Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (05): 115-121.doi: 10.13475/j.fzxb.20200505207

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and properties of cotton fabric modified by silver nanowires

ZHAO Yongfang, QIAN Jianhua(), SUN Liying, PENG Huimin, MEI Min   

  1. College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2020-05-26 Revised:2021-02-01 Online:2021-05-15 Published:2021-05-20
  • Contact: QIAN Jianhua E-mail:qianjianhua@zstu.edu.cn

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Abstract:

In order to increase the added value of cotton fabrics and improve its adsorption to modifying components, sodium periodate was used for oxidation treatment to increase the adhesion of cotton fiber. Silver nanowires (AgNWs) were then prepared by one-step polyol reduction method at 160 ℃ and dispersed in anhydrous ethanol. With a cotton fabric as the substrate, AgNWs was finished on the surface of the fabric by the impregnation drying method. The finished cotton fabric was characterized, and its UV resistance, conductivity and washing resistance were tested. The results show that with the increase of AgNWs concentration, the electrical conductivity of the fabric increases by more than 80%. When the AgNWs concentration is 10 g/L, the UV protection factor (UPF) value reaches 55, and the UV transmittance is reduced to less than 2.5%. The washing resistance of the modified cotton fabric is improved by 20% after the oxidation treatment, and the UPF value of the modified fabric after three times of washing reaches 46.51. The flexible conductive cotton fabric can be applied to flexible electronic textiles and anti ultraviolet products.

Key words: silver nanowire, cotton fabric, oxidation treatment, UV resistance, conductivity, flexible conductive fabric

CLC Number: 

  • TS156

Fig.1

Color changes of solution during preparation of AgNWs"

Fig.2

SEM images of AgNWs"

Fig.3

Distribution of length (a) and diameter (b) of AgNWs"

Fig.4

XRD pattern of AgNWs"

Tab.1

Evaluation standards of UV resistance of samples"

UPF值范围 防护效果 紫外线透过率/% UPF等级
15~24 良好 6.7~4.2 15,20
25~39 很好 4.1~2.6 25,30,35
40~50,50 极佳 ≤2.5 40,45,50,50+

Fig.5

Relationship between AgNWs mass concentration and UPF"

Fig.6

Relationship between AgNWs mass concentration and UVA transmittance (a) or UVB transmittance(b)"

Tab.2

Sheet resistance of modified cotton fabric treated with different mass concentration of silver nanowires"

AgNWs质量浓度/
(g·L-1)		 方块电阻/
(Ω·□-1)		 AgNWs质量浓度/
(g·L-1)		 方块电阻/
(Ω·□-1)
10 87 30 60
20 75 40 15

Fig.7

SEM images of cotton fabric before(a) and after (b)oxidation treatment (×1 000)"

Fig.8

SEM image of AgNWs attached to cotton fabric(×1 000)"

Fig.9

Sheet resistance of fabric obtained by oxidation treatment at different times"

Fig.10

Breaking strength of cotton fabric with different oxidation treatment time"

Tab.3

UV resistance of cotton samples after washing for 3 times"

氧化处理时间/min UPF值 透过率平均值/%
UVA UVB
0 30.46 2.01 1.61
15 42.17 0.97 0.62
30 45.42 0.93 0.60
45 46.51 0.89 0.51

Fig.11

Effect of oxidation treatment time on washing weight loss of modified cotton fabric"

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