Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (09): 102-107.doi: 10.13475/j.fzxb.20190803606

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Graphene oxide loading on polyester fabrics and antistatic properties

LI Liang1,2,3, LIU Jingfang4, HU Zedong4, GENG Changjun4, LIU Rangtong1,2,4()   

  1. 1. Collaborative Innovation Center of Textiles and Clothing in Henan Province, Zhengzhou, Henan 451191, China
    2. Henan Province Key Laboratory of Functional Textile Materials, Zhengzhou, Henan 451191, China
    3. Textile College, Zhongyuan University of Technology, Zhengzhou, Henan 451191, China
    4. Fashion Technology College, Zhongyuan University of Technology, Zhengzhou, Henan 451191, China
  • Received:2019-08-13 Revised:2020-04-05 Online:2020-09-15 Published:2020-09-25
  • Contact: LIU Rangtong E-mail:ranton@126.com

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Abstract:

In order to solve the electrostatic problem of polyester fabrics, the polyester fabric specimens was cyclically impregnated in graphene oxide solution after treated by in-situ polymerization of dopamine. The structure and antistatic property of the polyester fabric were characterized by scanning electron microscope, infrared spectrometer and fabric electrostatic tester. The results show that the introduction of dopamine is beneficial to the loading of graphene oxide, and the hydrophilic groups are increased to improve the antistatic performance of polyester fabric after treatment. When the graphene concentration keeps lower than 20 g/L, with the increase of graphene oxide concentration, the antistatic property of the fabric is gradually improved. When the concentration of graphene oxide is 15 g/L, the surface static voltage and half-life of the plain polyester fabric are 1 156 V and 1.210 s respectively, while that of twill polyester fabric are 1 243 V and 1.510 s. After 15 cycles of washing, the surface static voltage and half-life of the plain polyester fabric could still reach 1 179 V and 1.290 s, while that of twill can also reach 1 263 V and 1.580 s.

Key words: polyester fabric, dopamine, graphene oxide, antistatic property, antistatic finishing

CLC Number: 

  • TS195

Fig.1

Surface loading GO mechanism of dopamine in situ polyester"

Fig.2

SEM images of polyester fabric. (a)Original sample; (b) Sample loaded with dopamine; (c) Sample loaded with dopamine and 10 g/L GO; (d) Sample loaded with dopamine and 15 g/L GO"

Fig.3

Infrared spectra of polyester fabrics before and after in-situ polymerization of dopamine and GO loading"

Fig.4

XRD of polyester fabric before and after dopamine in-situ polymerization and GO loading"

Fig.5

TG (a) and DTG (b) of fabrics before and after GO loading"

Tab.1

Antistatic property of polyester fabric with different finishing schemes before washing"

整理方案 平纹织物 斜纹织物
静电压/V 静电压
标准差/V		 半衰期/s 半衰期
标准差/s		 静电压/V 静电压
标准差/V		 半衰期/s 半衰期
标准差/s
未经多巴胺和GO整理 3 835 — 300.000 — 3 982 — 300.000 —
多巴胺 3 417 ±6.811 13.040 ±0.010 3 524 ±1.000 13.460 ±0.036
多巴胺+5 g/L GO 2 687 ±4.643 7.630 ±0.026 2 876 ±2.645 8.290 ±0.035
多巴胺+10 g/L GO 1 332 ±2.582 1.860 ±0.043 1 621 ±3.165 2.660 ±0.010
多巴胺+15 g/L GO 1 156 ±1.244 1.210 ±0.020 1 243 ±3.134 1.510 ±0.072
多巴胺+20 g/L GO 1 226 ±8.605 1.530 ±0.065 1 436 ±6.221 1.830 ±0.088

Tab.2

Antistatic property of polyester fabric with different finishing schemes after washing 15 times"

整理方案 平纹织物 斜纹织物
静电压/V 静电压
标准差/V		 半衰期/s 半衰期
标准差/s		 静电压/V 静电压
标准差/V		 半衰期/s 半衰期
标准差/s
未经多巴胺和GO整理 — — — — — — — —
多巴胺 3 487 ±5.165 13.290 ±0.020 3 614 ±4.848 13.700 ±0.010
多巴胺+5 g/L GO 2 722 ±1.000 7.780 ±0.036 2 915 ±1.605 8.390 ±0.026
多巴胺+10 g/L GO 1 367 ±3.211 2.020 ±0.017 1 652 ±0.732 2.750 ±0.034
多巴胺+15 g/L GO 1 179 ±0.983 1.290 ±0.026 1 263 ±1.645 1.580 ±0.010
多巴胺+20 g/L GO 1 266 ±7.193 1.700 ±0.060 1 501 ±8.074 1.980 ±0.091

Fig.6

Static voltage and half-life change rate of fabrics after washing"

Fig.7

SEM images of polyester fabric after washing. (a) Sample loaded with dopamine; (b) Sample loaded with dopamine and GO (10 g/L); (c) Sample loaded with dopamine and GO (15 g/L)"

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