Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (09): 122-127.doi: 10.13475/j.fzxb.20181205906

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and application of polyacrylate/rhodamine B composite latex by miniemulsion polymerization

XIANG Wei(), YANG Honglin, QUAN Qiongying   

  1. Jianhu Institute, Zhejiang Industry Polytechnic College, Shaoxing, Zhejiang 312000, China
  • Received:2018-12-26 Revised:2019-06-18 Online:2019-09-15 Published:2019-09-23

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Abstract:

In order to improve the stability of rhodamine B in water, polyacrylate/rhodamine B composite latex was prepared by miniemulsion polymerization and the property of polyacrylate/rhodamine B composite latex was also discussed. The particle size, Zeta potential, morphological structure and fluorescenct performance of rhodamine B solution and composite latex were tested by particle size analysis, transmission electron microscopy, X-ray diffractometry and fluorescence spectrometry, respectively. The influences of composite latex mass percent and binder mass percent on the fluorescent properties of cotton fabrics were discussed as application of polyacrylate/rhodamine B composite latex on the cotton fabrics by scraping. It is found that the average particle size and Zeta potential of polyacrylate/rhodamine B composite latex are 86.2 nm and -54.7 mV, respectively. The dispersion stability and fluorescent performance of composite latex are enhanced. The K/S values and fluorescent reflectance of cotton fabrics are higher, and the washing fastness and rubbing fastness reaches grade 4 and 3-4 under the condition of the mass percent of latex 10% and the binder mass percent of latex 20%, respectively.

Key words: miniemulsion polymerization, composite latex, fluorescence property, polyacrylate, rhodamine B

CLC Number: 

  • TS194.9

Tab.1

Average particle sizes and Zeta potential of composite latex at different weight contents of rhodamine B"

罗丹明B
质量分数/%		 平均粒径/
nm		 PDI Zeta电位值/
mV
0.4 70.3 0.053 -50.7
0.6 78.0 0.488 -45.8
0.8 85.8 0.515 -44.0
1.0 89.8 0.483 -37.2
1.2 116.5 0.588 -27.2

Fig.1

Diagrams of different structures. (a) Rhodamine B;(b)Polyacrylate/rhodamine B composite latex"

Tab.2

Average particle sizes and Zeta potential of composite latex at different contents of emulsifier"

乳化剂质量
分数/%		 平均粒径/
nm		 PDI Zeta电位值/
mV
0.4 89.8 0.483 -37.2
2.0 88.4 0.501 -45.6
4.0 87.1 0.377 -49.9
6.0 86.2 0.324 -54.7

Fig.2

TEM images of polyacrylate/rhodamine B composite latex at different magnifications"

Fig.3

XRD patterns of rhodamine B and polyacrylate/rhodamine B composite latex"

Fig.4

Fluorescence spectra of polyacrylate/rhodamine B composite latex at different contents of rhodamine B"

Tab.3

Influence of different composite latex contents on fluorescent reflectance of fabrics"

复合乳胶质量分数/% K/S值 ΔR/%
5 0.882 7 3.92
10 1.578 6 5.05
15 2.150 8 3.15
20 2.616 1 1.67
25 3.406 1 1.66

Tab.4

Influence of different binder contents on fluorescent reflectance of fabrics"

黏合剂质量分数/% K/S值 ΔR/%
5 1.598 5 5.27
10 1.532 4 5.23
20 1.578 6 5.05
30 1.467 8 5.02
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