Journal of Textile Research ›› 2024, Vol. 45 ›› Issue (02): 162-170.doi: 10.13475/j.fzxb.20231008201

• Dyeing and Finishing Engineering • Previous Articles     Next Articles

Preparation and properties of flame-retardant polyester-cotton fabrics with chitosan-based intumescent flame retardant system

LI Ping1,2,3,4,5, ZHU Ping1,2,3,4,5, LIU Yun1,2,3,4,5()   

  1. 1. College of Textiles & Clothing, Qingdao University, Qingdao, Shandong 266071, China
    2. Institute of Functional Textiles and Advanced Materials, Qingdao University, Qingdao, Shandong 266071, China
    3. National Engineering Research Center for Advanced Fire-Safety Materials D & A (Shandong), Qingdao University, Qingdao, Shandong 266071, China
    4. State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, Shandong 266071, China
    5. Qingdao Key Laboratory of Flame-Retardant Textile Materials, Qingdao University, Qingdao, Shandong 266071, China
  • Received:2023-10-24 Revised:2023-11-27 Online:2024-02-15 Published:2024-03-29

Abstract:

Objective Polyester/cotton (T/C 65/35) fabrics have been widely used in both clothing and industrial fields, because of their great moisture absorption and breathability associated with cotton fibres and good mechanical property provided by polyester fibres. However, T/C fabrics are extremely flammable and hard to be flame-retardant, because the special ″scaffolding effect″ of polyester and cotton can arise violent flame, large amount of heat and copious smoke. Therefore, T/C fabrics used in public places such as curtains, need to meet the flame-retardant requirements to can reduce the fire risk.

Method To prepare polyester/cotton (T/C,65/35) fabrics that are flame-retardant and meet practical application requirements, chitosan (CS) and γ-piperazinyl propylmethyl dimethoxy silane (GP-108) were utilized to prepare flame-retardant T/C fabrics through one-step dip-coating method, and the micromorphology, thermal stability, flame retardancy, tensile strength, flame-retardant mechanism and whiteness of T/C fabrics and flame-retardant T/C fabrics were studied.

Results The results showed that PCS/GP coatings successfully formed a film on the surface of T/C fabrics and enveloped both polyester and cotton fibers. T/C-PCS/GP exhibited a typical thermal degradation process of polyester-cotton fabrics with char residues value of 28.5% retained at 700 ℃, indicating that the PCS/GP coatings improved the thermal stability of flame-retardant T/C fabrics in the high temperature zone. The LOI value of T/C-PCS/GP was increased to 26.5%, achieving self-extinguishing during the vertical flame test(VFT). The scanning electron microscopy (SEM) photos of char residues after VFT showed that PCS/GP eliminated the scaffolding effect of polyester-cotton fabrics. The peak heat release rate and fire growth index of T/C-PCS/GP were decreased by 20% and 40% respectively compared with those of T/C fabrics, indicating a significant reduction in fire hazard. The SEM pictures of char residues after CCT showed that polyester in T/C fabrics was completely melted, while T/C-PCS/GP kept the original shape of fibers and presented perfect intumescent flame-retardant char layers. T/C-PCS/GP underwent the thermal degradation processes in advance compared with T/C fabrics, because of the catalysis effect of phosphoric acid. However, T/C-PCS/GP released less volatiles at the maximum thermal degradation temperature and barely no gas products release during the high temperature zoon. T/C-PCS showed decreased tensile strength compared with T/C, while owing to the addition of GP-108, T/C-PCS/GP obtained better tensile strength compared with T/C-PCS. Meanwhile, the use of GP-108 solved the yellowing problem of T/C-PCS and increased the whiteness of T/C-PCS/GP.

Conclusion The results showed that an eco-friendly flame-retardant coating had deposited on the surface of T/C fabrics which presented ideal flame retardancy, mechanical property and whiteness. PCS/GP coatings are capable of endowing T/C fabrics with great flame retardancy through establishing instrument flame-retardant char layers after heating. Fortunately, T/C-PCS/GP showed decreased fire hazard. For the utilization of GP-108, the damage of tensile strength associated with PCS had been avoided and the whiteness of T/C-PCS/GP was better than that of T/C-PCS. The design of PCS/GP was hopeful to provide more stratagems for the intumescent flame-retardant system with environmental materials. Meanwhile, the application of silane agent solved the decreasing tensile strength and whiteness owing to PCS. This work was lack of analysis containing the original properties of T/C, such as hand feeling, which played a key role on the practical application of flame-retardant T/C.

