Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (03): 31-37.doi: 10.13475/j.fzxb.20211105307

• Invited Column: Biomedical Textiles • Previous Articles     Next Articles

Preparation and properties of antibacterial hemostatic nonwoven elastic bandage

CHENG Yue1, HU Yingjie2, FU Yijun1,3(), LI Dawei1,3, ZHANG Wei1,3   

  1. 1. School of Textile and Clothing, Nantong University, Nantong, Jiangsu 226019, China
    2. College of Textiles, Donghua University, Shanghai 201620, China
    3. National & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Health, Nantong, Jiangsu 226019, China
  • Received:2021-11-09 Revised:2022-01-06 Online:2022-03-15 Published:2022-03-29
  • Contact: FU Yijun E-mail:fuyj@ntu.edu.cn

RichHTML

27

PDF (PC)

112

Abstract:

In emergencies, surgical operations and military conflicts, the human body may suffer from severe trauma resulting in massive bleeding. In order to effectively control bleeding and reduce the chance of wound infection, an elastic bandage with antibacterial hemostatic functions was developed. Polypropylene (PP) spunbonded elastic nonwovens were chosen as the base materials and treated with hydrophilic modification of polyvinyl alcohol (PVA) and grafting modification of chitosan (CH) to obtain PP-PVA-CH elastic nonwovens with both functions of antibacterial and hemostasis. The properties of the samples before and after modification were analyzed. The results show that PVA and CH were successfully loaded on the surface of nonwovens without affecting the main crystal structures. The maximum tensile breaking strength and elongation at break of PP-PVA-CH were 1.40 and 1.24 times higher than that of PP, and elastic recovery rate of PP-PVA-CH was 88%. Contact angle of the modified sample decreased effectively, and the diffusion areas of deionized water and synthetic blood were 13.0 and 12.9 times that of PP elastic nonwovens, respectively. Antibacterial rate of PP-PVA-CH elastic nonwovens against E.coli and S.aureus were found higher than 99.0%.

Key words: medical and hygiene textiles, elastic bandage, antibacterial, liquid adsorption, nonwoven, chitosan

CLC Number: 

  • TS101.4

Fig.1

Diagram of elasticity test at fixed elongation"

Fig.2

Micromorphology of different samples"

Fig.3

Infrared spectra of different samples"

Fig.4

XRD patterns of different samples"

Tab.1

Surface density and loading capacity of different samplesg/m2"

试样 面密度 负载量
PP 47.2±1.3 0
PP-PVA 58.7±1.9 11.5±1.1
PP-PVA-CH 70.0±1.5 11.3±1.2

Tab.2

Maximum tensile breaking force and elongation at break of different samples"

试样 最大拉伸断裂强力/N 断裂伸长率/%
PP 18.21±1.57 54.36±2.98
PP-PVA 18.56±2.16 56.62±3.45
PP-PVA-CH 25.47±2.31 67.30±4.56

Fig.5

Typical tensile curve of different samples"

Tab.3

Results of elasticity test at constant elongation of different samples"

试样 L0/mm L1/mm L2/mm ρ/% ε/%
PP 100 150 103 94 3
PP-PVA 100 150 105 90 5
PP-PVA-CH 100 150 106 88 6

Fig.6

Elasticity test photos of different samples"

Fig.7

Liquid diffusion properties of different samples. (a) Photographs; (b) Diffusion area of samples"

Tab.4

Antibacterial rate of different samples%"

试样 抑菌率
大肠杆菌 金黄色葡萄球菌
PP 1.56±0.21 2.38±0.51
PP-PVA-CH 99.9±1.05 99.0±0.89

Fig.8

Antibacterial effect of different samples. (a) For E.coli; (b) For S.aureus"

