Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (11): 133-140.doi: 10.13475/j.fzxb.20210902908

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Peracetic acid activation for efficient degradation of p-nitrophenol by mixed-valence iron-based metal-organic framework

HU Qian1,2, YANG Taoyu1, ZHU Feichao3, LÜ Wangyang3,4, WU Minghua1,3, YU Deyou1,2,4()   

  1. 1. Engineering Research Center for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Tongxiang Research Institute, Zhejiang Sci-Tech University, Jiaxing, Zhejiang 314500, China
    3. Key Laboratory of Advanced Textile Materials & Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    4. School of Materials Science & Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2021-09-09 Revised:2022-03-15 Online:2022-11-15 Published:2022-12-26
  • Contact: YU Deyou E-mail:yudeyou92@zstu.edu.cn

RichHTML

8

PDF (PC)

39

Abstract:

In order to improve the advanced treatment efficiency of iron-based metal-organic frame-works (Fe-MOFs) for printing and dyeing wastewater, mixed-valence MIL-53(Fe) (MV-MIL-53(Fe)) containing Fe(Ⅱ) and Fe(Ⅲ) was prepared by an in-situ doping solvothermal approach. The MV-MIL-53(Fe) was systematically characterized with X-ray diffraction, scanning electron microscopy, nitrogen adsorption equipment, and pyridine chemisorbed infrared spectroscopy. p-nitrophenol and peracetic acid (PAA) were selected as the model target and green oxidant respectively to study the degradation activity and major active species of MV-MIL-53(Fe). The results show that Fe(Ⅱ) dopant increased the Lewis acidity of MIL-53(Fe), thus offering more active sites for PAA activation. The 4-NP degradation kinetic rate constant of MV-MIL-53(Fe)/PAA system could reach to 0.052 1 min-1, which was 2.05, 1.45, and 6.68 times higher than MV-MIL-53(Fe)/H2O2, MIL-53(Fe)/PAA, and MIL-53(Fe)/H2O2 counterparts, respectively. After successive cycling for five runs, the MV-MIL-53(Fe) still exhibited good structure stability and catalysis activity for 4-NP degradation using PAA. Hydroxyl radicals were verified as the main reactive species converting from PAA for the rapid degradation of 4-NP.

Key words: iron-based metal-organic framework, peracetic acid, catalytic degradation, p-nitrophenol, dyeing and printing wastewater

CLC Number: 

  • O643.32

Fig.1

XRD patterns of MV-MIL-53(Fe) and MIL-53(Fe) catalysts"

Fig.2

Molecular structure and element composition of MV-MIL-53(Fe) and MIL-53(Fe) catalysts. (a) FT-IR spectra; (b) High-resolution Fe 2p XPS spectra"

Fig.3

Morphology and porous structure of MV-MIL-53(Fe) and MIL-53(Fe) catalysts. (a) FE-SEM image; (b) N2 adsorption-desorption curves"

Tab.1

Lewis acidity of prepared MV-MIL-53(Fe) and MIL-53(Fe) catalysts"

样品名称 酸位强度 酸位密度/(mmol·g-1)
细分 总计
MIL-53(Fe) 弱酸 0.48 2.59
中酸 0.82
强酸 1.29
MV-MIL-53(Fe) 弱酸 1.00 3.49
中酸 1.64
强酸 0.85

Fig.4

Comparisons of PAA or H2O2 activation for 4-NP degradation by MV-MIL-53(Fe) and MIL-53(Fe) catalysts. (a) Degradation curves of 4-NP concentration with time; (b) k values of 4-NP degradation in different systems"

Fig.5

Recyclability and stability of MV-MIL-53(Fe). (a) 4-NP degradation curves over five times cycles; (b) XRD pattern of spent MV-MIL-53(Fe); (c) FE-SEM image of spent MV-MIL-53(Fe)(×3 000)"

Fig.6

Identification of major reactive species for 4-NP degradation in MV-MIL-53(Fe)/PAA system. (a) Effect of radical scavengers on 4-NP degradation ; (b) EPR spectra"

