Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (04): 177-184.doi: 10.13475/j.fzxb.20180203008

• Comprehensive Review • Previous Articles    

Review on novel halogen-free polymer flame retardants

LI Qianglin1,2(), HUANG Fangqian2, XIAO Xiuchan1, QIU Cheng1, WU Juzhen1   

  1. 1. Center of Big Data for Smart Environmental Protection, Chengdu Technological University,Chengdu, Sichuan 611730, China
    2. Chengdu Textile College, Chengdu, Sichuan 611731, China
  • Received:2018-02-08 Revised:2018-12-14 Online:2019-04-15 Published:2019-04-16

RichHTML

8

PDF (PC)

252

Abstract:

In order to improve the durability and washable resistance of flame retardant textiles, and avoid the generation of secondary pollutants such as dioxins and hydrogen halides at high temperature for conventional halogenated flame retardants, using halogen-free polymer flame retardant is one of the effective methods. This paper systematically described a series of branched, linear and crosslinked polymer flame retardants and their monomers containing flame retardant elements such as phosphorus, nitrogen and silicon. The types, structures, synthesis, properties and applications of polymer flame retardants such as phosphates (phosphonates), phosphoramides (phosphonamides), phosphorus-containing polysiloxane and bio-based flame retardants were mainly introduced. The current problems of flame retardants for textiles were analyzed. It was pointed out that the durable flame retardant should focus on the synthesis of eco-friendly flame retardants with high phosphorus-nitrogen content and high reactivity, and should increase the research on synergistic mechanism of multi-component compounds, and accelerate the research direction of modern physical finishing technology research.

Key words: flame retardant textile, halogen-free flame retardant, bio-based flame retardant, coating, polymer

CLC Number: 

  • TS106.5

Fig.1

Schematic diagrame of graft reaction for preparation of branched-chain polymatic flame retardant"

Fig.2

Structure of MOPEHCP and EOPEHCP"

Fig.3

Schematic diagrame of copolymerization for preparation of branched-chain flame-retardant polymers"

Fig.4

Structure diagram of multifunctional monomer block copolymer flame retardants"

Fig.5

Structure diagram of bifunctional flame retardant monomers"

[1] 李强林, 黄方千, 肖秀婵, 等. 反应性含磷阻燃单体在纺织品中的研究进展[J]. 印染, 2018,44(11):53-56.
LI Qianglin, HUANG Fangqian, XIAO Xiuchan, et al. Review on reactive phosphorus-containing flame-retardant monomers for textiles[J]. China Dyeing & Finishing, 2018,44(11):53-56.
[2] HORROCKS A R, WEI L. Recent developments and challenges in flame retardation of textiles and fibres[J]. Materials China, 2015,54(9):56-60.
[3] 任元林, 张悦, 曾倩, 等. 织物阻燃涂层新工艺的研究进展[J]. 纺织学报, 2017,38(9):168-173.
REN Yuanlin, ZHANG Yue, ZENG Qian, et al. Research progress on new technology of fabric flame retardant coating[J]. Journal of Textile Research, 2017,38(9):168-173.
[4] KOCH C, SCHMIDT-KOTTER S T, RUPP R, et al. Review of hexabromocyclododecane (HBCD) with a focus on legislation and recent publications concerning toxicokinetics and-dynamics[J]. Environmental Pollution, 2015,199:26-34.
pmid: 25618363
[5] 李强林, 黄方千, 杨东洁, 等. 冷等离子体接枝聚合阻燃改性纺织品研究进展[J]. 成都纺织高等专科学校学报, 2015,32(4):12-16.
LI Qianglin, HUANG Fangqian, YANG Dongjie, et al. Research progress on flame retardant modified textile by cold plasma graft polymerization[J]. Journal of Chengdu Textile Colloge, 2015,32(4):12-16.
[6] 李娜娜, 姜国伟, 周光远, 等. 有机磷类阻燃剂的合成及应用进展[J]. 应用化学, 2016,33(6):611-623.
LI Nana, JIANG Guowei, ZHOU Guangyuan, et al. Synjournal and application of organic phosphorus flame retardants[J]. Chinese Journal of Applied Chemistry, 2016,33(6):611-623.
[7] 李博, 李强林. 含磷聚合物阻燃剂研究进展[J]. 成都纺织高等专科学校学报, 2014,31(1):21-25.
LI Bo, LI Qianglin. Research progress on phosphorus-containing polymer flame retardant[J]. Journal of Chengdu Textile College, 2014,31(1):21-25.
[8] LI Q L, WANG X L, WAND D Y, et al. Durable flame retardant finishing of PET/cotton blends using a novel PVA-based phosphorus-nitrogen polymer[J]. Journal of Applied Polymer Science, 2011,122(1):342-353.
[9] 王灿灿. 磷酸酯阻燃剂的合成及其在黄麻织物上的应用[D]. 太原: 太原理工大学, 2012: 25-27.
WANG Cancan. Synthesis of phosphate flame retardant and its application in jute fabric[D]. Taiyuan:Taiyuan University of Technology, 2012: 25-27.
[10] YOSHIOKA T M, CONDON B D, CINTRÓN M S, et al. Enhanced flame retardant property of fiber reactive halogen-free organophosphonate[J]. Industrial & Engineering Chemistry Research, 2012,51(34):11031-11037.
[11] 任元林, 张悦, 谷叶童, 等. 含磷阻燃聚丙烯腈纤维的制备及其性能[J]. 纺织学报, 2017,38(8):1-5.
REN Yuanlin, ZHANG Yue, GU Yetong, et al. Preparation and properties of phosphorus-containing flame-retardant polyacrylonitrile fibers[J]. Journal of Textile Research, 2017,38(8):1-5.
[12] 王斐, 邓启刚, 陈朝晖, 等. 亚麻用降解壳聚糖含磷阻燃剂的合成及应用[J]. 精细化工, 2015,32(4):461-465.
WANG Fei, DENG Qigang, CHEN Zhaohui, et al. Synjournal and application of flame retardant for degradation of flax in chitosan[J]. Fine Chemicals, 2015,32(4):461-465.
[13] 林锐彬, 李战雄, 赵言, 等. 环三磷腈丙烯酸酯合成及其在棉织物阻燃整理中的应用[J]. 印染助剂, 2010,27(4):25-28.
LIN Ruibin, LI Zhanxiong, ZHAO Yan, et al. Cyclotriphosphazene acrylate synjournal and its application in cotton fabric flame retardant finishing[J]. Dyeing Auxiliaries, 2010,27(4):25-28.
[14] 钱立军, 叶龙健, 韩鑫磊, 等. 基于磷杂菲基团化合物的构建与性能[J]. 化学进展, 2010,22(9):1776-1783.
QIAN Lijun, YE Longjian, HAN Xinlei, et al. Construction and properties of phosphaphenanthrene based compounds[J]. Progress in Chemistry, 2010,22(9):1776-1783.
[15] 金崇业, 贾丽霞. 有机磷阻燃剂在羊毛纺织品中的应用和发展[J]. 纺织导报, 2015,31(4):32-35.
JIN Chongye, JIA Lixia. Application and development of the organic phosphorus flame retardant for wool fabric[J]. China Textile Leader, 2015,31(4):32-35.
[16] 帅博旺. 新型丙烯酸酯聚合物的合成及其在棉织物上的应用研究[D]. 上海:东华大学, 2012:25-38, 77-80.
SHUAI Bowang. New acrylic polymer synthesis and its application in cotton fabric[D]. Shanghai: Donghua University, 2012:25-38, 77-80.
[17] 董朝红. 棉用含磷氮元素聚硅氧烷阻燃剂的制备及性能研究[D]. 无锡:江南大学, 2014:37-38, 50-52.
DONG Chaohong. Preparation and properties of polysiloxane flame retardants containing phosphorus and nitrogen for cotton[D]. Wuxi: Jiangnan University, 2014:37-38, 50-52.
[18] HORROCKS A R. Flame retardant challenges for textiles and fibres: new chemistry versus innovatory solu-tions[J]. Polymer Degradation & Stability, 2011,96(3):377-392.
