Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (01): 21-27.doi: 10.13475/j.fzxb.20210910807

• Fiber Materials • Previous Articles     Next Articles

Biomass-derived magnetic carbon composites towards microwave absorption

QIANG Rong1,2(), FENG Shuaibo1, LI Wanying1, YIN Linzhi1, MA Qian1, CHEN Bowen1, CHEN Yi1   

  1. 1. College of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China
    2. Henan Collaborative Innovation Center of Textile and Garment Industry, Zhengzhou, Henan 450007, China
  • Received:2021-09-27 Revised:2021-11-04 Online:2022-01-15 Published:2022-01-28

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Abstract:

In response to the national carbon neutrality and carbon emission peak target and in order to solve the potential preparation problem of magnetic carbon composite, it proposed a new biomass-derived strategy for the preparation of carbon-based microwave absorption composites. The iron/mushroom precursor was obtained by absorbing iron ions, where mushrooms acted as the raw material and iron salt severed as metal source. The Fe/Fe4N/C composites were acquired by controlled high-temperature pyrolysis, and the phase structure, morphology, thermal stability, magnetic stability, physiochemical properties and microwave absorption performance of composites were analyzed and discussed. It was proved that the increased pyrolysis temperature would improve the crystallinity of magnetic nanoparticles, and that the increases in Fe4N content would induce the decrease of coercivity and saturation magnetization simultaneously. The high pyrolysis temperature was conductive to the transformation from amorphous carbon to microcrystalline graphite,inducing the increased degree of graphitization degree of carbon components. The Fe/Fe4N/C composite pyrolyzed at 700 ℃ was regarded as the best microwave absorber. With a composite thickness being 4 mm, the effective bandwidth of microwave that could be absorbed reached to 6.64 GHz, from 4.00 to 10.64 GHz. The appropriate impedance matching and synergistic enhancement of dielectric loss and magnetic loss were considered to be responsible for the intensified microwave absorption. It is believed that the research provides a reference for the preparation of magnetic carbon microwave absorbers, and promotes the popularization and application of biomass-derived method.

Key words: biomass-derived method, carbon composites, magnetic, microwave absorption performance

CLC Number: 

  • O613.71

Fig.1

Schematic diagram for preparation of Fe/Fe4N/C composites"

Fig.2

Phase and morphology of Fe/Fe4N/C composites. (a) XRD pattern; (b) SEM image"

Fig.3

Analysis diagram of Fe/Fe4N/C composite. (a) Thermogravimetric analysis; (b) Raman spectra analysis"

Fig.4

Hysteresis curves of Fe/Fe4N/C composites"

Fig.5

Dielectric constant and complex permeability of Fe/Fe4N/C composites"

Fig.6

Dielectric loss tangent of Fe/Fe4N/C composites"

Fig.7

Magnetic loss tangent of Fe/Fe4N/C composites"

Fig.8

2-D reflection loss diagrams of Fe/Fe4N/C composites"

Fig.9

Attenuation factor curves of Fe/Fe4N/C composites"

Fig.10

Impedance matching diagram of Fe/Fe4N/C composites"

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