[1] 章耀鹏, 沈忱思, 徐晨烨, 等. 纺织工业典型污染物治理技术回顾[J]. 纺织学报, 2021, 45(8): 24-33.
ZHANG Yaopeng, SHEN Chensi, XU Chenye, et al. Review on treatment technology for typical pollutants in textile industry[J]. Journal of Textile Research, 2021, 45(8): 24-33.
[2] LIN X Q, KONG W M, LIN X. Degradation of high-concentration p-nitrophenol by Fenton oxidation[J]. Water Science & Technology, 2020, 81(10): 2260-2269.
[3] D'ALMEIDA S R, BUORO R M. Determination of p-nitrophenol in synthetic textile wastewater samples using a graphene oxide/palladium nanoparticles modified carbon paste electrode[J]. Electroanalysis, 2021, 33: 1623-1632.
doi: 10.1002/elan.202060539
[4] 王海人, 石兴阳, 徐育, 等. 废铁屑处理含酚废水的新方法及其机理研究[J]. 环境科学与技术, 2010, 33(12): 309-311.
WANG Hairen, SHI Xingyang, XU Yu, et al. New method of scrap iron dealing with p-nitrophenol simulated wastewater and the research of its mechanism[J]. Environmental Science & Technology, 2010, 33(12): 309-311.
[5] 杨明, 刘琪, 孙健, 等. 印染废水深度处理研究及应用进展[J]. 净水技术, 2020, 39(10): 109-115.
YANG Ming, LIU Qi, SUN Jian, et al. Research and application progress of advanced treatment of dyeing wastewater[J]. Water Purification Technology, 2020, 39(10): 109-115.
[6] PEREIRA A, RODRIGUES F, PAULINO A, et al. Recent advances on composite hydrogels designed for the remediation of dye-contaminated water and wastewater: a review[J]. Journal of Cleaner Production, 2021, 284: 124703.
doi: 10.1016/j.jclepro.2020.124703
[7] EPSZTEIN R, DUCHANOIS R, RITT C, et al. Towards single-species selectivity of membranes with subnanometre pores[J]. Nature Nanotechnology, 2020, 15(6): 426-436.
doi: 10.1038/s41565-020-0713-6 pmid: 32533116
[8] 胡承志, 刘会娟, 曲久辉. 电化学水处理技术研究进展[J]. 环境工程学报, 2018, 12(3): 677-696.
HU Chengzhi, LIU Huijuan, QU Jiuhui. Research progress of electrochemical technologies for water treatment[J]. Chinese Journal of Environmetal Engineering, 2018, 12(3): 677-696.
[9] HODGES B, CATES E, KIM J. Challenges and prospects of advanced oxidation water treatment processes using catalytic nanomaterials[J]. Nature Nanotechnology, 2018, 13(8): 642-650.
doi: 10.1038/s41565-018-0216-x pmid: 30082806
[10] YANG Z, QIAN J, YU A, et al. Singlet oxygen mediated iron-based Fenton-like catalysis under nanoconfinement[J]. Proceedings of the National Academy of Sciences of the United States of America, 2019, 116(14): 6659-6664.
doi: 10.1073/pnas.1819382116 pmid: 30872470
[11] ZHOU P, REN W, NIE G, et al. Fast and long-lasting iron(Ⅲ) reduction by boron toward green and accelerated Fenton chemistry[J]. Angewandte Chemie International Edition, 2020, 59(38): 16517-16526.
doi: 10.1002/anie.202007046
[12] SUN M, CHU C, GENG F, et al. Reinventing Fenton chemistry: iron oxychloride nanosheet for pH-insensitive H2O2 cctivation[J]. Environmental Science & Technology Letters, 2018, 5(3): 186-191.
[13] ZHAO H, QIAN L, GUAN X, et al. Continuous bulk FeCuC aerogel with ultradispersed metal nanoparticles: an efficient 3D heterogeneous electro-Fenton cathode over a wide range of pH 3-9[J]. Environmental Science & Technology, 2016, 50(10): 5225-5233.
doi: 10.1021/acs.est.6b00265
[14] XIA Q, WANG H, HUANG B, et al. State-of-the-art advances and challenges of iron-based metal organic frameworks from attractive features, synthesis to multifunctional applications[J]. Small, 2018, 15(2): 1803088.