[19] LIU W, CHEN L, WANG Y Z. A novel phosphorus-containing flame retardant for the formaldehyde-free treatment of cotton fabrics[J]. Polymer Degradation & Stability, 2012,97(12):2487-2491.
[20] 周羿凝, 许苗军, 孙才英. N-羟甲基丙烯酰胺螺环磷酸酯的合成及表征[J]. 精细化工, 2015,32(8):917-920.
ZHOU Yining, XU Miaojun, SUN Caiying. Preparation and characterization of N-methylolacrylamide spiro phosphates[J]. Fine Chemicals, 2015,32(8):917-920.
[21] 陈金玲. 涤纶用有机磷阻燃水性聚氨酯涂层胶的制备及应用研究[D]. 杭州:浙江理工大学, 2013:13-16, 39-45.
CHEN Jinling. Polyester with organic phosphorus flame retardant water-based polyurethane coating adhesive preparation and application[D]. Hangzhou: Zhejiang Sci-Tech University, 2013:13-16, 39-45.
[22] 李强林, 黄方千, 魏玉君, 等. 涤棉织物的金属离子改性聚磷酸铵阻燃整理[J]. 印染, 2017,43(19):11-16.
LI Qianglin, HUANG Fangqian, WEI Yujun, et al. Metal ion modified ammonium polyphosphate flame retardant finishing of polyester/cotton fabric[J]. China Dyeing & Finishing, 2017 (19):11-16.
[23] 王琦. 棉用无甲醛阻燃剂的合成及应用[D]. 上海: 东华大学, 2014: 33-37.
WANG Qi. Cotton with formaldehyde-free flame retardant synthesis and application[D]. Shanghai: Donghua University, 2014: 33-37.
[24] 董振泉. 磷酸酯阻燃剂PPAP的制备及其在纯棉织物上的应用研究[D]. 上海: 东华大学, 2011: 33-38.
DONG Zhenquan. Preparation of phosphate flame retardant PPAP and its application in pure cotton fabric[D]. Shanghai: Donghua University, 2011: 33-38.
[25] 周向东, 陈迎春, 蒲泽佳, 等. 锦纶用耐久性阻燃剂的合成与应用[J]. 成都纺织高等专科学校学报, 2016,33(1):37-41.
ZHOU Xiangdong, CHEN Yingchun, PU Zejia, et al. Synjournal and application of durable flame retardant for polyamide[J]. Journal of Chengdu Textile College, 2016,33(1):37-41.
[26] 杨敏芬. 有机磷系阻燃剂的合成及其在尼龙中的应用[D]. 杭州:浙江理工大学, 2015: 28-30.
YANG Minfen. Synthesis of organic phosphorus flame retardants and its application in nylon [D]. Hangzhou: Zhejiang Sci-Tech University, 2015: 28-30.
[27] 蒋立, 丁斌, 郝凤岭, 等. 环三磷腈类阻燃剂的研究现状[J]. 印染助剂, 2017,34(4):6-11.
JIANG Li, DING Bin, HAO Fengling, et al. Research status of cyclotriphosphazene flame retardants[J]. Textile Auxiliaries, 2017,34(4):6-11.
[28] 高维全, 唐淑娟, 孙德, 等. 羟基环三磷腈衍生物阻燃剂的合成和性能研究[J]. 染整技术, 2008,30(9):11-14,59.
GAO Weiquan, TANG Shujuan, SUN De, et al. Studies on the synjournal and properties of hydroxyl cyclotriphosphazene derivatives flame retardant[J]. Dyeing and Finishing Technology, 2008,30(9):11-14,59.
[29] 陈文杰, 胡毅, 许春磊, 等. 棉织物架桥型水性聚氨酯-NPAZ阻燃整理[J]. 印染, 2010,36(24):1-3.
CHEN Wenjie, HU Yi, XU Chunlei, et al. Flame retardant finishing of waterborne polyurethane-NPAZ cotton fabric bridge[J]. China Dyeing & Finishing, 2010,36(24):1-3.
[30] LI Q L, HUANG F Q, JIANG X J. Preparation and properties of a washable flame-retardant coated fabric[J]. Indian Journal of Fibre & Textile Research, 2016,41:40-46.
[31] 王立春. 新型含磷阻燃剂的合成及无卤阻燃交联EVA复合材料的制备与性能研究[D]. 上海:上海交通大学, 2011: 47-50.
WANG Lichun. Synthesis of a new phosphorus-containing flame retardant and halogen-free flame retardant cross-linked EVA composite material preparation and performance[D]. Shanghai: Shanghai Jiao Tong University, 2011: 47-50.
[32] ZHONG H, WEI P, JIANG P, et al. Synjournal and characteristics of a novel silicon-containing flame retardant and its application in poly[2,2-propane-(bisphenol)carbonate]/acrylonitrile butadiene styrene[J]. Journal of Polymer Science Part B: Polymer Physics, 2007,45(13):1542-1551.
doi: 10.1002/(ISSN)1099-0488
[33] BOSCO F, CARLETTO R A, ALONGI J, et al. Thermal stability and flame resistance of cotton fabrics treated with whey proteins[J]. Carbohydrate Polymers, 2013,94:372-377.
pmid: 23544551
[34] BOSCO F, CARLETTO R A, ALONGI J, et al. DNA: a novel,green,natural flame retardant and suppressant for cotton[J]. Journal of Materials Chemistry A, 2013(1):4779-4785.
[35] ALONGI J, CARLETTO R A, BLASIO A D, et al. Intrinsic intumescentlike flame retardant properties of DNA-treated cotton fabrics[J]. Carbohydrate Polymers, 2013,96:296-304.
doi: 10.1016/j.carbpol.2013.03.066 pmid: 23688484
[36] ALONGI J, CARLETTO R A, BLASIO A D, et al. Caseins and hydrophobins as novel green flame retardants for cotton blends[J]. Polymer Degradation and Stability, 2014,99:111-117.
