Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (02): 189-195.doi: 10.13475/j.fzxb.20211103907

• Dyeing and Finshing & Chemicals • Previous Articles     Next Articles

External electric field polarized Ag-BaTiO3/polyester fabric and its photocatalytic properties

YANG Tengxiang1, SHEN Guodong1,2(), QIAN Lijiang2, HU Huajun2, MAO Xue1,3, SUN Runjun1,3   

  1. 1. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    2. Zhejiang Shaoxing Yongli Printing and Dyeing Co., Ltd., Shaoxing, Zhejiang 312073, China
    3. State Key Laboratory of Intelligent Textile Material and Products, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
  • Received:2021-11-05 Revised:2021-11-15 Online:2022-02-15 Published:2022-03-15
  • Contact: SHEN Guodong E-mail:shenguodong@xpu.edu.cn

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Abstract:

In order to reduce the secondary recombination of photon-generated charge carriers and improve the recyclability of powder photocatalysts after degrading dyeing and printing wastewater, Ag-BaTiO3 nano powder was prepared by applying external electric field polarization with surface deposition of precious metal. Polyester-based Ag-BaTiO3 composite materials (Ag-BaTiO3/polyester fabric) were prepared with polyester fabric as substrate, and the microstructure and morphology of composite materials were characterized. Meanwhile, the photocatalytic properties of Ag-BaTiO3/polyester fabric before and after polarization were evaluated reactive yellow X-B dye as degradation object. The results show that Ag-BaTiO3 nano particles are deposited evenly on the polyester fabric surface. The surface deposition of precious metal Ag improves the visible light absorption activity of BaTiO3. The residual polarization strength of Ag-BaTiO3 increases from 1.61 μC/cm2 to 4.22 μC/cm2, and the degradation ratio of Ag-BaTiO3/polyester fabric over the target dye increases from 88.36% to 99.36% by applying external electric field polarization treatment.

Key words: Ag-BaTiO3, power photocatalysts, external electric field polarization, polyester fabric, photocatalytic degradation

CLC Number: 

  • TS151

Fig.1

XRD patterns of BaTiO3 and Ag-BaTiO3(a), with different treatmentpolyester, BatiO3 and Ag-BaTiO polyester fabric(b)"

Fig.2

SEM and TEM images of BaTiO3, Ag-BaTiO3, polyester fabric and fabric-based composite photocatalytic materials. (a) BaTiO3; (b) Ag-BaTiO3; (c) Polyester fabric; (d) BaTiO3/polyester fabric; (e) Ag-BaTiO3/polyester fabric"

Fig.3

XPS spectra of BaTiO3 and Ag-BaTiO3. (a) Survey spectra; (b) Ba 3d spectra; (c) Ti 2p spectra; (d) Ag 3d spectra"

Fig.4

Comparisons of hysteresis loop before and after applied external electric field polarization"

Fig.5

UV-Vis diffuse reflectance spectra of BaTiO3 and Ag-BaTiO3"

Fig.6

Photocatalytic degradation performance of powder photocatalysts(a) and polyester fabric-based composite photocatalytic materials(b) over reactive yellow X-B dye"

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