[1] 陈淑珍. 医用绷带中国专利分析[J]. 纺织科学研究, 2019(7):78-80.
CHEN Shuzhen. Analysis of Chinese patent for medical bandage[J]. Textile Science Research, 2019(7):78-80.
[2] 林建云, 罗时荷, 杨崇岭, 等. 生物基高分子型止血材料和伤口敷料[J]. 化学进展, 2021,33(4):581-595.
doi: 10.7536/PC200437
LIN Jianyun, LUO Shihe, YANG Chongling, et al. Bio-based polymeric hemostatic material and wound dressing[J]. Progress in Chemistry, 2021,33(4):581-595.
doi: 10.7536/PC200437
[3] 王璐, 关国平, 王富军, 等. 生物医用纺织材料及其器件研究进展[J]. 纺织学报, 2016,37(2):133-140.
WANG Lu, GUAN Guoping, WANG Fujun, et al. Research progress on biomedical textile materials and devices[J]. Journal of Textile Research, 2016,37(2):133-140.
[4] 安玉山, 王端, 刘洪玲. 医用绷带的发展[J]. 上海纺织科技, 2001(1):49-50.
AN Yushan, WANG Duan, LIU Hongling. Development of medical bandages[J]. Shanghai Textile Science & Technology, 2001(1):49-50.
[5] 金晓东. 基于双针床经编机生产一次成形医用绷带的工艺设计与开发[J]. 青岛大学学报(自然科学版), 2019,32(4):6-10.
JIN Xiaodong. Process design and development of producing one-time forming medical bandage based on double needle bed warp-knitting machine[J]. Journal of Qingdao University(Natural Science), 2019,32(4):6-10.
[6] 王玉晓, 李晶, 王丹, 等. 医用非织造产品的研究与应用进展[J]. 纺织导报, 2017(12):69-72.
WANG Yuxiao, LI Jing, WANG Dan, et al. Progress in the research and application of medical nonwovens[J]. China Textile Leader, 2017(12):69-72.
[7] 李刚健, 王林, 袁炜, 等. 医用聚丙烯材料发展现状[J]. 化工技术与开发, 2020,49(6):66-70.
LI Gangjian, WANG Lin, YUAN Wei, et al. Development status of medical polypropylene materials[J]. Technology & Development of Chemical Industry, 2020,49(6):66-70.
[8] 田光亮, 张文馨, 靳向煜, 等. 非织造材料用纤维的研究进展及发展趋势[J]. 产业用纺织品, 2019,37(9):1-6.
TIAN Guangliang, ZHANG Wenxin, JIN Xiangyu, et al. Research progress and development trend of fibers for nonwovens[J]. Technical Textiles, 2019,37(9):1-6.
[9] ELSABAHY Mahmoud, HAMAD Mostafa A. Design and preclinical evaluation of chitosan/kaolin nanocomposites with enhanced hemostatic efficiency[J]. Marine Drugs, 2021,19(2):50-65.
doi: 10.3390/md19020050
[10] 程冉, 徐瑞, 何前虹, 等. 水刺/机织绷带的复合工艺及性能研究[J]. 产业用纺织品, 2021,39(6):29-33.
CHENG Ran, XU Rui, HE Qianhong, et al. Study on the composite process and properties of spunlaced/woven bandages[J]. Technical Textiles, 2021,39(6):29-33.
[11] 陈健, 高璨, 高晓鸣. 美国纺织品抗菌性能检测标准最新进展[J]. 中国纤检, 2019(6):94-97.
CHEN Jian, GAO Can, GAO Xiaoming. Latest developments in testing standards for antibacterial properties of textiles in the United States[J]. China Fiber Inspection, 2019(6):94-97.
[12] HIROMI K S, MASAHIKO T, TEPPEI I, et al. Quick and easy sample preparation without resin embedding for the bone quality assessment of fresh calcified bone using fourier transform infrared imaging[J]. Plos One, 2018,13(2):e0189650.
doi: 10.1371/journal.pone.0189650
[13] 傅奇炜. 聚丙烯的晶体结构表征[J]. 生物化工, 2020,6(3):99-101.
FU Qiwei. Crystal structure characterization of polypropylene[J]. Biological Chemical Engineering, 2020,6(3):99-101.
[14] SREEJA S, SREEDHANYA S, SMIJESH N, et al. Organic dye impregnated poly(vinyl alcohol) nanocomposite as an efficient optical limiter: structure, morphology and photophysical properties[J]. Journal of Materials Chemistry C, 2013,1(24):3851-3861.
doi: 10.1039/c3tc30427b
[15] DU Yankai, PEI Meishan, HE Youjun, et al. Preparation, characterization and application of magnetic Fe3O4-CS for the adsorption of orange I from aqueous solutions[J]. Plos One, 2014,9(10):113-116.
[16] PEREZ J, NADRES E T, NGUYEN H N, et al. Response surface methodology as a powerful tool to optimize the synjournal of polymer-based graphene oxide nanocomposites for simultaneous removal of cationic and anionic heavy metal contaminants[J]. RSC Advances, 2017,7(30):18480-18490.
doi: 10.1039/C7RA00750G
[17] NISHINO T, MATSUMOTO T, NAKAMAE K. Surface structure of isotactic polypropylene by X-Ray diffraction[J]. Polymer Engineering & Science, 2000,40(2):336-343.
[18] 张燕, 徐庆南, 孔祥茹, 等. 常压N2+H2O气液DBD等离子体处理PP无纺布的超亲水性研究[J]. 真空科学与技术学报, 2019,39(9):767-774.
ZHANG Yan, XU Qingnan, KONG Xiangru, et al. Superhydrophilicity of PP nonwoven fabric modified with atmospheric gas-liquid DBD plasma[J]. Chinese Journal of Vacuum Science and Technology, 2019,39(9):767-774.