doi: 10.1016/j.polymdegradstab.2013.11.016
[37] CAROSIO F, BLASIO A D, CUTTICA F, et al. Flame retardancy of polyester and polyester-cotton blends treated with caseins[J]. Industry & Engineering Chemistry Research, 2014,53:3917-3923.
[38] 庞琳. 无甲醛大豆蛋白基阻燃胶黏剂的制备与应用研究[D]. 南京: 南京理工大学, 2016: 45-49.
PANG Lin. Preparation and application of formaldehyde-free soy protein-based flame retardant adhesive[J]. Nanjing: Nanjing University of Science and Technology, 2016: 45-49.
[1] WANG Yang, CHENG Chunzu, JIANG Li′na, REN Yuanlin, GUO Yingbin. Preparation of durable flame retardant polyacrylonitrile fabrics using UV-induced photo-grafting polymerization combined with sol-gel coating [J]. Journal of Textile Research, 2020, 41(10): 107-115.
[2] SHENG Mingfei, ZHANG Liping, FU Shaohai. Preparation and property of dye-doped liquid crystal microcapsules for electro-stimulated responsive smart textiles [J]. Journal of Textile Research, 2020, 41(08): 63-68.
[3] WANG Jingjing, CHEN Yong, WANG Chaosheng, WANG Huaping, BIAN Shuchang, WU Jing. Extraction of oligomers from bio-based propylene terephthalate polyester and its thermal properties [J]. Journal of Textile Research, 2020, 41(06): 1-7.
[4] HAO Zhifen, XU Naiku, FENG Yan, DUAN Mengxin, XIAO Changfa. Preparation of fibrous membrane by blending polymethacrylate with polyacrylate and its oil / water separation property [J]. Journal of Textile Research, 2020, 41(06): 21-26.
[5] HU Chengye, MIAO Runwu, HAN Xiao, HONG Jianhan, GIL Ignacio. Effect of polyvinyl alcohol on durability of polyaniline conductive layer on poly(p-phenylene terephthamide) yarn surface [J]. Journal of Textile Research, 2020, 41(04): 91-97.
[6] WU Yingxin, HU Chengye, ZHOU Xiaoya, HAN Xiao, HONG Jianhan, GIL Ignacio. Strain sensing property of flexible wearable spandex / polyaniline / polyurethane composites [J]. Journal of Textile Research, 2020, 41(04): 21-25.
[7] WANG Xiaofei, WAN Ailan. Preparation of polypyrrole / silver conductive polyester fabric by ultraviolet exposure [J]. Journal of Textile Research, 2020, 41(04): 112-116.
[8] ZHANG Xing, LIU Jinxin, ZHANG Haifeng, WANG Yuxiao, JIN Xiangyu. Preparation technology and research status of nonwoven filtration materials for individual protective masks [J]. Journal of Textile Research, 2020, 41(03): 168-174.
[9] GAO Simeng, WANG Hongbo, DU Jinmei, WANG Wencong. Synthesis of polybetaine antibacterial agent and its applications in cotton textiles finishing [J]. Journal of Textile Research, 2020, 41(02): 89-94.
[10] GUO Zengge, JIANG Zhaohui, JIA Zhao, PU Congcong, LI Xin, CHENG Bowen. Influence of pressure on rheological behavior of polyethylene terephthalate-polyamide 6 copolymer/polyamide 6 blends [J]. Journal of Textile Research, 2019, 40(12): 27-31.
[11] CUI Yifan, HOU Wei, ZHOU Qianxi, YAN Jun, LU Yanhua, HE Tingting. Influence of silk sericin temperature sensitive hydrogel on properties of cotton fabrics [J]. Journal of Textile Research, 2019, 40(12): 74-78.
[12] ZHANG Ze, XU Weijun, KANG Hongliang, XU Jian, LIU Ruigang. Thoughts on preparation technology of high performance polyacrylonitrile-based carbon fibers [J]. Journal of Textile Research, 2019, 40(12): 152-161.
[13] ZHANG Jiao, GAO Xuefeng, WANG Yuzhou, LIU Haihui, ZHANG Xingxiang. Preparation and properties of polyamide 66/amino-functionalized multi-walled carbon nanotubes fibers [J]. Journal of Textile Research, 2019, 40(11): 1-8.
[14] ZHANG Zhibin, LI Gang, MAO Senxian, LI Xunxun, CHEN Yushuang, MAO Qingshan, LI Yi, PAN Zhijuan, WANG Xiaoqin. Preparation and antibacterial activity of silk fibroin/chitosan microspheres [J]. Journal of Textile Research, 2019, 40(10): 7-12.
[15] GUO Dongyan, XU Naiku, XIAO Changfa. Preparation of poly(meth)acrylate hollow fiber with internal coating of manganese oxide and its capability to decolorize dyes of methylene blue [J]. Journal of Textile Research, 2019, 40(10): 26-32.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd