Journal of Textile Research ›› 2024, Vol. 45 ›› Issue (06): 105-112.doi: 10.13475/j.fzxb.20230507301

• Dyeing and Finshing Engineering • Previous Articles     Next Articles

Construction of catalytic system by FeⅢ(tpy)Cl3 complexes-activated periodate and its catalytic degradation mechanism for dyeing wastewater

WU Shouying1,2, HUANG Qichao2, ZHANG Kaifeng2, ZHANG Linping1,2,3, ZHONG Yi1,2,3, XU Hong1,2,3, MAO Zhiping1,2,3()   

  1. 1. College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China
    2. Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    3. National Innovation Center of Advanced Dyeing & Finishing Technology, Shandong Zhongkang Guochuang Research Institute of Advanced Dyeing & Finishing Technology Co., Ltd., Taian, Shandong 271000, China
  • Received:2023-05-30 Revised:2023-11-21 Online:2024-06-15 Published:2024-06-15

RichHTML

8

PDF (PC)

10

Abstract:

Objective The dyeing wastewater poses a threat to the ecological environment. Advanced oxidation processes (AOPs) exhibit excellent oxidation efficiency in wastewater treatment. The solid-state and stability of periodate (PI) make it obtained wide attention. As a result, PI-based AOPs are gradually gaining research and being tried for the treatment of dyeing wastewater. However, current transition metal-based activators for PI often require larger doses to obtain the desired effect, which undoubtedly increases the cost of wastewater treatment. Metal coordination complexes are applied similarly to biological enzymes, with trace and efficient application effects. This study aimed to construct a novel catalytic system by activating PI by FeⅢ(tpy)Cl3 complex to investigate its application prospects in wastewater treatment and to elucidate the catalytic mechanism.

Method The catalytic degradation performance of the FeⅢ(tpy)Cl3/PI system was tested using the dye Acid Red 1 (AR1) as the target pollutant. The effects of catalyst and oxidant dosage, pH, and temperature on the catalytic performance of this system were explored. Meanwhile, the catalytic mechanism of the system was investigated by capture and probe experiments. Moreover, the practical application prospects of the system were evaluated by testing the degradation efficiency of various organics and the resistance to inorganic salt ions.

Results The result showed that the FeⅢ(tpy)Cl3 complexes have excellent activation effects on PI, which could remove 98% of AR1 within 15 min. More importantly, the performance of the FeⅢ(tpy)Cl3/PI system is much higher than that of the previously reported FeⅢ(tpy)Cl3/H2O2 system. Meanwhile, the test results show that the concentration of FeⅢ(tpy)Cl3 and PI has a great influence on the performance of the FeⅢ(tpy)Cl3/PI system. In detail, the degradation of AR1 in the FeⅢ(tpy)Cl3/PI system is following the pseudo-first-order kinetic model, while the rate constant of AR1 degradation increase linearly with the increase of FeⅢ(tpy)Cl3 and PI dose. Moreover, the results show that the catalytic performance of FeⅢ(tpy)Cl3/PI system is almost independent of pH and could achieve efficient degradation of the dye over a wide pH range (3-9). Also, the increase in temperature could increase the catalytic activity of the FeⅢ(tpy)Cl3/PI system and accelerate the degradation of AR1. In addition, the active species in this system were investigated using methanol, benzoquinone, and furfuryl alcohol as hydroxyl radical, superoxide radical, and singlet oxygen trapping agents, respectively, and PMSO as a probe for high-valent metal-oxo. The results of mechanism studies show that FeⅢ(tpy)Cl3/PI system includes superoxide radicals, singlet oxygen, and high-valent metal-oxo, and these active species together promote the degradation of AR1. The removal rates of sulfamethoxazole, 2,4-dichlorophenol, 2,4,6-trichlorophenol, and rhodamine B in the FeⅢ(tpy)Cl3/PI system are 100%, 81%, 89%, and 89%, respectively, indicating that the FeⅢ(tpy)Cl3/PI system is well suited for the removal of most organics. Inorganic salt ions are usually included in the actual organic wastewater. The results show that the catalytic system is not disturbed by common inorganic salt ions for the degradation of organic matter and has good prospects for practical application.

