Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (11): 127-132.doi: 10.13475/j.fzxb.20211104006

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Different influence of hydroxyethyl methyl cellulose pretreatment on surface properties of cotton and polyamide

QIAO Xiran1, FANG Kuanjun1,2,3,4(), LIU Xiuming1, GONG Jixian1, ZHANG Shuai1, ZHANG Min1   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. College of Textiles & Clothing, Qingdao University, Qingdao, Shandong 266071, China
    3. Collaborative Innovation Center for Eco-Textiles of Shandong Province and the Ministry of Education, Qingdao, Shandong 266071, China
    4. State Key Laboratory for Bio-Fibers and Eco-Textiles, Qingdao, Shandong 266071, China
  • Received:2021-11-08 Revised:2022-04-30 Online:2022-11-15 Published:2022-12-26
  • Contact: FANG Kuanjun E-mail:13808980221@163.com

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Abstract:

The large difference in surface properties of cotton and polyamide fibers makes the spreading and permeation behaviors of dye inks different on the two fibers, which brings great difficulties for the inkjet printing of cotton/polyamide interwoven fabrics to obtain clear patterns. Herein, the surface properties of the cotton and polyamide fibers were modified by using multiple polymers for the cotton/polyamide interwoven fabrics. The results showed that the effect for the two fibers were different when the cotton/polyamide interwoven fabric was modified by only hydroxyethyl methyl cellulose. The hydrophilicity of the cotton fiber surface was decreased while the hydrophilicity of the polyamide fiber surface was enhanced. The dye depth values of cyan, magenta, yellow, and black on the interwoven fabric modified with hydroxyethyl methyl cellulose were increased by 34.6%, 45.0%, 40.0%, and 31.5%, respectively, compared with fabric modified with sodium alginate. Meanwhile the ink-jet printing pattern definition of the modified cotton-polyamide interwoven fabric was improved as a result.

Key words: cotton/polyamide fabric, surface modification, hydroxyethyl methyl cellulose, reactive dye, inkjet printing

CLC Number: 

  • TS194.4

Fig.1

Optical microscope photo of inkjet printing lines on polyamide fabric (a) and cotton/polyamide fabric (b) modified by different water-soluble polymers"

Tab.1

Contact angle and line width of cotton/polyamide interwoven fabrics modified by different polymers"

水溶性聚合物处理前后试样 接触角/(°) 线宽/mm
原布 29.3 0.23
空白对照样 23.2 0.25
海藻酸钠 27.1 0.24
黄原胶 50.3 0.22
瓜尔胶 39.1 0.24
羧甲基羟丙基纤维素 21.8 0.21
羧甲基纤维素钠 23.1 0.18
羟乙基甲基纤维素LH40MR 116.9 0.18
羟乙基甲基纤维素LH20MR 117.2 0.15
羟丙基淀粉醚 18.9 0.22
阴离子聚丙烯酰胺 21.2 0.21
非离子聚丙烯酰胺 21.4 0.21

Fig.2

Spreading process and contact angle of water droplets on fabric surface. (a) Untreated cotton fabric; (b) Cotton fabric modified by hydroxyethyl methylcellulose; (c) Untreated polyamide fabric; (d) Polyamide fabric modified by hydroxyethyl methyl cellulose; (e) Untreated cotton/polyamide interwoven fabric; (f) Cotton/polyamide interwoven fabric modified by hydroxyethyl methyl cellulose"

Tab.2

Inkjet printing K/S values of color block on cotton/ polyamide interwoven fabrics modified by different polymers"

水溶性聚合物处理前后试样 青 品红 黄 黑
原布 1.80 0.97 0.88 4.91
空白对照样 10.55 7.04 5.49 14.89
海藻酸钠 9.04 7.44 4.72 13.12
黄原胶 10.43 8.36 6.40 12.89
瓜尔胶 8.03 5.84 4.61 12.56
羧甲基羟丙基纤维素 11.19 10.80 6.63 14.04
羧甲基纤维素钠 11.09 9.55 6.45 13.32
羟乙基甲基纤维素LH40MR 12.17 10.79 6.61 17.25
羟乙基甲基纤维素LH20MR 13.09 12.53 6.48 17.84
羟丙基淀粉醚 10.08 7.04 5.29 14.83
阴离子聚丙烯酰胺 8.79 8.02 5.31 12.58
非离子聚丙烯酰胺 8.06 7.33 4.67 12.91

Fig.3

Photographs of inkjet printing patterns on cotton/polyamide interwoven fabrics modified by different water-soluble polymers. (a) Untreated; (b) Sodium alginate; (c) Hydroxyethyl methyl cellulose"

Tab.3

Colour fastness to rubbing of cotton/polyamide interwoven fabrics with different pretreatments 级"

预处理方式 经向 纬向
干 湿 干 湿
未处理 5 4 5 4
海藻酸钠处理 5 3~4 5 3~4
羟乙基甲基纤维素处理 5 3~4 5 3~4
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