[15] YU D, WU M, HU Q, et al. Iron-based metal-organic frameworks as novel platforms for catalytic ozonation of organic pollutant: efficiency and mechanism[J]. Journal of Hazardous Materials, 2019, 367: 456-464.
doi: S0304-3894(18)31257-3 pmid: 30611038
[16] WU Q, YANG H, KANG L, et al. Fe-based metal-organic frameworks as Fenton-like catalysts for highly efficient degradation of tetracycline hydrochloride over a wide pH range: acceleration of Fe(Ⅱ)/Fe(Ⅲ) cycle under visible light irradiation[J]. Applied Catalysis B: Environmental, 2020, 263: 1-6.
[17] GAO C, CHEN S, QUAN X, et al. Enhanced Fenton-like catalysis by iron-based metal organic frameworks for degradation of organic pollutants[J]. Journal of Catalysis, 2017, 356: 125-132.
doi: 10.1016/j.jcat.2017.09.015
[18] TANG J, WANG J. Metal-organic framework with coordinatively unsaturated sites as efficient Fenton-like catalyst for enhanced degradation of sulfamethazine[J]. Environmental Science & Technology, 2018, 52(9): 5367-5377.
doi: 10.1021/acs.est.8b00092
[19] AO X, ELORANTA J, HUANG C, et al. Peracetic acid-based advanced oxidation processes for decontamination and disinfection of water: a review[J]. Water Reseach, 2021, 188: 1-6.
[20] EBRAHIM A, BANDOSZ T. Ce(III) doped Zr-based MOFs as excellent NO2 adsorbents at ambient condi-tions[J]. ACS Applied Materials Interfaces, 2013, 5(21): 10565-10573.
doi: 10.1021/am402305u
[21] GAO C, SU Y, QUAN X, et al. Electronic modulation of iron-bearing heterogeneous catalysts to accelerate Fe(III)/Fe(II) redox cycle for highly efficient Fenton-like catalysis[J]. Applied Catalysis B: Environmental, 2020, 276: 1-8.
[22] THOMMES M, KANEKO K, NEIMARK ALEXANDER V, et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)[J]. Pure and Applied Chemistry, 2015, 87(9/10): 1051-1069.
doi: 10.1515/pac-2014-1117
[23] LECLERC H, VIMONT A, LAVALLEY J, et al. Infrared study of the influence of reducible iron(Ⅲ) metal sites on the adsorption of CO, CO2, propane, propene and propyne in the mesoporous metal-organic framework MIL-100[J]. Physical Chemistry Chemical Physics, 2011, 13(24): 11748-11756.
doi: 10.1039/c1cp20502a
[24] BING J, HU C, ZHANG L. Enhanced mineralization of pharmaceuticals by surface oxidation over mesoporous γ-Ti-Al2O3 suspension with ozone[J]. Applied Catalysis B: Environmental, 2017, 202: 118-126.
doi: 10.1016/j.apcatb.2016.09.019
[25] WANG J, WANG Z, CHENG Y, et al. Molybdenum disulfide (MoS2): a novel activator of peracetic acid for the degradation of sulfonamide antibiotics[J]. Water Research, 2021, 201: 1-5.
[1] ZHENG Linjuan, YU Jia, YIN Chong, LIANG Zhijie, MAO Qinghui. Preparation and photocatalytic properties of cotton fabrics loaded with polymetallic organic framework material [J]. Journal of Textile Research, 2022, 43(10): 106-111.
[2] FENG Yan, LI Liang, LIU Shuping, LI Shujing, LIU Rangtong. Photocatalytic synergistic efficiency of viscose fabric loaded with nitrogen carbon quantum dots/titanium dioxide [J]. Journal of Textile Research, 2022, 43(10): 112-118.
[3] ZHANG Yaning, ZHANG Hui, SONG Yueyue, LI Wenming, LI Wenjun, YAO Jiale. Preparation of discarded mask-based ZIF-8/Ag/TiO2 composite and its photocatalytic property for dye degradation [J]. Journal of Textile Research, 2022, 43(07): 111-120.
[4] YANG Tengxiang, SHEN Guodong, QIAN Lijiang, HU Huajun, MAO Xue, SUN Runjun. External electric field polarized Ag-BaTiO3/polyester fabric and its photocatalytic properties [J]. Journal of Textile Research, 2022, 43(02): 189-195.
