Journal of Textile Research ›› 2023, Vol. 44 ›› Issue (07): 141-150.doi: 10.13475/j.fzxb.20221100501

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Multi-component quantitative analysis method for dyeing with reactive dyes

GUO Yuqiu1,2, ZHONG Yi1,2,3, XU Hong1,2,3, MAO Zhiping1,4,5()   

  1. 1. College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China
    2. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    3. Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
    4. Research Institute of Advanced Dyeing & Finishing Technology Co., Ltd., Taian, Shandong 271000, China
    5. National Engineering Research Center For Dyeing and Finishing of Textiles, Shanghai 201620, China
  • Received:2022-11-03 Revised:2023-04-24 Online:2023-07-15 Published:2023-08-10

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Abstract:

Objective Color matching dyes in the dyeing process has been attracting more attention, and more research efforts have been made to explore the principle and technology of color matching dyeing. The key to study the dyeing principle and promote the dyeing technology is to monitor the change of dye concentration in the dyeing process. At present, there is a lack of a mature and systematic online detection method and detection equipment. The difficulty lies in how to achieve fast and accurate online detection which offers strong applicability and a wide range of concentration detection.

Method A simple, sensitive and accurate multi-component quantitative analysis method was established by combining Raman spectroscopy with chemometrics method (partial least squares method), for simultaneous quantitative analysis of multi-components in mixed liquids. This detection method was adopted to construct a rapid detection and quantitative analysis model for the concentration of each component in the mixed dye solution of Reactive Violet 4 (RR4), Reactive Orange 4(RY4) and Reactive Black 5(RB5), and the process of dyeing cotton fabrics with different concentration ratios was monitored online. The detection limit of the components to be tested was determined according to the linear relationship between the characteristic peaks of Raman spectroscopy and the dye concentration, and the applicable concentration range of the quantitative components was determined.

Results The detection ranges of RR4, RY4 and RB5 were 0.08-15 g/L, 0.08-20 g/L and 0.05-20 g/L, respectively (Fig. 1 and 2). The quantitative analysis model of multi-component mixed system was constructed. The results showed that the correlation coefficient (R2) between the fitting value of the model and the standard value was greater than 0.99, and the values of root mean square error(RMSECV) and root mean square error of prediction (RMSEP) were smaller than 0.2. The multi-component quantitative analysis model constructed by this method offered high accuracy. Finally, the compatibility of dyes was further evaluated by detecting the concentration change of each component and the dyeing efficiency of fibers during the adsorption process of reactive dyes with divinylsulfone active group structure. Under the condition of dye dosage of 1% (o. w. f), in the RR4/RY4 mixed system, the dyeing percentage curve and S value of the two dyes were significantly different from those of the single component dyeing, but the dyeing consistency of the two dyes was stable under the experimental concentration ratio. The dyeing behaviors of RY4/RB5 and RR4/RB5 were consistent, and the difference was not significant compared with that of the single component dyeing. Therefore, it was generally believed that the three dyes selected showed good compatibility in the process of color matching and dyeing at lower dye dosage. In the mixed system of RR4/RY4, RR4 and RY4 still showed a competitive relationship when the dye dosage was 2% (o. w. f), but the dyeing synchronicity was not much different and the compatibility was still good. In the mixed system of RY4/RB5 and RR4/RB5, the dyeing percentage of single component fluctuated greatly and the compatibility became worse.

Conclusion The concentration range of Raman spectroscopy is found limited. When the dye concentration is too low, the sample content is low and the spectral signal is weak. When the dye concentration is too high, the fluorescence characteristics of the dye itself will affect the intensity and accuracy of the Raman spectral signal, and even fluorescence quenching occurs, making the Raman spectral signal annihilate, and limiting the detectable concentration range. Then, the study on the compatibility of reactive dyes with divinylsulfone active group structure shows that the structure and mass ratio of the mixed dyes will affect the dyeing process of a single component. Therefore, the compatibility can be evaluated according to the actual dyeing process of each component dye, so as to further guide the dye formulation design.

Key words: Raman spectroscopy, multi-component quantitative analysis model, reactive dye, matching dyeing, cotton fabric

CLC Number: 

  • O657.37

Fig. 1

Raman spectrum of RR4, RY4 and RB5 reactive dyes. (a) Full Raman spectrum of RR4; (b) Full Raman spectrum of RY4; (c) Full Raman spectrum of RB5; (d) Local Raman spectrum of RY4 at 1 595.124 cm-1; (e) Local Raman spectrum of RY4 at 1 584.581 cm-1; (f) Local Raman spectrum of RB5 at 1 156.856 cm-1"

Fig. 2

Mass concentration standard curves of RR4, RY4 and RB5 reactive dyes"

Tab. 1

Parameters of binary and ternary mixture models and their prediction results"

预处理方法 混合组分 校正集参数 预测集参数
PCs RMSECV R2 RMSEP R2
一阶导数预处理 RR4/RY4 RR4 3 0.132 0 0.997 0 0.125 0.996 2
RY4 4 0.112 0 0.997 2 0.127 0.996 8
RY4/RB5 RY4 6 0.096 2 0.998 3 0.170 0.993 9
RB5 5 0.083 4 0.997 9 0.175 0.994 8
RB5/RR4 RB5 3 0.145 0 0.996 5 0.156 0.993 6
RR4 5 0.128 0 0.997 5 0.128 0.992 8
一阶导数加光谱
平滑预处理		 RR4/RY4 RR4 3 0.135 0 0.996 8 0.125 0.996 0
RY4 4 0.115 0 0.997 0 0.131 0.996 2
RY4/RB5 RY4 7 0.084 6 0.998 7 0.154 0.994 4
RB5 5 0.083 4 0.997 8 0.173 0.994 9
RB5/RR4 RB5 3 0.144 0 0.996 4 0.152 0.993 9
RR4 5 0.125 0 0.997 5 0.124 0.993 1

Fig. 3

Dyeing percentage of low concentration single component dyeing"

Fig. 4

Dyeing percentage of low concentration RR4/RY4 color matching system and S values"

Fig. 5

Dyeing percentage of low concentration RY4/RB5 color matching system and S values"

Fig. 6

Dyeing percentage of low concentration RB5/RR4 color matching system and S values"

Fig. 7

Dyeing percentage (a) and S values (b) of high concentration single component dyeing"

Fig. 8

Dyeing percentage of high concentration RR4/RY4 color matching system and S value"

Fig. 9

Dyeing percentage of high concentration RY4/RB5 color matching system and S value"

Fig. 10

Dyeing percentage of high concentration RB5/RR4 color matching system and S value"

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