Key words: polyester/cotton blended fabric, flame-retardant finishing, chitosan, intumescent flame retardant system, silane coupling agent

CLC Number: 

  • TS195.2

Fig. 1

SEM images of T/C, T/C-PCS, T/C-GP and T/C-PCS/GP at different magnifications"

Fig. 2

TG(a) and DTG(b) curves of T/C and flame-retardant T/C samples under N2 atmosphere"

Tab. 1

TG and DTG data of samples under N2 atmosphere"

样品名称 T5%/
Tmax1/
Rmax1/
(%·℃-1)
Tmax2/
Rmax2/
(%·℃-1)
700 ℃
时残炭
量/%
T/C 330 366 0.58 426 0.73 0.0
T/C-PCS 222 281 0.19 417 0.56 28.1
T/C-GP 280 - - 394 0.61 21.5
T/C-PCS/GP 231 279 0.19 418 0.55 28.5

Fig. 3

TG(a) and DTG(b) curves of T/C and flame-retardant T/C samples under air atmosphere"

Tab. 2

TG and DTG data of samples under air atmosphere"

样品名称 T5%/
Tmax1/
Rmax1/
(%·℃-1)
Tmax2/
Rmax2/
(%·℃-1)
Tmax3/
Rmax3/
(%·℃-1)
700 ℃时残
炭量/%
T/C 323 354 0.58 420 0.68 533 0.16 0.0
T/C-PCS 226 282 0.20 420 0.61 546 0.12 28.1
T/C-GP 266 - - 420 0.67 534 0.15 21.5
T/C-PCS/GP 195 301 0.17 423 0.57 543 0.11 28.5

Fig. 4

Photos of T/C and flame-retardant T/C fabrics after VFT and SEM images of char residues at different magnifications"

Tab. 3

VFT and LOI data of T/C and flame-retardant T/C fabrics"

样品
名称
续燃时
间/s
阴燃时
间/s
损毁长
度/cm
LOI值/
%
T/C 17±2 6±1 30.0 17.6
T/C-PCS 0 0 7.8 27.3
T/C-GP 14±3 0 30.0 19.7
T/C-PCS/GP 0 0 8.4 26.5

Fig. 5

HRR (a) and THR (b) curves of T/C and flame-retardant T/C blended samples"

Tab. 4

Relative data of T/C and flame-retardant T/Cfabrics obtained from CCT"

样品名称 TTI/s PHRR/
(kW·m-2)
TPHRR/
s
THR/
(MJ·m-2)
TSP/
m2
T/C 18 149 40 5.6 0.9
T/C-PCS 57 120 75 4.3 1.2
T/C-GP 17 178 45 6.3 1.5
T/C-PCS/GP 34 119 55 5.0 1.1

Fig. 6

SPR (a), TSP (b), COP (c), and CO2P (d) curves of T/C and flame-retardant T/C samples"

Fig. 7

SEM images of char residues after CCT for T/C and T/C-PCS/GP"

Fig. 8

FT-IR spectra at different temperature of T/C (a) and T/C-PCS/GP (b) during thermal degradation process"

Fig. 9

Tensile strength of T/C and flame-retardant T/C samples"

Tab. 5

Whiteness of T/C and flame-retardant T/C"

