Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (08): 128-134.doi: 10.13475/j.fzxb.20201007107

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation of aramid fiber supported BiOBr composite materials and its photocatalytic degradation of dyeing wastewater

ZHANG Yuhan1, SHEN Guodong1,2, FAN Wei1,3, SUN Runjun1,3()   

  1. 1. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    2. School of Materials Science & Engineering, Shaanxi University of Science & Technology, Xi'an, Shaanxi 710021, China
    3. State Key Laboratory of Intelligent Textile Material and Products, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
  • Received:2020-10-29 Revised:2021-03-26 Online:2021-08-15 Published:2021-08-24
  • Contact: SUN Runjun E-mail:shenguodong@xpu.edu.cn

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Abstract:

Aramid fiber (AF) supported BiOBr composite materials (BiOBr/AF) were prepared by the solvothermal method to solve the easy agglomeration and difficult recycling during degrading textile printing and dyeing wastewater by powder photocatalyst. The morphology and microstructure of the BiOBr/AF were characterized and analyzed, and the deep photocatalytic degradation performance of simulated dyeing wastewater by BiOBr/AF under visible light irradiation was also studied. The results show that the thick sheets of BiOBr with regular morphology are uniformly grown on the surface of AF by using ethylene glycol as solvent, citric acid as chelating agent and AF as supporting matrix at 160 ℃ for 12 h. BiOBr/AF has good deep degradation performance to the simulated dyeing wastewater of Direct Lake Blue 5B, Weak Acid Brilliant Blue A and Reactive Light Yellow K-4S. The degradation rates to all target dyes are more than 98%. In addition, BiOBr/AF presents good recycling stability. The chemical oxygen demand and biochemical oxygen demand degradation efficiency are higher than 70%, which meets the requirements for the emission limits of textile dyeing and finishing industrial water pollutants.

Key words: aramid fiber, photocatalytic degradation, solvothermal method, dyeing wastewater treatment

CLC Number: 

  • TS151

Fig.1

Dyeing process. (a) Dyeing cotton fabric with Direct Lake Blue 5B dye; (b) Dyeing power spinning silk fabric with Weak Acid Brilliant Blue A dye; (c) Dyeing mercerizing bleach cotton fabric with Reactive Lright Yellow K-4S dye"

Fig.2

XRD patterns of BiOBr,AF and BiOBr/AF samples"

Fig.3

SEM and TEM images of BiOBr, AF and BiOBr/AF samples. (a) BiOBr; (b) Untreated AF; (c) Plasma-etched AF; (d) BiOBr/AF; (e) TEM and SEAD image of BiOBr/AF; (f) HR-TEM image of BiOBr/AF"

Fig.4

UV-Vis DRS (a) and Eg (b) image of BiOBr"

Fig.5

Degradation effect of BiOBr/AF over dyeing wastewater(a) and COD and BOD(b)"

Fig.6

Effect of BiOBr/AF on cycling degradation of three kinds of simulated dyeing wastewater"

Fig.7

Schematic diagram of photocatalytic degrading organic dye mechanism by BiOBr/AF"

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