Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (02): 135-141.doi: 10.13475/j.fzxb.20201008308

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Bonding fastness of magnetron sputtering nano-films with various textile substrates

LIU Mingxue1, ZHAO Qian1, WANG Xiaohui1, LIU Qiongxi2,3, SHAO Jianzhong1()   

  1. 1. Engineering Research Centre for Eco-Dyeing and Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Guangdong Rising Well Science & Technology Co., Ltd., Jiangmen, Guangdong 529300, China
    3. Beijing Nano Color Science and Technology Co., Ltd., Beijing 100089, China
  • Received:2020-10-29 Revised:2020-11-21 Online:2021-02-15 Published:2021-02-23
  • Contact: SHAO Jianzhong E-mail:jshao@zstu.edu.cn

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Abstract:

To address the problem that the magnetron sputtering nano-films on natural fiber substrates are prone to whole layer shedding, the rubbing fastness and soaping of the magnetron sputtering structural color films on different fiber substrates were systematically tested, and the effects of the initial moisture content and the low-temperature plasma surface modification on the bonding fastness of the magnetron sputtering films to the fiber substrates were investigated in detail. The underlying reasons for the different bonding fastness of the magnetron sputtering films to different fiber substrates were studied by means of scanning electron microscope analysis technique combined with the analysis on physical and chemical properties of different fiber materials. The results show that due to the softening point of the thermoplastic polyester fiber, the kinetic energy of the energetic magnetron sputtered particles is converted into thermal energy when they are deposited on the fiber surface, causing the polyester fibers to locally reach the softening point and bonding the sputtered particles. On the contrary, cotton and silk fibers have no softening point, so the fibers have no melt-bonding effect on the magnetron sputtering particles. In addition, as cotton and silk fibers have hygroscopic swelling properties, the intrusion of water molecules during the soaping process weakens the interaction force between the fibers and nanoparticles, causing the easy shedding of the magnetron sputtering nano-films.

Key words: magnetron sputtering, textile substrate, bonding fastness, structural coloration, low temperature plasma, moisture content, physical coloration

CLC Number: 

  • TS193.5

Tab.1

Color fastness of structurally colored fabrics with magnetron sputtering thin-film"

织物
基材		 耐摩擦色牢度 耐皂洗
色牢度
干摩 湿摩
涤纶仿蚕丝a 5 4~5 3~4
涤纶仿蚕丝b 5 4~5 3~4
涤纶欧根纱a 5 4 3~4
涤纶欧根纱b 5 4~5 3~4
棉斜纹a 4~5 4 0
棉斜纹b 4 4 0
棉平纹a 4 4 0
棉平纹b 4 4 0
蚕丝斜纹绸a 4~5 4 0
蚕丝斜纹绸b 4 4 0
蚕丝缎纹a 4 4 0
蚕丝缎纹b 4 4 0

Tab.2

Relationship between initial moisture content and colorfastness to soaping of nano-films fabrics"

织物
基材		 初始含水率/%
0 10 30 50 70 90
涤纶 3~4 3~4 3~4 3~4 3~4 3~4
棉 0 0 0 0 0 0
蚕丝 0 0 0 0 0 0

Fig.1

Relationship between initial moisture content of fabrics and vacuum time"

Tab.3

Color fastness to soaping of magnetron sputtering coated fabrics"

织物基材 未处理 氧等离子体处理
涤纶 3~4 4
棉 0 0
蚕丝 0 0

Fig.2

Effect of oxygen plasma treatment power on color fastness to soaping of magnetron sputtering coated fabrics"

Fig.3

FESEM images of original polyester(a), cotton(b) and silk fiber(c) surfaces"

Fig.4

FESEM images of copper nano-particles (a) and titanium nano-particles (b) magnetron sputtered fiber surfaces"

Fig.5

FESEM images of magnetron sputtered and soap washed sample surfaces.(a)Copper nano-particles sputtered and soap washed;(b) Titanium nano- particles sputtered and soap washed"

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