废旧棉与涤纶纺织品化学法循环再生利用的研究进展

doi:10.13475/j.fzxb.20211201806

Abstract

Abstract:

A large number of waste cotton and polyester textiles are produced in China, but the recycling rate is low and high quality products are rare. Focusing on this problem, the recycling of waste cotton and polyester fabrics based on chemical recycling was reviewed. The technology of waste cotton pulp preparation and its fiber spinning, the monomer preparation from the depolymerization of waste polyester and its polymerization were examined. The literature review indicated that the small-scale production of waste cotton was involved in the making of regenerated Lyocell fibers by mixing low proportion of waste cotton regenerated pulp with the primary wood pulp, and that 10 000-ton scale production of chemically regenerated polyethylene terephthalate(PET) from waste PET textiles has been achieved through glycol alcoholysis-methanol ester exchange technology. However, there are still problems such as technical difficulties, high production cost, low recovery and utilization rate, poor product quality, and high degree of " waste production caused by waste treatment ". Hence, key technology development for waste textile recycling should be the focus of research emphasizing on clean recycling and high value utilization of waste cotton and polyester textiles.

Key words: textiles, waste cotton, waste polyester, chemical recycling, recycling and regeneration

CLC Number:

TS106

CHEN Long, ZHOU Zhe, ZHANG Jun, XU Shimei, NI Yanpeng. Research progress in chemical recycling of waste cotton and polyester textiles[J].Journal of Textile Research, 2022, 43(05): 43-48.

