Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (12): 125-130.doi: 10.13475/j.fzxb.20211107106

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Rapid determination of quinoline in textiles

YIN Zhe1,2, ZHAO Hailang2(), XU Hong1, MAO Zhiping1, TAN Yujing2   

  1. 1. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    2. Shanghai Institute of Quality Inspection and Technical Research, Shanghai 200040, China
  • Received:2021-11-16 Revised:2022-09-14 Online:2022-12-15 Published:2023-01-06
  • Contact: ZHAO Hailang E-mail:zhaohl@sqi.org.cn

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Abstract:

In order to reduce the extraction time from small amount of organic reagent, a rapid analytical method for the determination of quinoline in textiles by pyrolysis/thermal desorption-gas chromatography-mass spectrometry(Py/TD-GC-MS) was established. This method requires no sample processing, and the quinoline is thermally desorbed directly in the pyrolysis/thermal desorption device before entering the GC-MS for qualitative and quantitative determination. To solve the problem of quinoline volatilization before and during the analysis process, polyvinyl chloride(PVC) was added as the adsorbent of quinoline to improve the accuracy of quinoline standard solution analysis. The thermal desorption temperature was 240 ℃, the thermal desorption time was 6 s, the heating rate was 50 ℃/min and the interface temperature was 300 ℃. The results show that the linear range of the method was 10-1 000 mg/kg, the correlation coefficient was 0.994, the limit of detection was 3.520 mg/kg, the limit of quantification was 11.760 mg/kg, the spiked recoveries were 90.02%-102.07%, and the relative standard deviation was 1.27%-4.53%. All these suggest that this method is suitable for rapid determination of quinoline in textiles.

Key words: textile, quinoline, adsorbent, thermal desorption-gas chromatography-mass spectrometry, rapid determination method, polyvinyl chloride

CLC Number: 

  • O657.63

Fig.1

Effect of waiting time on response intensity of quinoline mass spectrometry"

Fig.2

Effect of PVC solution concentration on response strength of quinoline mass spectrometry"

Fig.3

EGA-MS selective ion diagrams of PVC solution and quinoline standard solution B"

Fig.4

Influence of pyrolysis temperature on response intensity of quinoline mass spectrometry"

Fig.5

Effect of pyrolysis time on response intensity of quinoline mass spectrometry"

Fig.6

Effect of heating rate on response intensity of quinoline mass spectrometry"

Fig.7

Effect of interface temperature on responseintensity of quinoline mass spectrometry"

Fig.8

Linear relation of quinoline standard curve"

Tab.1

Spiked recovery and precision of quinoline"

纺织面料 加标量/(mg·kg-1) 平均加标回收率/% RSD/%
棉 10 91.79 4.22
200 96.77 1.89
1 000 102.07 3.44
羊毛 10 94.51 4.53
200 97.84 3.33
1 000 101.31 1.27
涤纶 10 90.75 4.25
200 94.92 1.54
1 000 98.59 1.71
锦纶 10 90.02 3.93
200 93.13 1.48
1 000 97.49 1.63

Tab.2

Comparison between chemical extraction detection method and Py/TD-GC-MS method"

检测方法 样品处理
有机试剂		 样品处理
时间/min		 喹啉含量/(mg·kg-1)
橙色纱线 黑色纱线
化学提取检测法 15 mL甲醇 30 69.73 60.33
Py/TD-GC-MS法 - 5 91.63 79.04
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