样品名称 白度值/%
T/C 81.62±0.07
T/C-PCS 67.05±0.10
T/C-GP 76.00±0.01
T/C-PCS/GP 77.02±0.07
[1] ALONGI J, CAROSIO F, KIEKENS P. Recent advances in the design of water based-flame retardant coatings for polyester and polyester-cotton blends[J]. Polymers, 2016, 8(10): 357.
doi: 10.3390/polym8100357
[2] 徐英俊, 王芳, 倪延朋, 等. 纺织品的阻燃及多功能化研究进展[J]. 纺织学报, 2022, 43(2): 1-9.
XU Yingjun, WANG Fang, NI Yanpeng, et al. Research progress on flame-retardation and multi-functionalization of textiles[J]. Journal of Textile Research, 2022, 43(2): 1-9.
doi: 10.1177/004051757304300101
[3] WANG B, LIU Jianglong, XU Yingjun, et al. Flame retardation of polyester/cotton blended fabrics via intumescent sol-gel coatings[J]. Polymer Degradation and Stability, 2022. DOI:10.1016/j.polymdegradstab.2022.110115.
[4] LIU Longxiang, PAN Ying, WANG Zhou, et al. Layer-by-layer assembly of hypophosphorous acid-modified chitosan based coating for flame-retardant polyester-cotton blends[J]. Industrial & Engineering Chemistry Research. 2017, 56(34): 9429-9436.
doi: 10.1021/acs.iecr.7b02303
[5] FANG Yinchun, SUN Weihao, LI Junwei, et al. Eco-friendly flame retardant and dripping-resistant of polyester/cotton blend fabrics through layer-by-layer assembly fully bio-based chitosan/phytic acid coating[J]. Internationl Journal of Biological Macromolecules, 2021, 175: 140-146.
[6] CHEN Qin, ZHAO Tao. The thermal decomposition and heat release properties of the nylon/cotton, polyester/cotton and Nomex/cotton blend fabrics[J]. Textile Research Journal, 2016, 86(17): 1859-1868.
doi: 10.1177/0040517515617423
[7] 方寅春, 陈吕鑫, 李俊伟. 阻燃超疏水涤/棉混纺织物的制备及其性能[J]. 纺织学报, 2022, 43(11): 113-118.
FANG Yinchun, CHEN Lüxin, LI Junwei. Preparation and properties of flame retardant and superhydrophobic polyester/cotton fabrics[J]. Journal of Textile Research, 2022, 43(11): 113-118.
[8] 荣智, 陈启杰, 赵雅兰, 等. 生物基绿色阻燃剂的研究进展[J]. 现代化工, 2020, 40(7): 50-54.
RONG Zhi, CHEN Qijie, ZHAO Yalan, et al. Research progress in bio-based green flame retardants[J]. Modern Chemical Industry, 2020, 40(7): 50-54.
[9] 王彬. 含磷、氮、硅聚电解质复合物表面阻燃涤棉织物研究[D]. 青岛: 青岛大学, 2021: 53-70.
WANG Bin. Phosphorus/nitrogen/silicon-containing polyelectrolyte complexes for flame-retardant surface treatments of polyester/cotton blended fabrics[D]. Qingdao: Qingdao University, 2021: 53-70.
[10] 黄益婷. 含磷阻燃剂对涤/棉混纺织物的阻燃整理[D]. 苏州: 苏州大学, 2022: 46-48.
HUANG Yiting. The flame retardant tretment of T/C blended fabrics by phosphorus-containing flame retardants[D]. Suzhou: Soochow University, 2022: 46-58.
[11] CAIN A A, MURRAY S, HOLDER K M, et al. Intumescent nanocoating extinguishes flame on fabric using aqueous polyelectrolyte complex deposited in single step[J]. Macromolecular Material and Engineering, 2014, 299(10): 1180-1187.
[12] QI L Y, CAI W, ZHANG W, et al. Application of silver-loaded halloysite nanotubes in flame retardant and smoke-suppressive coating for polyester-cotton fabric[J]. ACS Applied Materials & Interfaces, 2023, 15(19): 23725-23735.
[13] 蒋琦, 刘云, 朱平. 茶多酚基阻燃/防紫外线棉织物的制备及其性能[J]. 纺织学报, 2023, 44(2): 222-229.
JIANG Qi, LIU Yun, ZHU Ping. Preparation and properties of flame retardant/anti-ultraviolet cotton fabrics with tea polyphenol based flame retar-dants[J]. Journal of Textile Research, 2023, 44(2): 222-229.