Figures/Tables 4

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References 52

[1]	废旧化纤纺织品资源再生循环技术发展战略研究报告[R]. 北京: 中国工程院, 2018.
	Research report on recycling technology development strategy of waste chemical fiber textile resources[R]. Beijing: Chinese Academy of Engineering, 2018.
[2]	中国废旧纺织品再生利用技术进展白皮书[R]. 贵阳: 中国再生资源回收利用协会, 2019.
	White paper on the progress of recycling technology of waste textile in china[R]. Guiyang: China Renewable Resources Recycling and Utilization Association, 2019.
[3]	Declaration of extra-financial perfor-mance[R/OL]. Villeneuve d'Ascq: Decathlon, 2019.
[4]	The clobal commitment 2020 progress report[R/OL]. Cowes: Ellen MacArthur Foundtion & UN Environment Programme, 2020.
[5]	BARROWCLOUGH D, DEERE Birkbeck C. Transforming the global plastics economy: the political economy and governance of plastics production and pollution[R/OL]. Oxford: GEG Working Paper, 2020.
[6]	赵国樑. 我国废旧纺织品综合再利用技术现状及展望[J]. 北京服装学院学报 (自然科学版), 2019, 39(1): 95-100.
	ZHAO Guoliang. Current situation and prospect of comprehensive recycling technology of waste textiles in China[J]. Journal of Beijing Institute of Fashion Technology (Natural Science Edition), 2019, 39(1): 95-100.
[7]	BUKHARI M A, CARRASCO-GALLEGO R, PONCE-CUETO E. Developing a national programme for textiles and clothing recovery[J]. Waste Management & Research, 2018, 36(4): 321-331.
[8]	HAHLADAKIS J N, VELIS C A, WEBER R, et al. An overview of chemical additives present in plastics: migration, release, fate and environmental impact during their use, disposal and recycling[J]. J Hazard Mater, 2018, 344: 179-199. doi: 10.1016/j.jhazmat.2017.10.014
[9]	SANDIN G, PETERS G M. Environmental impact of textile reuse and recycling: a review[J]. Journal of Cleaner Production, 2018, 184: 353-365. doi: 10.1016/j.jclepro.2018.02.266
[10]	HAMAD K, KASEEM M, DERI F. Recycling of waste from polymer materials: an overview of the recent works[J]. Polymer Degradation and Stability, 2013, 98(12): 2801-2812. doi: 10.1016/j.polymdegradstab.2013.09.025
[11]	PENSUPA N, LEU S Y, HU Y, et al. Recent trends in sustainable textile waste recycling methods: current situation and future prospects[J]. Chemistry and Chemical Technologies in Waste Valorization, 2017, 375(5): 189-228.
[12]	陈烨, 王少博, 柯福佑, 等. 废旧聚酯纤维制品资源再生循环技术发展[J]. 纺织科学研究, 2019, 8: 64-66.
	CHEN Ye, WANG Shaobo, KE Fuyou, et al. Development of recycling technology of waste polyester fiber products[J]. Textile Science Research, 2019, 8:64-66.
[13]	ELANDER M, LJUNGKVIST H. Critical aspects in design for fiber-to-fiber recycling of textiles[R/OL]. Stockholm: Mistra Future Fashion. 2016.
[14]	张帆, 杨术莉, 杜平凡. 废旧纺织品回收再利用综述[J]. 现代纺织技术, 2015, 23(6): 56-62.
	ZHANG Fan, YANG Shuli, DU Pingfan. Review on recycling and reusing of waste textiles[J]. Advanced Textile Technology, 2015, 23(6): 56-62.
[15]	LEAL Filho W, ELLAMS D, HAN S, et al. A review of the socio-economic advantages of textile recycling[J/OL]. Journal of Cleaner Production, 2019, 218: 10-20. doi: 10.1016/j.jclepro.2019.01.210
[16]	We make fashion sustainable[R/OL]. Genève, Re:newcell, 2017.
[17]	PERIYASAMY A P, MILITKY J. Sustainability in regenerated textile fibers[M]//Sustainability in the Textile and Apparel Industries. Springer, 2020: 63-95.
[18]	Lenzing unveils REFIBRA^TM breakthrough technology strengthening their commitment to the circular economy in textiles[R/OL]. [2019-3-12]. .
[19]	王萨丽. 废旧棉纺织品的溶解再生及应用拓展[D]. 上海: 东华大学, 2021:41.
	WANG Sali. Dissolution and regeneration of waste cotton textiles and its application[D]. Shanghai: Donghua University, 2021:41.
[20]	王婕, 李国栋, 梁宝仁, 等. 废旧纺织品回收再利用的现状及研究进展[J]. 齐鲁工业大学学报, 2020, 34(5):16-24.
	WANG Jie, LI Guodong, LIANG Baoren, et al. Present situation and research progress of waste textiles recycling and reuse[J]. Journal of Qilu University of Technology, 2020, 34(5):16-24.
[21]	董正. 源头绿色创新驱动行业变革:赛得利FINEX纤生代-(TM)启动仪式盛大举办[J]. 中国纺织, 2020(Z4):139.
	DONG Zheng. Source of green innovation drive industry change:sateri FINEX fiber generation born-(TM) launching ceremony held a grand[J]. China Texitles, 2020(Z4):139.
[22]	PIRJO Heikkilä T K, EETTA Saarimäki, JUKKA Pesola, et al. Recycled cotton fibres in technical and clothing applications[R]. Finland: VTT Technical Research Centre of Finland, 2019.
[23]	H&M Conscious Exclusive becomes the first retail collection to feature Circulose^®[R/OL]. (2020-1-13). .
[24]	唐山三友和Re:newcell联合推出新型粘胶短纤维 50%的原料来自回收纺织品[R/OL].(2019-10-16). .
	Tangshan sanyou and RE: newcell jointly launch new viscose staple fiber with 50% raw material from recycled textiles[R/OL].(2019-10-16). .
[25]	ASAADI S, HUMMEL M, AHVENAINEN P, et al. Structural analysis of ioncell-F fibres from birch wood[J]. Carbohydrate Polymers, 2018, 181: 893-901. doi: 10.1016/j.carbpol.2017.11.062
[26]	MEISTER G, WECHSLER M. Biodegradation of N-methylmorpholine-N-oxide[J]. Biodegradation, 1998, 9(2): 91-102. doi: 10.1023/A:1008264908921
[27]	CUISSINAT C, NAVARD P. Swelling and dissolution of cellulose: part II: free floating cotton and wood fibres in NaOH-water-additives systems[J]. Macromolecular Symposia, 2006, 244(1): 19-30. doi: 10.1002/masy.200651202
