茜草色素对生物基聚酰胺56的染色性能

doi:10.13475/j.fzxb.20230202001

Abstract

Abstract:

Objective Madder pigment is a natural dye of bright red color with stable performance. Bio-based polyamide 56 (PA56)is an environment-friendly and excellent bio-based polyamide material. In this research, madder pigment was adopted to dye PA56 fabrics, the dyeing process was optimized,and the dyeing kinetic mechanism was studied. The research results provide a theoretical basis for the application of madder natural dyes to bio-based PA56 fabrics. Furthermore, applying natural dyes to bio-based materials would meet the requirements of circular economy and low-carbon sustainable development.

Method In order to study the dyeing performance of madder on PA56 fabric, the parameters including pH, dyeing time, dyeing temperature and mass fraction of Peregal O were explored to find the optimal conditions. Through K/S value and color characteristics, the influences of mordants and mordant treatment processes were studied. The optimal conditions obtained were subsequently adopted to study the kinetic of madder pigment dyeing. Pseudo first-order and pseudo second-order kinetic models were adopted to examine the mechanism of the adsorption process. Kinetic parameters of madder pigment dyeing on PA56 fiber with different temperature, pH, auxiliaries and mordant were calculated.

Results The results showed that the optimum process for dyeing bio-based PA56 fabrics with madder pigment was as follows: dyeing pH value is 4.2, dyeing temperature is 80 ℃, dyeing time is 40 min and the amount of Peregal O is 1 g/L. After mordant dyeing, the K/S values of the dyed fabrics were significantly increased, and the color characteristics of dyed fabric changes obviously. Compared with the direct dyed fabric, the color fastness of the mordant dyed fabric has been improved. The kinetics of adsorption for different dye temperatures were evaluated by the pseudo first-order and second-order models. A large equilibrium adsorption density difference between the experiment and calculation was observed for the pseudo first-order model, indicating a poor pseudo first-order fit to the experimental data. The experimental data fitted well to the pseudo second-order kinetic model with high correlation coefficient above 0.999. In addition, the C_∞ agreed well with both experiment and calculation, suggesting that the second-order kinetic model well describes the adsorption of madder pigment onto PA56 fiber. The half-dyeing time decreased,and the diffusion coefficient increased with increasing temperature. The influences of dyeing pH, auxiliaries and mordant on the dyeing kinetic parameters were further analyzed. With the increase of pH value, the equilibrium adsorption amount decreased, the half-dyeing time was shortened,and the diffusion coefficient was increased. The addition of sodium sulfate and Peregal O reduced the equilibrium dyeing amount and the half-dyeing time of maddering dye. The rate constant (k₂) and the diffusion coefficient were increased with the addition of sodium sulfate and Peregal O. After mordant dyeing, the equilibrium adsorption amount was decreased, the half-dyeing time increased and the diffusion coefficient decreased, but K/S values of the dyed fabrics were increased.

Conclusion The optimal conditions and dyed fabric with darker color of bio-based PA56 dyed with madder pigment were obtained. The type and mode of mordant can enrich the color tone and improve the color fastness. Fitting calculations reveal that the dyeing process of madder pigment dyeing on bio-based PA56 fabrics conforms to the pseudo second order kinetic model. Madder has a fast adsorption rate on PA56 fabric. The adsorption capacity was dependent with pH value. The addition of sodium sulfate and Peregal O, as well as the pretreatment with mordant, the dyeing processes also conform to the quasi-second order kinetic model.

Key words: natural dye, madder pigment, bio-based polyamide 56, dyeing, kinetics

CLC Number:

TS193.2

HUANG Lianxiang, WANG Xiangrong, HOU Xueni, QIAN Qinfang. Dyeing properties of madder pigment on bio-based polyamide 56[J].Journal of Textile Research, 2024, 45(07): 94-103.

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URL: http://www.fzxb.org.cn/EN/10.13475/j.fzxb.20230202001

http://www.fzxb.org.cn/EN/Y2024/V45/I07/94

Figures/Tables 17

Fig.1

Tab.1

Fig.2

Tab.2

Tab.3

Fig.3

Fig.4

Fig.5

Tab.4

Quasi-first-order and quasi-second-order kinetic parameters of madder pigment dyeing on PA56 fiber"

温度/℃	准一级动力学参数					准二级动力学参数
温度/℃	回归方程	R²	C_∞,exp/ (mg·g^-1)	C_{∞, cal}/ (mg·g^-1)	k₁/ min^-1	回归方程	R²	C_∞,exp/ (mg·g^-1)	C_{∞, cal}/ (mg·g^-1)	k₂/ (g $·$ mg^-1 $·$ min^-1)
60	y=-0.033x+1.626	0.815	16.81	5.09	0.03	y=0.058x+0.132	0.999	16.81	17.39	0.03
70	y=-0.031x+0.956	0.666	16.99	2.61	0.03	y=0.058x+0.055	0.999	16.99	17.21	0.06
80	y=-0.040x+1.000	0.779	17.35	2.72	0.04	y=0.057x+0.044	0.999	17.35	17.57	0.07

