Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (05): 26-31.doi: 10.13475/j.fzxb.20211206006

• Invited Column: Expert Opinion of the 11th China Textile Academic Conferenc • Previous Articles     Next Articles

Preparation and printing properties of castor oil-based UV-curable water-based coating ink

QI Dongming1, FAN Gaoqing1, YU Yihao2, FU Ye2, ZHANG Yan1, CHEN Zhijie3()   

  1. 1. Zhejiang Provincial Engineering Center for Green and Low-Carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Zhejiang King Label Technology Co., Ltd., Huzhou, Zhejiang 313100, China
    3. Key Laboratory of Surface Modification Technology for Polymer Materials and Electromechanical Products, Wenzhou Polytechnic, Wenzhou, Zhejiang 325035, China
  • Received:2021-12-18 Revised:2022-02-11 Online:2022-05-15 Published:2022-05-30
  • Contact: CHEN Zhijie E-mail:chenzhijie5262@163.com

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Abstract:

Waterborne polyurethane emulsions were prepared aiming at difficulty in achieve good handle and fastness through the traditional coat printing. This emulsion was produced by condensing castor oil, isophorone diisocyanate, and 2,2-bis(hydroxymethyl)butyric acid, using pentaerythritol triacrylate as a capping agent, for improved dispersibility, water resistance, and bonding fastness. Castor oil-based ultraviolet (UV)-curable waterborne coating inks were obtained by adding nano-pigments to the waterborne polyurethane emulsions. The effect and mechanism of castor oil content on the emulsion particle size, cured film performance, and water resistance were studied and analyzed. Subsequently, the castor oil-based UV-curable water-based coating ink was sprayed on polyester plain fabrics, and the surface morphology, stiffness and wet and dry friction fastness of the printed fabrics were comparatively characterized. The results obtained showed that the ink-jet printed fabric has good flexibility and color fastness under the optimum amount of castor oil 42.1%.

Key words: castor oil, polyurethane, pigment printing, ultraviolet curing, ink-jet printed fabric

CLC Number: 

  • TQ325

Fig.1

Effect of castor oil mass fraction on the particle size of polyurethane emulsion"

Fig.2

DSC curves of polyurethane film with different mass fractions of castor oil"

Tab.1

Influence of castor oil mass fraction on water absorption of polyurethane film"

蓖麻油质量分数/% 吸水率/%
30.5 8.64
36.4 6.85
42.1 3.23
47.7 3.12
53.3 3.10

Fig.3

Scanning electron micrographs of printed fabrics made of polyurethane with different mass fractions of castor oil (×2 000)"

Fig.4

Effect of CO content on stiffness of printed fabric"

Tab.2

Effect of castor oil mass fraction on dry and wet rubbing fastness of printed fabrics"

蓖麻油质量分数/% 耐摩擦色牢度/级
干 湿
30.5 2 2
36.4 4 2
42.1 4~5 4~5
47.7 4 4
53.3 4 4
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