[28]	CUISSINAT C, NAVARD P, HEINZE T. Swelling and dissolution of cellulose: part IV: free floating cotton and wood fibres in ionic liquids[J]. Carbohydrate Polymers, 2008, 72(4): 590-596. doi: 10.1016/j.carbpol.2007.09.029
[29]	REFIBRA^TM technology: right out revolutionary[R/OL]. [2019-3-12]. .
[30]	BARTOLOME L, IMRAN M, CHO B G, et al. Recent developments in the chemical recycling of PET[M]. Rijeka: InTech, 2012.
[31]	KOSLOSKI-OH S C, WOOD Z A, MANJARREZ Y, et al. Catalytic methods for chemical recycling or upcycling of commercial polymers[J]. Materials Horizons, 2021, 8(4): 1084-1129. doi: 10.1039/D0MH01286F
[32]	SINHA V, PATEL M R, PATEL J V. PET waste management by chemical recycling: a review[J]. Journal of Polymers and the Environment, 2010, 18(1): 8-25. doi: 10.1007/s10924-008-0106-7
[33]	AL-SABAGH A M, YEHIA F Z, ESHAQ G, et al. Greener routes for recycling of polyethylene terephthalate[J]. Egyptian Journal of Petroleum, 2016, 25(1): 53-64. doi: 10.1016/j.ejpe.2015.03.001
[34]	ISSAM A M. A new approach to obtain Kevlar-49 from PET waste bottles[J]. Research on Chemical Intermediates, 2014, 40(8): 3033-3044. doi: 10.1007/s11164-013-1149-5
[35]	NAKAO T, CHIKATSUNE T, NAKASHIMA M, et al. Method for recycling PET bottle: US 7462649B2[P]. 2008-12-9.
[36]	ISHIHARA K, ISHIDA K, MIYAMOTO M, et al. Method for separating and recovering dimethyl terephthalate and ethylene glycol from polyester waste: US 6706843B1[P]. 2004-3-16.
[37]	余新健, 徐允武, 叶建荣, 等. 废旧聚酯纺织品化学法循环再生技术探讨[J]. 合成纤维工业, 2018, 41(4): 34-37.
	YU Xinjian, XU Yunwu, YE Jianrong, et al. Discussion on recycling technology of waste polyester textile by chemical method[J]. China Synthetic Fiber Industry, 2018, 41(4): 34-37.
[38]	余新健, 叶建荣, 徐允武, 等. 废旧涤纶纺织品的化学解聚工艺[J]. 合成纤维, 2018, 47(6): 34-36.
	YU Xinjina, YE Jianrong, XU Yunwu, et al. Chemical depolymerization of waste polyester textile[J]. Synthetic Fiber in China, 2018, 47(6): 34-36.
[39]	ROTIMI E O O, TOPPLE C, HOPKINS J. Towards a conceptual framework of sustainable practices of post-consumer textile waste at garment end of lifecycle: a systematic literature review approach[J]. Sustainability, 2021, 13(5): 2965. doi: 10.3390/su13052965
[40]	JACQUEL N, FREYERMOUTH F, FENOUILLOT F, et al. Synthesis and properties of poly(butylene succinate): efficiency of different transesterification catalysts[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49(24): 5301-12. doi: 10.1002/pola.25009
[41]	LIU X, TIAN F, ZHAO X, et al. Multiple functional materials from crushing waste thermosetting resins[J]. Mater Horiz, 2021, 8(1): 234-43. doi: 10.1039/D0MH01053G
[42]	NI Y P, LI Q T, CHEN L, et al. Semi-aromatic copolyesters with high strength and fire safety via hydrogen bonds and π-π stacking[J]. Chemical Engineering Journal, 2019, 374:694-705. doi: 10.1016/j.cej.2019.05.212
[43]	金开元, 詹伟东, 刘萍, 等. 有机无机杂化钛系催化剂的应用研究[J]. 石油化工技术与经济, 2021, 37(3):6.
	JIN Kaiyuan, ZHAN Weidong, LIU Ping, et al. Application study of organic-inorganic hybrid Titanium catalyst[J]. Technology & Economics in Petrochemicals, 2021, 37(3):6.
[44]	DI Serio M, TESSER R, FERRARA A, et al. Heterogeneous basic catalysts for the transesterification and the polycondensation reactions in PET production from DMT[J]. Journal of Molecular Catalysis A: Chemical, 2004, 212(1): 251-257. doi: 10.1016/j.molcata.2003.10.032
[45]	朱永群. 金属化合物在酯交换和缩聚反应中的催化活性[J]. 合成纤维, 1981, 5 (10): 52-59.
	ZHU Yongqun. Catalytic activity of metal compounds in transesterification and polycondensation[J]. Synthetic Fiber in China, 1981, 5 (10): 52-59.
[46]	FLORES I, DEMARTEAU J, MÜLLER A J, et al. Screening of different organocatalysts for the sustainable synthesis of PET[J]. European Polymer Journal, 2018, 104: 170-176. doi: 10.1016/j.eurpolymj.2018.04.040
[47]	孙芮. 含锑废水在上海的行业分布特征及分析[J]. 净水技术, 2020, 39(SI): 168-173.
	SUN Rui. Industrial distribution characteristics and analysis of antimony containing wastewater in Shanghai[J]. Water Purification Technology, 2020, 39(S1): 168-173.
[48]	周梅, 赵瑞方, 朱银, 等. 纺织品中的重金属问题及检测标准[J]. 中国纤检, 2019, 532(12): 96-99.
	ZHOU Mei, ZHAO Ruifang, ZHU Yin, et al. Problems and testing standards of heavy metals in textiles[J]. China Textile Inspection, 2019, 532(12): 96-99.
[49]	董冲冲, 蒋红, 俞昊, 等. 涤纶生命周期中重金属锑的来源解析及检测[J]. 纺织检测与标准, 2015(1): 25-30.
	DONG Chongchong, JIANG Hong, YU Hao, et al. Source analysis and detection of heavy metal Antimony in polyester life cycle[J]. Textile Inspection & Standard, 2015(1):25-30.
[50]	孙宾, 王鸣义. 钛系催化剂在PET合成领域的应用进展及趋势:下[J]. 纺织导报, 2019(10): 45-47.
	SUN Bin, WANG Mingyi. Technology and prospect of titanium-based catalysts in the synthesis and application of polyester:Ⅱ[J]. China Textile Leader, 2019(10): 45-47.
[51]	孙宾, 王鸣义. 钛系催化剂在聚酯合成领域的应用进展及趋势:上[J]. 纺织导报, 2019(9): 37-48.
	SUN Bin, WANG Mingyi. Application and prospect of Titanium-based catalysts in the polyester synthesis:Ⅱ[J]. China Textile Leader, 2019(9): 37-48.
[52]	张大省. 钛系催化剂在聚对苯二甲酸乙二醇酯合成中的应用[J]. 纺织导报, 2020(1): 48-52.
	ZHANG Dasheng. Application of titanium catalyst in the synthesis of polyethylene terephthalate[J]. China Textile Leader, 2020(1): 48-52.

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Research progress in chemical recycling of waste cotton and polyester textiles

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