Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (07): 101-108.doi: 10.13475/j.fzxb.20190600208

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Dyeing kinetics of reactive dye on cotton yarn in Pickering emulsion system

DING Yongsheng1,2, DAI Yamin1,2, ZHONG Yi1,2(), XU Hong3, MAO Zhiping1,4, ZHANG Linping1,2, CHEN Zhize1,2   

  1. 1. Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    2. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
    3. Lutai Textile Co., Ltd., Zibo, Shandong 255000, China
    4. Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
  • Received:2019-06-03 Revised:2020-01-15 Online:2020-07-15 Published:2020-07-24
  • Contact: ZHONG Yi E-mail:zhongyi@dhu.edu.cn

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Abstract:

In order to explore the dyeing mechanism of reactive dye on cotton yarn in SiO2 emulsion (Pickering emulsion)system, Reactive Red M-3BF was used to explore the kinetics for cotton dyeing. The dyeing performance of the dye in Pickering emulsion system and the traditional aqueous system were compared, before the data of cotton yarn dyed in Pickering emulsion system was fitted, and the kinetic parameters were calculated and compared with the traditional aqueous system. The results show that the dye utilization of Reactive Red M-3BF in the Pickering emulsion system are higher than that in the traditional aqueous bath dyeing system and the washing fastness is equivalent under the same dye dosages, and the dyeing of reactive Red M-3BF on cotton fibers in both systems conforms to the quasi-second-order kinetic adsorption model equation. The equilibrium adsorption capacity of dye in Pickering emulsion system is higher than that of traditional aqueous system, and the adsorption activation energy is smaller, the half-dyeing time is shortened. Sodium sulfate can increase the equilibrium adsorption capacity and speed up the dyeing rate.

Key words: reactive dye, Pickering emulsion system, cotton yarn, dyeing, silica emulsion

CLC Number: 

  • TS193.5

Fig.1

Dyeing process. (a) Pickering emulsion system;(b) Traditional aqueous system"

Fig.2

Dye utilization of Reactive Red M-3BF in different systems with different dye dosages"

Fig.3

Kinetic curves of Reactive Red M-3BF dyeing cotton yarn in different systems at different temperatures"

Fig.4

Fitting curves of quasi-first-order kinetics of adsorption of Reactive Red M-3BF dyeing on cotton fiber in different systems. (a) Pickering emulsion system; (b) Traditional aqueous system"

Tab.1

Correlation coefficient of quasi-first-order kinetics of Reactive Red M-3BF adsorption on cotton fiber in different systems"

染色体系 温度/℃ R2
皮克林乳液体系 40 0.865 16
60 0.604 27
80 0.671 02
传统水浴体系 40 0.953 10
60 0.898 17
80 0.971 79

Fig.5

Fitting curves of quasi-second-order kinetics of adsorption of Reactive Red M-3BF dyeing on cotton fiber in different systems. (a) Pickering emulsion system;(b) Traditional aqueous system"

Tab.2

Quasi-second-order kinetic parameters of Reactive Red M-3BF adsorption on cotton fiber in different systems"

染色
体系		 温度/
℃		 qe,exp/
(mg·g-1)		 准二级动力学参数
k2/
(g·mg-1·min-1)		 qe,cal/
(mg·g-1)		 R2
皮克
林乳液
体系		 40 17.99 0.115 18.14 0.999 94
60 17.90 0.164 18.01 0.999 97
80 17.76 0.243 17.83 0.999 98
传统
水浴体系		 40 13.05 0.043 13.39 0.999 63
60 12.10 0.071 12.38 0.999 64
80 10.44 0.147 10.58 0.999 91

Fig.6

Fitting curves in different systems"

Tab.3

Half-dyeing time of Reactive Red M-3BF dyeing cotton yarns in different systems"

染色体系 温度/℃ 半染时间t1/2/min
皮克林
体系乳液		 40 0.48
60 0.34
80 0.23
传统
水浴体系		 40 1.78
60 1.16
80 0.65

Fig.7

Kinetic curves of Reactive Red M-3BF dyeing cotton yarn in different systems and different temperatures at different salt dosages"

Tab.4

Quasi-second-order kinetic parameters of Reactive Red M-3BF adsorption on cotton fiber in different systems at different salt dosages"

染色
体系		 Na2SO4
质量
浓度		 R2 qe,exp k2 qe,cal t1/2
皮克林
乳液体系		 40 1.000 00 19.23 0.260 19.29 0.20
60 0.999 99 19.36 0.289 19.41 0.18
80 0.999 99 19.57 0.409 19.60 0.12
传统
水浴体系		 40 0.999 51 9.80 0.068 13.39 1.50
60 0.999 64 12.10 0.071 12.38 1.16
80 0.999 88 13.37 0.076 10.58 0.98

Tab.5

Diffusion coefficients of Reactive Red M-3BF at different temperatures in different systems"

染色体系 温度/℃ D×1016/(m2·s-1)
皮克林
乳液体系		 40 3.475
60 4.782
80 6.419
传统
水浴体系		 40 2.546
60 4.081
80 5.775
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