Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (09): 1-7.doi: 10.13475/j.fzxb.20191106007

• Fiber Materials •     Next Articles

Preparation of graphene fibers by wet spinning and fiber characterization

PANG Yali1,2, MENG Jiayi1,2, LI Xin1,2(), ZHANG Qun1,2, CHEN Yankun1,2   

  1. 1. Beijing Key Laboratory of Clothing Materials R & D and Assessment, Beijing Institute of Fashion Technology, Beijing 100029, China
    2. Beijing Engineering Research Center of Textile Nanofiber, Beijing 100029, China
  • Received:2019-11-26 Revised:2020-06-12 Online:2020-09-15 Published:2020-09-25
  • Contact: LI Xin E-mail:clylx@bift.edu.cn

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Abstract:

In order to prepare graphene fiber with both conductivity and flexibility, the soluble graphene oxide was prepared through modified Hummers method. The graphene oxide solution was used as the spinning solution, and the CaCl2 ethanol solution as the coagulation bath. The graphene fiber was obtained by hydroiodic reduction via wet spinning. The fiber was treated with carboxymethylcellulose as cross-linking agent to obtain cross-linked graphene fiber for comparison. The surface morphology, electrical conductivity and mechanical properties of the two graphene fibers were characterized for preliminary applications. The results show that the prepared graphene oxide fiber has an oxygen content of 31.37% and a monolayer thickness of 0.88 nm. Besides, the surfaces of the two types of graphene fibers are smooth, but the inner layers of the cross-linked graphene fiber are arranged more closely with the conductivity of 124 S/cm, which is similar to the conductivity of the graphene fiber before crosslinking. However, the tensile strength is significantly increased from 120 MPa to 179 MPa after crosslinking. The single cross-linked graphene fiber can be used as a circuit wire to light the bulb, and can be arbitrarily bent and knotted to form a petal and a plain mesh structure.

Key words: graphene, wet spinning, conductive fiber, conductivity, mechanical property, smart textiles

CLC Number: 

  • TS102.5

Fig.1

Cross-linking mechanism of CMC and rGO fiber"

Fig.2

AFM image of graphene oxide powder"

Fig.3

XRD patterns of graphite and GO powder"

Fig.4

FT-IR spectra of graphite and GO powder and rGO fiber"

Fig.5

XPS spectra of GO powder and rGO fiber"

Tab.1

Contents of different elements in GO powder and rGO fiber%"

样品名称 C O N S I
GO粉末 65.57 31.37 1.79 1.27
rGO纤维 83.46 14.55 1.68 0.32

Fig.6

Raman spectra of graphite and GO powder and rGO fiber"

Fig.7

Cross-section SEM images of rGO fiber before (a) and after (b) crosslinking"

Fig.8

Tensile curve of rGO fiber before and after crosslinking"

Fig.9

Cross-linked rGO fiber woven into different shapes. (a) Wet cross-linked graphene fiber; (b) Dry cross-linked graphene fiber;(c)Petal structure of cross-linked graphene fiber;(d)Plain structure of cross-linked graphene fiber"

Fig.10

Photo of cross-linked rGO fiber in circuit"

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