Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (10): 119-125.doi: 10.13475/j.fzxb.20210708007

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and antifouling properties of super-slip cotton fabric based on polymer microspheres grafted with silicone oil

ZHANG Diandian1,2, YU Mengnan1,2, LI Min1,2, LIU Mingming1,2, FU Shaohai1,2,3()   

  1. 1. Jiangsu Engineering Research Center for Digital Textile Inkjet Printing, Wuxi, Jiangsu 214122, China
    2. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
    3. National Manufacturing Innovation Center of Advanced Dyeing and Finishing Technology, Taian, Shandong 271000, China
  • Received:2021-07-29 Revised:2022-07-14 Online:2022-10-15 Published:2022-10-28
  • Contact: FU Shaohai E-mail:shaohaifu@hotmail.com

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Abstract:

In order to improve the physical and chemical stability of super-slip(SLIPS) fabrics, the self-adhesive core-shell polymer microspheres were prepared by emulsion polymerization using vinyl-modified silica nanoparticles (V-SiO2) as the raw material. After the dipping and baking process, it was bonded to the surface of cotton fabric to obtain a rough substrate. The amino silicone oil was then grafted onto rough substrate surface by amino-epoxy graft reaction and amino-hydroxyl hydrogen bond to obtain a SLIPS-cotton fabric(SLIPS-Cotton). The properties of liquid repellent, antifouling, physical and chemical stability of SLIPS-Cotton were studied. The results shown that the rough structure of the SLIPS in SLIPS-Cotton is composed of microspheres with a particle size of 321.3 nm, and the contact angle of water droplets on the surface is 138°. The sliding angles of water and dimethyl sulfoxide on the surface of the SLIPS-Cotton are 7° and 15° respectively. After contacting with tomato sauce and coffee contaminants, the amount of adhesion on the surface of SLIPS-Cotton is significantly reduced. After water splash washing within 200 mL, the sliding angles of water and dimethyl sulfoxide on SLIPS-Cotton surface are less than 12° and 26°, respectively. The contact angles of droplets on the surface of the SLIPS-Cotton are stable between 42° and 49° at pH 3-9.

Key words: super-slip cotton fabric, emulsion polymerization, polymer microsphere, core-shell structure, liquid repellent and antifouling, antifouling performance

CLC Number: 

  • TS195.9

Tab.1

Preparation formula of polymer microspheres"

聚合物
微球名称		 质量/g
St DVB HEMA GMA
Poly-V-SiO2-O-1 1.00 0.40 0.30 0.30
Poly-V-SiO2-T-1 1.00 0.40 0.30 0.30
Poly-V-SiO2-O-2 1.00 0.40 0.15 0.30
Poly-V-SiO2-T-2 1.00 0.40 0.15 0.30
Poly-V-SiO2-O-3 1.00 0.40 0.10 0.30
Poly-V-SiO2-T-3 1.00 0.40 0.10 0.30

Fig.1

Preparation process of SLIPS-Cotton by polymer microspheres grafted with silicone oil. (a) Preparation of Poly-V-SiO2; (b) Preparation of Poly-V-SiO2-Cotton; (c)Preparation of SLIPS -Cotton"

Fig.2

Morphology of Poly-V-SiO2 microspheres. (a) SEM images; (b) TEM images"

Tab.2

EDS element content of polymer microspheres%"

聚合物微球名称 C O Si
V-SiO2 15.42 58.26 26.32
Poly-V-SiO2-T-2 32.06 48.65 19.29

Fig.3

XPS spectra (a) and TG and DTG (b) curves of different microspheres"

Fig.4

SEM images of Poly-V-SiO2-Cotton"

Fig.5

Wettability of cotton fabric (a), Poly-V-SiO2-Cotton before (b) and after (c) baking"

Fig.6

Contact angle, sliding angle and sliding process of droplet on surface of SLIPS-Cotton. (a) Water; (b) DMSO"

Fig.7

Ketchup, coffee adhesion on surface of cotton fabric (a) and SLIPS-Cotton (b)"

Fig.8

Water impact resistance performance(a) and acid and alkali resistance performance(b) of SLIPS-Cotton"

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