[19] LI J, ZHUANG S. Antibacterial activity of chitosan and its derivatives and their interaction mechanism with bacteria: current state and perspectives[J]. European Polymer Journal, 2020,138(1):109984.
doi: 10.1016/j.eurpolymj.2020.109984
[20] MA Z, GARRIDO A, JEONG K C. Application, mode of action, and in vivo activity of chitosan and its micro and nanoparticles as antimicrobial agents: a review[J]. Carbohydrate Polymers, 2017,176:257-265.
doi: 10.1016/j.carbpol.2017.08.082
[21] 秦益民. 壳聚糖纤维的理化性能和生物活性研究进展[J]. 纺织学报, 2019,40(5):170-176.
QIN Yimin. Physicochemical properties and bioactivities of chitosan fibers[J]. Journal of Textile Research, 2019,40(5):170-176.
[1] WANG Chenmeizi, WANG Ling, ZHANG Qingle, WANG Ying, XIA Xin. Preparation and property of composite hydrogel nonwoven based fresh-keeping material [J]. Journal of Textile Research, 2022, 43(03): 132-138.
[2] YU Fan, ZHENG Tao, TANG Tao, JIN Mengting, ZHU Hailin, YU Bin. Preparation of nonwoven composites based on metal-organic frame compounds and removal of hexavalent chromium from wastewater [J]. Journal of Textile Research, 2022, 43(03): 139-145.
[3] ZHANG Tao, WANG Fuping, CHEN Guobao, WU Jiyu, PANG Yani, CHEN Zhongmin. Preparation and performance of chitosan-based antibacterial gel [J]. Journal of Textile Research, 2022, 43(03): 71-77.
[4] WU Yang, LIU Fangtian, CAO Mengjie, CUI Jinhai, DENG Hongbing. Progress in biomass fiber medical dressings [J]. Journal of Textile Research, 2022, 43(03): 8-16.
[5] WEI Na'na, LIU Die, MA Zheng, JIAO Chenlu. Adsorption performance of cellulose/chitosan magnetic aerogel prepared by freeze-thawing method [J]. Journal of Textile Research, 2022, 43(02): 53-60.
[6] ZHAO Jiaming, SUN Hui, YU Bin, YANG Xiaodong. Preparation of CuO/polypropylene/ethylene-octene copolymer composite melt-blown nonwovens and their oil absorption properties [J]. Journal of Textile Research, 2022, 43(02): 89-97.
[7] DUO Yongchao, QIAN Xiaoming, GUO Xun, GAO Longfei, BAI He, ZHAO Baobao. Preparation and properties of hollow pie-segmented high shrinkage polyester/polyamide 6 microfiber nonwovens [J]. Journal of Textile Research, 2022, 43(02): 98-104.
[8] DING Qian, DENG Bingyao, LI Haoxuan. Research progress in all-fiber solar induced interface evaporation system to assist desalination with zero carbon emission [J]. Journal of Textile Research, 2022, 43(01): 36-42.
[9] SUN Ting, ZHANG Ruquan, TANG Zijie, TU Hu, HU Min. Study on low-carbon and energy-saving cold pad-batch bleaching treatment of cotton spunlaced nonwoven [J]. Journal of Textile Research, 2022, 43(01): 89-95.
[10] ZHU Feichao, ZHANG Yujing, ZHANG Qiang, YE Xiangyu, ZHANG Heng, WANG Lunhe, HUANG Ruijie, LIU Guojin, YU Bin. Research progress and prospect on biodegradable polylactic acid-based melt-blown nonwovens [J]. Journal of Textile Research, 2022, 43(01): 49-57.
[11] HUANG Xiaohua, ZHOU Jialiang, CHI Shan, LIU Yanming, FU Guangwei, HU Zexu, XIANG Hengxue, ZHU Meifang. Preparation and properties of polyester/silica/orange active ingredient fiber [J]. Journal of Textile Research, 2021, 42(12): 21-27.
[12] WANG Zhihui, XU Yufei, GUO Haoyu, ZHANG Kanglei, PANG Xingchen, NIE Xiaolin, ZHUGE Jian, WEI Qufu. Progress in application of photodynamic antibacterial technology for textiles [J]. Journal of Textile Research, 2021, 42(11): 187-196.
[13] LIU Shuping, LI Liang, LIU Rangtong, HU Zedong, GENG Changjun. Flame retardant finishing of cotton fabric with tri-aminopropyl triethoxysilane [J]. Journal of Textile Research, 2021, 42(10): 107-114.
[14] ZHOU Huiling, ZHU Lisha, WU Xiongying, DING Xuemei. Effect of electro-spraying treatment on anti-pilling performance of wool fabrics [J]. Journal of Textile Research, 2021, 42(10): 120-125.
[15] ZHAI Lisha, WANG Zonglei, ZHOU Jingyi, GAO Chong, CHEN Fengxiang, XU Weilin. Research progress of antibacterial materials for textiles and their applications [J]. Journal of Textile Research, 2021, 42(09): 170-179.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd