Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (07): 119-127.doi: 10.13475/j.fzxb.20180703409

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Single-guide water non-fluorinated finishing of cotton spunlace non-woven materials

QI Guorui1, KE Qinfei1, LI Zu'an2, HUANG Zujian2, JIN Xiangyu1, HUANG Chen1()   

  1. 1. School of Textiles, Donghua University, Shanghai 201620, China
    2. Fujian Nanfang Co., Ltd., Nanping, Fujian 353000, China
  • Received:2018-07-16 Revised:2019-04-17 Online:2019-07-15 Published:2019-07-25

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Abstract:

In order to realize the industrialization of pure cotton spunlace non-woven materials single-directional water-free fluorine-free finishing process, self-made atomization equipment and the German fluorine-free water repellent RUCO-DRY ECO with a volume fraction of 0.67% were adopted to one-side water-repellent spray finish the cotton spunlace non-woven materials. This paper studied the physical and mechanical properties, contact angle and moisture management tester(MMT)performance of the materials after finishing for different spray time, discussed the reasons for the little change of physical and mechanical properties and the changes of contact angle and MMT performance, and carried out the diaper surface performance test of the finished cotton spunlace non-woven materials. The results show that its one-way transfer index (AOTC) can reach 1 093%, the liquid water dynamic transfer index (OMMC) can reach 0.960 6. Under the premise of ensuring pure cotton material does not reverse osmosis, the liquid penetration time can reach 4 s.

Key words: self-made spray device, pure cotton spunlace non-woven material, one-sided water repellent, non-fluorine finishing, side layer material of diaper

CLC Number: 

  • TS174.8

Fig.1

Self-made spray device"

Fig.2

Process flow chart"

Tab.1

Carding parameters"

梳理元件 喂给罗拉 锡林 杂乱辊 道夫 成卷
梳理速度/
(m·min-1)		 0.84 251 6.31 7.64 12.54

Tab.2

Spunlace parameters"

水刺工艺 速度/(m·min-1) 顺序 压力/kPa
预水刺 2 正 2 500
第1道 2 正 3 500
第2道 2 正 4 500
第3道 2 正 6 500
第4道 2 正 7 500

Fig.3

Comparison of SEM images before and after water spraying repellent finishing"

Fig.4

Comparison of FI-TR before and after water spraying repellent finishing"

Fig.5

Percentage increase in mass before and after water spraying repellent finishing"

Fig.6

Comparison of maximum breaking strength before and after water spraying repellent finishing. (a)MD direction;(b)CD direction"

Fig.7

Change in pore size before and after spraying finishing. (a)Average aperture; (b) Pore size distribution"

Fig.8

Air permeability changes before and after spraying finishing"

Fig.9

Hydrophobic contact angle before and after spraying finishing. (a) Hydrophilic surface; (b) Hydrophobic surface"

Tab.3

Liquid penetration when spraying time is 20, 25 and 30 s"

喷雾时间/s 方向 t/s B/% A/% C/%
20 ↓ 3.2 26 6 68
↑ 3.2 28 64 8
25 ↓ 4.0 20 5 75
↑ 4.0 25 75 0
30 ↓ 5.2 24 18 58
↑ 5.2 22 78 0

Fig.10

Liquid penetration process"

Tab.4

AOTC and OMMC performance rating table"

评语 单向传递指数
(AOTC)/%		 液态水动态传
递指数(OMMC)
非常差 <-50 0~0.2
差 <-50 0.2~0.4
好 100~200 0.4~0.6
非常好 200~400 0.6~0.8
极好 >400 >0.8

Fig.12

Schematic diagram of MMT for different spraying treatment time"

Fig.11

AOTC and OMMC for different spraying treatment time"

Fig.13

Appearance morphologies of samples A and B topography"

Tab.5

Liquid penetration time, slip amount and moisture return amount of samples A and B"

