Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (11): 22-28.doi: 10.13475/j.fzxb.20211001307

• Fiber Materials • Previous Articles     Next Articles

Bacterial cellulose/polyacrylamide hydrogel polymer electrolyte with dual-crosslinked network based on ionic liquid synergistic method

ZHANG Tianyun1,2(), SHI Xiaohong1, ZHANG Le1, WANG Fujuan1, XIE Yi'na1, YANG Liang1, RAN Fen2   

  1. 1. School of Mechanical and Electrical Engineering, Lanzhou University of Technology, Lanzhou, Gansu 730050, China
    2. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou, Gansu 730050, China
  • Received:2021-10-08 Revised:2022-01-19 Online:2022-11-15 Published:2022-12-26

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Abstract:

In order to achieve balance between different properties of the gel electrolyte, bacterial cellulose/polyacrylamide gel-polymer electrolyte with dual-crosslinked network was prepared by anionic imidazole-type ionic liquid and oxidized-bacterial cellulose, followed by crosslinking by acrylamide using in-situ free radical polymerization method. The anionic ionic liquids were 1-ethyl-3-methyl-imidazolium tetrafluoroborate (EMIMBF4), 1-ethyl-3-methyl-imidazolium hexafluorophosphate (EMIMPF6), and 1-ethyl-3-methyl-imidazolium bistrifluoromethosulfonimide (EMIMTFSI), respectively, which played important synergistic role in the construction of double crosslinked hydrogel polymer electrolyte. The results show that the gel polymer electrolyte based on EMIMBF4 has excellent mechanical properties and ionic conductivity, with its elongation at break being 38.60%, its tensile strength 175.25 kPa, and its ionic conductivity reached 20.16 mS/cm.

Key words: bacterial cellulose, polyacrylamide, ionic liquid, hydrogel electrolyte, dual-crosslinked network, electrochemical energy storage devices

CLC Number: 

  • TS102

Fig.1

FT-IR spectra of different hydrogel. (a) TBC-PAM and TBC-IL-PAM;(b) PAM, TBC, and TBC-PAM"

Fig.2

Stress-strain curves for TBC-PAM and TBC-IL-PAM"

Fig.3

EIS plots of TBC-PAM and TBC-IL-PAM (inset shows enlarged view at high-frequency region)"

Fig.4

Ionic conductivity of TBC/PAM and TBC-IL-PAM"

Tab.1

Comparison of swelling rate and water retention of composite gels%"

试样 吸液率 复吸率
TBC-PAM 274.95 76.67
TBC-B-PAM 324.51 52.46
TBC-P-PAM 308.16 75.70
TBC-T-PAM 262.15 76.95

Fig.5

Drying at 85 ℃ and reabsorption at 25 ℃ for TBC-PAM and TBC-IL-PAM"

Fig.6

Photos of TBC-PAM and TBC-IL-PAM at 85 ℃ for 1 h"

Fig.7

TGA curves of TBC-PAM and TBC-IL-PAM"

Fig.8

Tafel curves of zinc foil in different electrolytes"

Fig.9

Cycle curves of Zn symmetric cell assembled by ordinary glass fiber and TBC-B-PAM gel membrane"

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