Conclusion FeⅢ(tpy)Cl3 has excellent activation performance for PI, and the removal rate of AR1 is up to 98% within 15 min, which is much higher than the conventional FeⅢ(tpy)Cl3/H2O2 system. Compared with other iron-based catalysts, FeⅢ(tpy)Cl3 complexes are simple to prepare and require only minute doses to achieve efficient degradation of organic matter, which helps to reduce the economic cost of wastewater treatment. In addition, the system shows universality for the degradation of various organics, and the catalytic degradation process do not interfere with the solution pH and common inorganic salt ions, which makes this system excellent prospect for practical wastewater treatment applications. Overall, this study provides a novel PI activator and also provides an efficient method for dyeing wastewater treatment.

Key words: coordination complex, periodate, dyeing wastewater, degradation, catalytic mechanism, wastewater treatment, FeⅢ (tpy) Cl3

CLC Number: 

  • TS190.3

Fig.1

Comparison of degradation of AR1 in different systems"

Fig.2

Effect of FeⅢ(tpy)Cl3 and PI concentration on catalytic performance of FeⅢ(tpy)Cl3/PI system. (a) Effect of FeⅢ(tpy)Cl3 concentration; (b) Pseudo-first-order kinetic fitting on AR1 degradation under different FeⅢ(tpy)Cl3 concentration; (c) Effect of PI concentration; (d) Pseudo-first-order kinetic fitting on AR1 degradation under different PI concentration"

Fig.3

Effect of pH values (a) and temperature (b) on catalytic performance of FeⅢ(tpy)Cl3/PI system"

Fig.4

Investigation result of active species in FeⅢ(tpy)Cl3/PI system. (a)Hydroxyl radicals; (b)Superoxide radicals; (c) Singlet oxygen; (d) High-valent metal"

Fig.5

Application performance of FeⅢ(tpy)Cl3/PI system. (a) Degradation of different organic compounds in FeⅢ(tpy)Cl3/PI system; (b) Effect of inorganic salt ions on degradation of AR1 in FeⅢ(tpy)Cl3/PI system"