试样 液体穿透
时间/s		 滑移量/
g		 返湿量/g
A 1.06 0.092 3 0.052 2
B 2.24 0.918 1 0.124 8
A与B比值 0.47 0.10 0.42
[1] 王科林, 孟霞 . 精纺毛织物的无氟拒水整理[J]. 纺织学报, 2016,37(3):114-118.
WANG Kelin, MENG Xia . Fluorine-free water repellent finish of worsted fabric[J]. Journal of Textile Research, 2016,37(3):114-118.
[2] SHEN Keke, YU Miao, LI Qianqian . Synjournal of a fluorine-free polymeric water-repellent agent for creation of superhydrophobic fabrics[J]. Applied Surface Science, 2017,426:694-703.
[3] CAI Ronggang, KARINE Glinel, DE Smet . Environmentally friendly super-water-repellent fabrics prepared from water-based suspensions[J]. ACS Applied Materials & Interfaces, 2018,10:15346-15351.
doi: 10.1021/acsami.8b02707 pmid: 29688696
[4] MA Yue, ZHU Danjie, SI Yang . Fabricating durable, fluoride-free, water repellency cotton fabrics with CPDMS[J]. Journal of Applied Polymer Science, 2018,135(25):1-6.
[5] ZHANG Junping, LI Bucheng, WU Lei . Facile preparation of durable and robust superhydrophobic textiles by dip coating in nanocomposite solution of organosilanes[J]. Chemical Communications, 2013,49(98):11509-11511.
doi: 10.1039/c3cc43238f pmid: 23884359
[6] LIU Yang, XIN Jicong, CHOI Ch . Cotton fabrics with single-faced superhydrophobicity[J]. Langmuir, 2012,28(50):17426-17434.
doi: 10.1021/la303714h pmid: 23186211
[7] KAICHI Sasaki, MIZUKI Tenjimbayashi . Asymmetric superhydrophobic/superhydrophilic cotton fabrics designed by spraying polymer and nanoparticles[J]. ACS Applied Materials & Interfaces, 2016,8(1):651-659.
doi: 10.1021/acsami.5b09782 pmid: 26595458
[8] 刘慧慧, 王云仪 . 纸尿裤服用性能测评研究进展[J]. 纺织学报, 2018,39(6):175-182.
LIU Huihui, WANG Yunyi . Progress in holistic wearability evaluation of disposable diapers[J]. Journal of Textile Research, 2018,39(6):175-182.
[9] AIJAZ Ahmed Babar, WANG Xianfeng . Tailoring differential moisture transfer performance of nonwoven/polyacrylonitrile-SiO2 nanofiber composite mem-branes[J]. Advanced Materials Interfaces, 2017,15(4):1-10.
[10] MUHAMMAD Zahid, JOSE A . Robust water repellent treatment for woven cotton fabrics with ecofriendly polymers[J]. Chemical Engineering Journal, 2017,319:321-332.
[11] CAO Chunyan, GE Mingzheng . Robust fluorine-free superhydrophobic PDMS-ormosil@fabrics for highly effective self-cleaning and efficient oil-water separ-ation[J]. Journal of Materials Chemistry A, 2016(4):12179-12187.
[12] ZHAO Qing, LI Yiyang . Ambient-curable superhydrophbic fabric coating prepared by water-based non-fluorinated formulation[J]. Mater Des, 2016,92:541-545.
[13] SEYED Mostafa Hosseinalipour, HADISE Karimaei, EHSAN Movahednejad . Mechanical reinforcement and water repellency induced to cellulose sheets by a polymer treatment[J]. Cellulose, 2013,20:1501-1509.
[14] FU Qing, WANG Fei . Application of maximum entropy principle to predict droplet size distribution for swirl injectors[J]. Iranian Journal of science and Technology: Transactions of Mechanical Engineering, 2017,40(4):305-313.
[15] FENG Zhuangbo, ZHOU Xiaoqing . Impacts of humidification process on indoor thermal comfort and air quality using portable ultrasonic humidifier[J]. Building and Environment, 2018,133:62-72.
[16] SUN Di, WANG Wei . Preparation of fluorine-free water repellent finishing via thiol-ene click reaction on cotton fabrics[J]. Materials Letters, 2016,185:514-518.
[17] 王伟, 黄晨, 靳向煜 . 单向导湿织物的研究现状及进展[J]. 纺织学报, 2016,37(5):167-172.
WANG Wei, HUANG Chen, JIN Xiangyu . Development of unidirectional water-transfer fabrics[J]. Journal of Textile Research, 2016,37(5):167-172.
[18] 郝习波, 李辉芹, 巩继贤 , 等. 单向导湿功能纺织品的研究进展[J]. 纺织学报, 2015,36(7):157-161.
HAO Xibo, LI Huiqin , GONG Jixian,et.al.Review on unidirectional water transport functional fabrics[J]. Journal of Textile Research, 2015,36(7):157-161.
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