Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (06): 64-67.doi: 10.13475/j.fzxb.20180603604

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Synthesis of UV curing melamine resin and performance testing of its coating fabric

ZHANG Si1,2, WU Min1,2()   

  1. 1. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
    2. College of Textiles and Garment, Jiangnan University, Wuxi, Jiangsu 214122, China
  • Received:2018-06-08 Revised:2019-03-18 Online:2019-06-15 Published:2019-06-25
  • Contact: WU Min E-mail:xycwxdq@sina.com

Abstract:

In order to prepare UV curable melamine resin,hydroxyethyl acrylate (HEA) was used to modify methyl etherified melamine resin (HMMM). The unsaturated C=C double bond was introduced to increase the photocurability of melamine resin.The structure of the product was characterized by infrared spectroscopy.As a result,amino acrylate (HEA-MF) is successfully synthesized.Then,the photocurable melamine resin film and coated fabric were prepared,and the thermal property of the film was characterized by Thermal Gravity Analysis(TGA).The mechanical properties,stiffness,wear resistance,waterproof,moisture permeability and air permeability of coated samples were analyzed.The results show that under 300 ℃,the UV-cured film has stable structure and good thermal stability,it begins to lose weight quickly at 350 ℃.After coating,the breaking strength,stiffness and abrasion resistance of the fabric are improved.The fabric elongation at break,moisture permeability and air permeability are adversely affected,but the waterproof properties of the coated fabric are outstanding.

Key words: melamine resin, UV curing, amino acrylate, coating fabric, waterproof

CLC Number: 

  • TS194

Fig.1

Synthesis process of HEA-MF"

Fig.2

FT-IR spectra of fabric before and after reaction"

Fig.3

TGA of UV cured film"

Tab.1

Tensile strength of fabrics"

实验样品 断裂强力/ N 断裂伸长率/%
未处理涤/棉织物 1 108.2 17.51
UV照射涤/棉织物 460.0 20.29
HEA-MF涂层织物 1 181.4 8.94

Tab.2

Bending length and wear rate of fabrics"

实验样品 方向 弯曲长度/cm 磨损
率/%
1 2 3 4
未处理涤/ 4.59 4.57 4.73 4.68 3.55
棉织物 4.84 4.51 4.57 4.48
HEA-MF 10.65 11.06 10.40 11.03 1.39
涂层织物 10.46 11.13 10.84 10.63

Tab.3

Hydrostatic pressure and WVT of fabric"

实验样品 透湿量/(g·(m2·24 h)-1) 静水压/kPa
HEA-MF涂层织物 373 18.03
未处理涤/棉织物 3 235
[1] 马跃辉, 王炜, 蒋志康. 光固化技术在纺织印染中的应用进展[J]. 印染助剂, 2018,35(5):12-17.
MA Yuehui, WANG Wei, JIANG Zhikang. Application of UV curing technology in textile dyeing and printing[J]. Textile Auxiliaries, 2018,35(5):12-17.
[2] 南旭莹, 任晓峰, 黄益, 等. 光固化技术在纺织染整中的应用[J]. 印染, 2017,43(7):50-55.
NAN Xuying, REN Xiaofeng, HUANG Yi, et al. Application of UV curing technology in textile dyeing and printing[J]. China Dyeing & Finishing, 2017,43(7):50-55.
[3] 邵瑞梦, 张梅, 于范芹, 等. 三聚氰胺甲醛树脂改性的研究进展[J]. 广东化工, 2016,43(24):92-93,121.
SHAO Ruimeng, ZHANG Mei, YU Fanqin, et al. Research progress in modification of melamine formaldehyde resin[J]. Guangdong Chemical Industry, 2016,43(24):92-93,121.
[4] 张本刚, 吴志刚, 雷洪. 三聚氰胺树脂增韧改性研究进展[J]. 绿色科技, 2018(8):185-187.
ZHANG Bengang, WU Zhigang, LEI Hong. Research progress in toughening modification of melamine resin[J].Journal of Green Science and Technology, 2018(8):185-187.
[5] 李昭. 三聚氰胺树脂的合成工艺研究[J]. 山东化工, 2015,44(19):26-27,30.
LI Zhao. Study on the synjournal of melamine resin[J]. Shandong Chemical Industry, 2015,44(19):26-27,30.
[6] 熊冕, 马迎春, 王姣姣, 等. 三聚氰胺甲醛树脂研究与应用进展[J].广东化工, 2013, 40(22):68,74.
XIONG Mian, MA Yingchun, WANG Jiaojiao, et al. Research and application of melamine resin[J].Guangdong Chemical Industry, 2013, 40(22):68,74.
[7] 刘丹丹, 王欣, 刘甜, 等. 快速成型光固化树脂的制备[J]. 工程塑料应用, 2014,42(4):23-26.
LIU Dandan, WANG Xin, LIU Tian, et al. Preparation of stereolithography resin[J]. Engineering Plastics Application, 2014,42(4):23-26.
[8] ARVIN Z Y, JONAS M, SAHOUANI D C. Highly functional methacrylated bio-based resins for UV-curable coatings[J].Progress in Organic Coatings, 2018(122):219-228.
[9] LILIAN Boton, JOHN Marc Puguan, MUHAMMAD Latif, et al. Synjournal and properties of quick-drying UV-curable hyperbranched waterborne polyurethane coating[J].Progress in Organic Coatings, 2018(125):201-206.
[10] 宋玉. UV固化聚氨酯膜的制备及其在织物表面的应用[D]. 无锡:江南大学, 2014: 12-15.
SONG Yu. Preparation of UV curable polyurethane film and its application in the fabric surface[D]. Wuxi:Jiangnan University, 2014: 12-15.
[11] 那英, 杨福斌, 陈运能. 聚氨酯涂层棉织物性能研究[J]. 棉纺织技术, 2017,45(6):34-36.
NA Ying, YANG Fubin, CHEN Yunneng. Property study of polyurethane coated cotton fabric[J]. Cotton Textile Technology, 2017,45(6):34-36.
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