Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (02): 1-6.doi: 10.13475/j.fzxb.20210106206

• Invited Paper •     Next Articles

Promotion mechanism of color fastness to sublimation in thermovacuum environmental conditions for fibroin powder/pigment complex

CAO Genyang, WANG Yunli, SHENG Dan, PAN Heng, XU Weilin()   

  1. State Key Laboratory of New Textile Materials and Advanced Processing Technologies,Wuhan Textile University, Wuhan, Hubei 430200, China
  • Received:2021-01-05 Revised:2021-01-25 Online:2021-02-15 Published:2021-02-23
  • Contact: XU Weilin E-mail:weilin_xu@wtu.edu.cn

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Abstract:

In order to improve the thermal sublimation fastness of pigment particles on colored fabrics under thermovacuum environmental conditions, surface morphology, particle size and molecular structure of naphthol red F3RK pigment particles and silk fibroin powders were investigated, and the color of the fabric was tuned by mixing pigment particles with silk fibroin powder at different ratios. The subatomospheric pressure is used to simulate the thermal force field in the thermalvacuum environment, under which the adsorption performance was studied under different mixing ratios between pigment particles and silk fibroin powder. The interaction between silk fibroin powders and pigment particles were discussed, and the theoretical model was established. The results show that the silk fibroin powder is effective in improving thermal sublimation of colored fabrics in thermovacuum environmental conditions due to the synergistic effect of its large specific surface area and amido bonds. Employment of this method increases thermal sublimation fastness to level 5. The results of this study are of referencing significance for improving the thermal sublimation fastness of colored fabrics under extreme environmental conditions.

Key words: silk fibroin powder, nano-pigment, printing, thermovacuum environmental condition, thermal sublimation fastness

CLC Number: 

  • TS194.2

Fig.1

Characteristics of silk fibroin powder and pigment powder. (a) Molecular structure of naphthol red F3RK; (b) Molecular structure of silk fibroin; (c) Particle size and surface morphology;(d) Differential pore size distribution of silk fibroin powder; (e) Integral pore size distribution of silk fibroin powder"

Fig.2

Surface morphology of naphthol red F3RK powder and naphthol red F3RK particles adsorbed by silk fibroin powder. (a) Naphthol red F3RK powder;(b) Mix suction filtration residue of 0.5 g naphthol red F3RK powder and 5.0 g silk fibroin powder"

Fig.3

Effect of mixing ratio on adsorption capacity of silk fibroin powder"

Fig.4

Storage modulus image of different powder"

Fig.5

Model of micro-nano silk fibroin powder regulating pigment film structure"

Fig.6

Comparison samples with and without silk fibroin powder treated in high-low temperature circulation for 6.5 times in high vacuum. (a)Frock of winded samples in thermovacuum environmental conditions; (b) Sample treated with silk fibroin powder; (c) Sample treated without silk fibroin powder"

Tab.1

Sublimation fastness of fabrics controlled by silk fibroin powder"

样品 耐热升华色牢度/级
红色 黄色
未调控样品 1 2
调控样品 5 5
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