Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (01): 147-152.doi: 10.13475/j.fzxb.20210907106

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of dyeing promoter on dyeing kinetics and thermodynamics of polybutylene succinate fiber dyeing with disperse dye

WANG Chenglong1,2, LI Lixin2,3, WU Shaoming2, CHAI Liqin1,2, ZHOU Lan1,2()   

  1. 1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Engineering Research Center of Ecological Dyeing and Finishing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018,China
    3. Hangzhou Xinsheng Printing & Dyeing Co., Ltd., Hangzhou, Zhejiang 311200, China
  • Received:2021-09-22 Revised:2021-11-08 Online:2022-01-15 Published:2022-01-28
  • Contact: ZHOU Lan E-mail:lan_zhou330@163.com

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Abstract:

In order to develop polybutylene succinate (PBS) fiber disperse dye low-temperature dyeing technology, the role of dyeing promoters in the dyeing process was studied. Diethyl succinate was used to prepare dyeing promoter for the dyeing of PBS fiber with disperse dye. C.I. Disperse Red 60 was used to dye PBS fiber, the influence of dyeing promoter on the dyeing kinetics and thermodynamics of PBS fiber was studied, and dyeing mechanism of PBS fiber was investigated. The result showed that the dyeing kinetic equation of C.I. Disperse Red 60 on PBS fiber was in accordance with the quasi second order kinetic equation. Compared to dye without dyeing promoter, with the condition of dyeing at 70 ℃ with dye promoter, the equilibrium adsorption capacity of C.I. Disperse Red 60 on PBS fibers was increased, and the dyeing rate significantly was faster, the half-staining time was shortened, and the diffusion coefficient was also significantly increased. The addition of dyeing promoter played a certain role in promoting the dyeing of PBS fibers with disperse dyes. With or without dyeing accelerators, the dyeing of C.I. Disperse Red 60 on PBS fiber conformed to the Nernst type adsorption isotherm.

Key words: polybutylene succinate fiber, disperse dye, dyeing promoter, dyeing kinetics, dyeing thermodynamics

CLC Number: 

  • TS193.1

Fig.1

Dyeing rate curve for dyeing of PBS fiber with C.I. Disperse Red 60"

Fig.2

Fitting of quasi-first-order kinetic equation of C.I. Disperse Red 60 adsorption on PBS fiber"

Tab.1

Quasi-first-order kinetic parameters of C.I. Disperse Red 60 dyeing on PBS fiber"

有无染色
促进剂		 准一级动力学参数
C∞,exp/(mg·g-1) C∞,cal/(mg·g-1) k1/min-1
无 8.08 2.32 2.73×10-2
有 19.16 8.35 1.00×10-1

Fig.3

Fitting of quasi-second-order kinetic equation of C.I. Disperse Red 60 adsorption on PBS fiber"

Tab.2

Quasi-second-order kinetic parameters of C.I. Disperse Red 60 dyeing on PBS fiber"

有无染色
促进剂		 准二级动力学参数
C∞,exp/(mg·g-1) C∞,cal/(mg·g-1) k2/min-1
无 8.08 10.42 2.97×10-3
有 19.16 19.24 3.00×10-1

Tab.3

Dyeing kinetic parameters of C.I. Disperse Red 60 with different dyeing conditions"

有无染色促进剂 半染时间 t1/2/min 扩散系数D/
(10-15m2·min-1)
无 20.82 1.221
有 5.70 18.184

Fig.4

Adsorption isotherm of C.I. Disperse Red 60 on PBS fiber"

Fig.5

Nernst-type fitting curve of adsorption of C.I. Disperse Red 60 to PBS fiber"

Tab.4

Nernst-type fitting parameters of adsorption of C.I. Disperse Red 60 to PBS fiber"

染色温
度/℃		 有无染色
促进剂		 Kn/
(L·g-1)		 拟合公式 拟合
系数R2
70 无 0.444 9 y=0.444 9x+3.882 8 0.991 2
有 1.338 8 y=1.338 8x+4.263 5 0.994 9
90 无 1.476 5 y=1.476 5x+3.729 5 0.998 2
有 1.770 8 y=1.770 8x+4.458 5 0.997 3
[1] 王建平. 新型纤维材料开发中的生态安全与环境问题[J]. 合成纤维, 2012, 41(11): 1-8.
WANG Jianping. The problems of eco-safety and environment in the development of new fiber materials[J]. Synthetic Fiber in China, 2012, 41(11): 1-8.
[2] 陈文兴, 余志成, 胡智文. 21世纪的纤维与环境保护[J]. 纺织学报, 2002, 23(5): 82-84.
CHEN Wenxing, YU Zhicheng, HU Zhiwen. Fibers and environment protection in 21st centry[J]. Journal of Textile Research, 2002, 23(5): 82-84.
[3] 陈驰, 但卫华, 曾睿, 等. 可生物降解功能纤维的研究进展[J]. 纺织学报, 2006, 27(7): 100-103.
CHENG Chi, DAN Weihua, ZENG Rui, et al. Advances in research on biodegradable functional fibers[J]. Journal of Textile Research, 2006, 27(7): 100-103.
[4] 余莎莎. 聚丁二酸丁二醇酯(PBS)的降解菌株筛选及降解性研究[D]. 无锡: 江南大学, 2012: 2-3.
YU Shasha. Study on the screening and degradability of poly-(butylene succinate)[D]. Wuxi: Jiangnan University, 2012: 2-3.
[5] 韩艳萍. 聚丁二酸丁二醇酯(PBS)共聚聚酯的合成与性能研究[D]. 上海: 华东理工大学, 2013: 17-20.
HAN Yanping. Synthesis and properties of PBS and its copolyesters[D]. Shanghai: East China University of Science and Technology, 2013: 17-20.
[6] 李发学. 成纤用生物降解性聚丁二酸丁二醇-共-对苯二甲酸丁二醇酯(PBST)的合成及结构性能研究[D]. 上海: 东华大学, 2006: 8-11.
LI Faxue. Studies on the synthesis, structure and properties of biodegradable poly(butylene succinate-co-butylene terephthalate)s (PBST)[D]. Shanghai: Donghua University, 2006: 8-11.
[7] 邓利民. PBS及其共聚物的合成与表征[D]. 成都: 四川大学, 2004: 23-25.
DENG Limin. Synthesis and characterization of PBS and its copolymers[D]. Chengdu: Sichuan University, 2004: 23-25.
[8] HU Jiewen, WANG Qianqian, ZHU Ping. Structure and properties of degradable polybutylene succinate fibers[J]. Journal of Donghua University (English Edition), 2020(3): 191-198.
[9] LI Dawei, ZHANG Bingjie, WANG Shugen. A systematic study of dyeing polybutylene succinate fibres[J]. Coloration Technology, 2020, 136(1): 87-96.
doi: 10.1111/cote.12448
[10] 李立新, 金淑兰, 柴丽琴, 等. 可生物降解聚丁二酸丁二醇酯(PBS)纤维的染色性能研究[J]. 丝绸, 2020, 57(8): 12-18.
LI Lixin, JIN Shulan, CHAI Liqin, et al. Study on dyeing performance of biodegradable polybutylene succinate(PBS) fiber[J]. Journal of Silk, 2020, 57(8): 12-18.
[11] 唐杰, 吴赞敏. 新型环保载体对涤纶染色动力学影响及其机理研究[J]. 印染助剂, 2014, 31(5): 20-23.
TANG Jie, WU Zanmin. Effect of new environmental friendly carrier on kinetics of polyester fiber dyeing and its mechanism[J]. Textile Auxiliaries, 2014, 31(5): 20-23.
[12] HO Y S, MCKAY G. Sorption of dye from aqueous solution by peat[J]. Chemical Engineering Journal, 1998, 70(2): 115-124.
doi: 10.1016/S0923-0467(98)00076-1
[13] MOHAMMAD Tajul Islam, FRANCESCO Aimone, ADA Ferri, et al. Use of N-methylformanilide as swelling agent for meta-aramid fibers dyeing: kinetics and equilibrium adsorption of Basic Blue 41[J]. Dyes and Pigments, 2015, 113(2): 554-561.
doi: 10.1016/j.dyepig.2014.08.029
[14] HORI Terou, SATO Yasunori, SHIMIZU Toru. Contribution of swelling, dye affinity, glass transition temperature and other factors to the experimental diffusion coefficient of a dye into poly (ethylene terephthalate) from various solvents[J]. Journal of the Society of Dyers & Colourists, 1981(97): 6-13.
[15] 周岚. 基于纤维改性的棉织物天然染料染色技术及机理研究[D]. 天津: 天津工业大学, 2011: 168-190.
ZHOU Lan. Study on the natural dye's dyeing technology and its mechanism on modified cotton fibers[D]. Tianjin: Tiangong University, 2011: 168-190.
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[4] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(02): 103 -104 .
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