[5] SHI Minhui, LI Bingrui, WANG Ting, WU Liguang. Mechanism and performance of TiO2 composite photocatalysts for photo-degradation of methyl-orange in highly saline wastewater [J]. Journal of Textile Research, 2021, 42(12): 103-110.
[6] LI Qing, CHEN Linghui, LI Dan, WU Zhiqiang, ZHU Wei, FAN Zenglu. Research progress in photocatalytic degradation of dyes using metal-organic frameworks [J]. Journal of Textile Research, 2021, 42(12): 188-195.
[7] ZHANG Yuhan, SHEN Guodong, FAN Wei, SUN Runjun. Preparation of aramid fiber supported BiOBr composite materials and its photocatalytic degradation of dyeing wastewater [J]. Journal of Textile Research, 2021, 42(08): 128-134.
[8] ZHANG Tingting, XU Kexin, JIN Mengtian, GE Shijie, GAO Guohong, CAI Yixiao, WANG Huaping. Recent progress in preparation of cellulose-based organic-inorganic photocatalysts nanohybrids and it's application in water treatment [J]. Journal of Textile Research, 2021, 42(07): 175-183.
[9] XU Chenye, GU Chunjie, NI Yifan, SHEN Chensi, WANG Huaping, WU Jing, LI Fang. Occurrence and release of fibrous microplastic from dyeing and printing wastewater [J]. Journal of Textile Research, 2021, 42(06): 26-34.
[10] LOU Yaya, WANG Jing, DONG Yanchao, WANG Chunmei. Preparation and decolorization of rayon based zeoliticimidazolate framework functional material [J]. Journal of Textile Research, 2021, 42(02): 142-147.
[11] XIA Yun, LÜ Wangyang, CHEN Wenxing. Catalytic degradation of dye by metal phthalocyanine/multi-walled carbon nanotubes under simulated solar light [J]. Journal of Textile Research, 2020, 41(12): 94-101.
[12] LI Qing, GUAN Binbin, WANG Ya, LIU Tianhui, ZHANG Luohong, FAN Zenglu. Photosensitizers sensitized Cu-organic framework for highly efficient photocatalytic degradation of Reactive Dark Blue K-R [J]. Journal of Textile Research, 2020, 41(10): 87-93.
[13] HAN Ye, ZHANG Hui, ZHU Guoqing, WU Hailiang. Effect of polyethylene glycol on photocatalytic properties of polyethylene terephthalate fibers treated with titanium sulfate under hydrothermal conditions [J]. Journal of Textile Research, 2019, 40(10): 33-41.
[14] . Low temperature bonding preparation of functionalized ramie fabrics for formaldehyde photocatalytic degradation  [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(12): 106-111.
[15] . Microwave-assisted low temperature in-situ synthesis and coating of Tungsten-doped TiO2 onto cotton fabric and photocatalytic peerformance of coated fabric [J]. JOURNAL OF TEXTILE RESEARCH, 2014, 35(7): 88-0.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 33 -34 .
[2] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 35 -36 .
[3] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 107 .
[4] . [J]. JOURNAL OF TEXTILE RESEARCH, 2003, 24(06): 109 -620 .
[5] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(01): 1 -9 .
[6] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 101 -102 .
[7] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 103 -104 .
[8] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 105 -107 .
[9] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 108 -110 .
[10] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 111 -113 .
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd