc batteries based on different fiber materials"

正极材料 负极材料 电解质 比容量 能量密度 功率密度 循环性能 文献
钢纤维/NiCO(OH)x 不锈钢纤维/锌 PVA/Zn(CH3COO)2 5 mA·h/cm3 0.12 mW·h/cm2 32.8 mW/cm2 [43]
Mn-NiOx/Cu Zn/Li插层TiO2 PVA/KOH 19.6 mA·h/cm3 0.034 Wh·/cm3 17.5 W/cm3 20 000圈后放电容量95% [44]
NiO/CNFs/碳布 ZnO/CNFs/碳布 PVA/KOH 265 mA·h/g 7.76 mW·h/cm3 0.54 W/cm3 1 000圈后放电容量91.45% [34]
空气/N-NiSe2/碳布 锌箔 KOH/丙烯酸/
K2S2O8水凝胶		 504 mA·h/g [5]
空气/Co1-xFexO-NC/
碳布		 锌箔 KOH/醋酸锌 673 mA·h/g [10]
空气/N-Co3O4 锌包覆碳织物 碱性凝胶电解质 603.7 mA·h/g [15]
空气/Co3O4/碳纳米纤维 锌箔 KOH/ZnCl2溶液 125 mW/cm2 [21]
空气/Fe-CNFs 锌箔 KOH/醋酸锌 135 mW/cm2 [24]
空气/FeNi/N-CNTs 锌箔 KOH/醋酸锌 751 mA·h/g 917 W·h/kg 160.6 mW/cm2 960圈后无放电电压损耗 [27]
空气/Co/Co3O4杂化多孔CNFs 锌箔 KOH/Zn(CH3COO)2 748.5 mA·h/g 102 mW/cm2 [33]
空气/杂化多孔CNFs 锌箔 KOH/Zn(CH3COO)2 626 mA·h/g 776 W·h/kg 185 mW/cm2 500圈后电压间
隙增长0.13 V		 [33]
铁氰化锌/CNTs 锌/CNTs ZnSO4/纤维素 100.2 mA·h/cm3 195.4 mW·h/cm3 200圈后放电容量91.8% [39]
MnO2/CNTs 锌线 ZnCl2/PVA 290 mA·h/g 360 W·h/kg 100圈后放电容量98% [54]
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