Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (02): 44-52.doi: 10.13475/j.fzxb.20211101309

• Fiber Materials • Previous Articles     Next Articles

Fabrication of fluorescent cellulose nanocrystals hydrogels for chloride ion response

WU Jiayin1,2, WANG Hanchen1,2, HUANG Biao1, LU Qilin1,2()   

  1. 1. Fujian Key Laboratory of Novel Functional Textile Fibers and Materials, Minjiang University, Fuzhou, Fujian 350108, China
    2. College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
  • Received:2021-11-02 Revised:2021-12-08 Online:2022-02-15 Published:2022-03-15
  • Contact: LU Qilin E-mail:qilinlu@mju.edu.cn

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Abstract:

In order to avoid the usage of toxic reagents and reduce the high energy consumption and complicated multiple freeze-thaw cycles in the traditional preparation process of PVA composite hydrogels, PVA/F-CNCs/PA fluorescent cellulose nanocrystals hydrogels with good mechanical properties and high sensibility to Cl- were prepared by combining fluorescent cellulose nanocrystals (F-CNCs) and poly(vinyl alcohol) (PVA) through multiple hydrogen bonding under the cross-linking of phytic acid (PA). The fluorescent performance and Cl- sensibility of PVA hydrogel were improved significantly due to the excellent mechanical properties, high fluorescent performance, good biocompatibility and nanometer effect of F-CNCs. When the content of F-CNCs was 0.6 g, the compressive strength of PVA/F-CNCs/PA composite hydrogels was increased by 150%, and the crystallinity and thermal stability were also improved. The composite hydrogels were sensitive to Cl- at low pH, and the fluorescence quenching efficiency showed a linear response in the Cl- concentration range of 0-0.2 mol/L. The results indicated that the prepared fluorescent hydrogels had potential application in the field of Cl- concentration analysis and detection, biological and chemical sensors and disease diagnosis.

Key words: chloride ion response, fluorescent cellulose nanocrystal, phytic acid, multiple hydrogen bond, fluorescent hydrogel

CLC Number: 

  • TQ352

Fig.1

SEM images of composite hydrogels(×30 000)"

Fig.2

FT-IR spectra of composite hydrogels with different F-CNCs content and F-CNCs"

Fig.3

XRD spectra of composite hydrogels with different F-CNCs content(a) and F-CNCs(b)"

Fig.4

Swelling properties of composite hydrogels with different F-CNCs contents. (a) Swelling rate; (b) Re-swelling rate"

Fig.5

Compressive strength-strain and recovery curves of different F-CNCs content"

Fig.6

Rheological properties of PVA/F-CNCs/PA composite hydrogels with different F-CNCs contents. (a) Relationship between G'(G″) and strain; (b) Relationship between G'(G″) and scanning frequency; (c) Relationship between tanδ and scanning frequency; (d) Relationship between G'(G″) and temperature"

Fig.7

TG and DTG curves of composite hydrogel PVA/PA and PVA/F-CNCs/PA"

Fig.8

Fluorescence properties of PVA/F-CNCs/PA composite hydrogel. (a) Effect of Cl- concentration on fluorescent intensity; (b) Fitting curve between composite hydrogel and Cl- fluorescent quenching"

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