Tab.4

Tab.5

Fig.6

Tab.6

Quasi-second-order kinetic parameters of madder pigment dyeing on PA56 fiber at different pH values"

pH值	回归方程	R²	C_∞,exp/ (mg·g^-1)	C_{∞, cal}/ (mg·g^-1)	k₂/ (g $·$ mg^-1 $·$ min^-1)	t_1/2/min	D/ (m²·min^-1)
3.2	y=0.058x+0.084	0.999	17.05	17.24	0.04	1.44	2.55×10^-12
4.2	y=0.057x+0.044	0.999	17.35	17.54	0.07	0.77	3.09×10^-12
5.2	y=0.062x+0.045	0.999	15.83	16.05	0.09	0.72	4.78×10^-12
6.2	y=0.087x+0.058	0.999	11.49	11.52	0.13	0.67	5.10×10^-12

Tab.6

Fig.7

Tab.7

Quasi-second-order kinetic parameters of madder pigment dyeing on PA56 fiber with different dyeing auxiliaries"

助剂	回归方程	R²	C_∞,exp/ (mg·g^-1)	C_{∞, cal}/ (mg·g^-1)	k₂/ (g $·$ mg^-1 $·$ min^-1)	t_1/2/ min	D/ (m²·min^-1)	K/S值	λ_max/ nm
无助剂	y=0.057+0.044	0.999	17.35	17.54	0.07	0.77	4.78×10^-12	2.24	400
元明粉	y=0.068x+0.026	0.999	14.33	14.68	0.18	0.38	9.66×10^-12	2.17	400
平平加O	y=0.081x+0.058	0.999	12.28	12.38	0.11	0.72	5.13	2.14×10^-12	400

Tab.7

Fig.8

Fig.9

Tab.8

Quasi-second-order kinetic parameters of mordants on PA56 fiber dyed with madder pigment"

媒染剂	回归方程	R²	C_∞,exp/ (mg·g^-1)	C_{∞, cal}/ (mg·g^-1)	k₂/ (g $·$ mg^-1 $·$ min^-1)	t_1/2/ min	D/ (m²·min^-1)	K/S值	λ_max/ nm
直接染色	y=0.057x+0.044	0.999	17.35	17.54	0.07	0.77	4.78×10^-12	1.76	400
硫酸铝预媒染	y=0.080x+0.079	0.999	12.29	12.47	0.08	0.96	3.74×10^-12	3.56	510
硫酸亚铁预媒染	y=0.065x+0.117	0.999	15.31	15.34	0.04	1.79	2.06×10^-12	7.54	560

Tab.8

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平平加O质量浓度/ (g·L^-1)	K/S值	S_λ	λ_max/nm
0.5	2.12	0.024	400
1.0	2.14	0.020	400
1.5	2.05	0.018	400
2.0	2.05	0.017	400

染色方式	L^*	a^*	b^*	C^*	h/ (°)	λ_max/ nm	K/S值
直接染色	55.76	8.32	3.21	8.92	21.09	400	1.76
硫酸铝预媒染	50.20	28.80	10.50	30.66	20.03	510	3.56
硫酸铝同浴媒染	49.07	38.33	1.37	38.36	2.05	510	4.39
硫酸铝后媒染	50.80	28.02	12.10	30.52	23.37	510	3.12
硫酸铝预媒染	31.55	6.66	-9.51	11.62	305.01	560	7.54
硫酸亚铁同浴媒染	43.16	11.33	14.47	18.38	308.06	560	3.57
硫酸亚铁后媒染	36.25	5.90	-5.87	8.32	315.12	560	5.26

染色方式	耐光色牢度	耐皂洗色牢度			耐摩擦色牢度
染色方式	耐光色牢度	变色	棉沾	锦沾	干	湿
硫酸铝预媒染	4	4	4~5	4~5	4	3~4
硫酸铝同浴媒染	4	4	4~5	4~5	4	3~4
硫酸铝后媒染	3	4	4~5	4~5	4	4
硫酸亚铁预染媒	4	4	4~5	4~5	4	4
硫酸亚铁同浴媒染	3	4	4~5	4~5	4	3~4
硫酸亚铁后媒染	4	4	4~5	4~5	4	4
直接染色	2	3	4~5	4~5	4	4

Dyeing properties of madder pigment on bio-based polyamide 56

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温度/℃	半染时间t_1/2/min	扩散系数D/(m²·min^-1)
60	2.30	1.60 × 10^-12
70	0.95	3.88 × 10^-12
80	0.77	4.77 × 10^-12

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