[1] XIAO Hao, SUN Hui, YU Bin, ZHU Xiangxiang, YANG Xiaodong. Preparation of chitosan-SiO2 aerogel/cellulose/polypropylene composite spunlaced nonwovens and adsorption dye performance [J]. Journal of Textile Research, 2024, 45(02): 179-188.
[2] FAN Shuo, YANG Peng, ZENG Jinhao, SONG Xiaodi, GONG Yudan, XIAO Yao. Preparation of multi-component organic polysiloxane for flame retardancy of polyamide 6 fabrics with anti-dripping behavior [J]. Journal of Textile Research, 2024, 45(01): 152-160.
[3] LEI Caihong, YU Linshuang, JIN Wanhui, ZHU Hailin, CHEN Jianyong. Preparation and application of silk fibroin/chitosan composite fiber membrane [J]. Journal of Textile Research, 2023, 44(11): 19-26.
[4] ZHANG Guangzhi, YANG Fusheng, FANG Jin, YANG Shun. One bath flame retardant finishing of polylactic acid nonwoven by phytic acid/chitosan/boric acid [J]. Journal of Textile Research, 2023, 44(10): 120-126.
[5] SHAO Yanzheng, SUN Jianghao, WEI Chunyan, LÜ Lihua. Preparation and properties of adsorption fiber made from cotton stalk bark microcrystalline cellulose/modified chitosan [J]. Journal of Textile Research, 2023, 44(08): 18-25.
[6] JIANG Zhiming, ZHANG Chao, ZHANG Chenxi, ZHU Ping. Preparation and properties of flame-retardant viscose fabrics modified with phosphated polyethyleneimine [J]. Journal of Textile Research, 2023, 44(06): 161-167.
[7] YANG Haifu, LUO Lijuan, SHI Jianjun, MA Xiaoguang, ZHENG Zhenrong. Preparation of flame-retardant and waterproof multifunctional polyester tarpaulin [J]. Journal of Textile Research, 2023, 44(06): 168-174.
[8] DI Youbo, CHEN Xieyang, YAN Zhifeng, YIN Xuan, QIU Chunli, MA Weiliang, ZHANG Xiangbing. Iron ion removal from seed hemp pulp based on synergistic effect of chitosan and polyvinyl alcohol [J]. Journal of Textile Research, 2023, 44(06): 175-182.
[9] YI Jingyuan, PEI Liujun, ZHU He, ZHANG Hongjuan, WANG Jiping. Study on disperse dye staining on polyester/cotton blended fabrics in non-aqueous medium dyeing system [J]. Journal of Textile Research, 2023, 44(05): 29-37.
[10] DU Xun, CHEN Li, HE Jin, LI Xiaona, ZHAO Meiqi. Preparation and properties of colorimetric sensing nanofiber membrane with wound monitoring function [J]. Journal of Textile Research, 2023, 44(05): 70-76.
[11] FANG Yinchun, CHEN Lüxin, LI Junwei. Preparation and properties of flame retardant and superhydrophobic polyester/cotton fabrics [J]. Journal of Textile Research, 2022, 43(11): 113-118.
[12] HUANG Yiting, CHENG Xianwei, GUAN Jinping, CHEN Guoqiang. Phosphorus/nitrogen-containing flame retardant for flame retardant finishing of polyester/cotton blended fabric [J]. Journal of Textile Research, 2022, 43(06): 94-99.
[13] SHAO Lingda, HUANG Jinbo, JIN Xiaoke, TIAN Wei, ZHU Chengyan. Effect of silane coupling agent modification on properties of glass fiber fabric reinforced polyphenylene sulfide composites [J]. Journal of Textile Research, 2022, 43(04): 68-73.
[14] ZHOU Tianbo, ZHENG Huanda, CAI Tao, YU Zuojun, WANG Licheng, ZHENG Laijiu. One-bath dyeing of polyester/cotton blended fabrics in supercritical CO2 with Reactive Disperse Yellow dye [J]. Journal of Textile Research, 2022, 43(03): 116-122.
[15] WANG Chenmeizi, WANG Ling, ZHANG Qingle, WANG Ying, XIA Xin. Preparation and property of composite hydrogel nonwoven based fresh-keeping material [J]. Journal of Textile Research, 2022, 43(03): 132-138.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!