[1] AL-TOHAMY Rania, ALI Sameh S, LI Fanghua, et al. A critical review on the treatment of dye-containing wastewater: ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety[J]. Ecotoxicology and Environental Safety, 2022. DOI:10.1016/j.ecoenv.2021.113160.
[2] TKACZYK Angelika, MITROWSKA Kamila, POSYNIAK Andrzej. Synthetic organic dyes as contaminants of the aquatic environment and their implications for ecosystems: a review[J]. Science of the Total Environment, 2020. DOI:10.1016/j.scitotenv.2020.137222.
[3] ZHU Yanping, ZHU Runliang, XI Yunfei, et al. Strategies for enhancing the heterogeneous Fenton catalytic reactivity: a review[J]. Applied Catalysis B: Environmental, 2019. DOI:10.1016/j.apcatb.2019.05.041.
[4] KOHANTORABI Mona, MOUSSAVI Gholamreza, GIANNAKIS Stefanos. A review of the innovations in metal- and carbon-based catalysts explored for heterogeneous peroxymonosulfate (PMS) activation, with focus on radical vs. non-radical degradation pathways of organic contaminants[J]. Chemical Engineering Journal, 2021. DOI:10.1016/j.cej.2020.127957.
[5] WANG Jianlong, WANG Shizong. Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contami-nants[J]. Chemical Engineering Journal, 2018. DOI:10.1016/j.cej.2017.11.059.
[6] ULUCAN-ALTUNTAS Kubra, GUVENC Senem Yazici, CAN-GUVEN Emine, et al. Degradation of oxytetracycline in aqueous solution by heat-activated peroxydisulfate and peroxymonosulfate oxidation[J]. Environmental Science and Pollution Research, 2022, 29(6): 9110-9123.
[7] YANG Lie, HE Liuyang, MA Yongfei, et al. Periodate-based oxidation focusing on activation, multivariate-controlled performance and mechanisms for water treatment and purification[J]. Separation and Purification Technology, 2022. DOI:10.1016/j.seppur.2022.120746.
[8] LING Chen, WU Shuai, HAN Jiangang, et al. Sulfide-modified zero-valent iron activated periodate for sulfadiazine removal: performance and dominant routine of reactive species production[J]. Water Research, 2022. DOI:10.1016/j.watres.2022.118676.
[9] YU Yanghai, DONG Hongyu, LIAN Lushi, et al. Selective and rapid degradation of organic contaminants by Mn(V) generated in the Mn(II)-nitrilotriacetic acid/periodate process[J]. Chemical Engineering Journal, 2022. DOI:10.1016/j.cej.2022.136387.
[10] BOKARE Alok D, CHOI Wonyong. Singlet-oxygen generation in alkaline periodate solution[J]. Environmental Science & Technology, 2015, 49(24): 14392-14400.
[11] CHOI Yejin, YOON Ho-Il, LEE Changha, et al. Activation of periodate by freezing for the degradation of aqueous organic pollutants[J]. Environmental Science & Technology, 2018, 52(9): 5378-5385.
[12] ZHANG Xi, KAMALI Mohammadreza, ULENERS Timon, et al. UV/TiO2/periodate system for the degradation of organic pollutants-kinetics, mechanisms and toxicity study[J]. Chemical Engineering Journal, 2022. DOI:10.1016/j.cej.2022.137680.
[13] ZHANG Xi, YU Xiaobin, YU Xinyue, et al. Efficiency and mechanism of 2,4-dichlorophenol degradation by the $\mathrm{UV/IO}_4^-$ process[J]. Science of the Total Environment, 2021. DOI:10.1016/j.scitotenv.2021.146781.
[14] DU Jiangkun, XIAO Guangfeng, XI Yanxing, et al. Periodate activation with manganese oxides for sulfanilamide degradation[J]. Water Research, 2020. DOI:10.1016/j.watres.2019.115278.
[15] LEE Hongshin, YOO Ha-Young, CHOI Jihyun, et al. Oxidizing capacity of periodate activated with iron-based bimetallic nanoparticles[J]. Environmental Science & Technology, 2014, 48(14): 8086-8093.
[16] ZHANG Ying, ZHOU Minghua. A critical review of the application of chelating agents to enable Fenton and Fenton-like reactions at high pH values[J]. Journal of Hazardous Materials, 2019, 362: 436-450.
doi: S0304-3894(18)30830-6 pmid: 30261437
[17] YE Yuxin, WEN Cheng, WANG Jiawei, et al. Valence-dependent catalytic activities of iron terpyridine complexes for pollutant degradation[J]. Chemical Communication, 2020, 56(41): 5476-5479.
[18] IGARASHI Mami, ZHU Qianqian, SASAKI Masahide, et al. Catalytic oxidation of 2,4,6-tribromophenol using iron(Ⅲ) complexes with imidazole, pyrazole, triazine and pyridine ligands[J]. Journal of Molecular Catalysis A: Chemical, 2016, 413: 100-106.
[19] DU Jiangkun, TANG Shigang, FAHEEM, et al. Insights into periodate oxidation of bisphenol A mediated by manga-nese[J]. Chemical Engineering Journal, 2019, 369: 1034-1039.
doi: 10.1016/j.cej.2019.03.158
[20] ZONG Yang, ZHANG Hua, SHAO Yufei, et al. Surface-mediated periodate activation by nano zero-valent iron for the enhanced abatement of organic contaminants[J]. Journal of Hazardous Materials, 2022. DOI:10.1016/j.jhazmat.2021.126991.
[21] WANG Lingli, LAN Xu, PENG Wenya, et al. Uncertainty and misinterpretation over identification, quantification and transformation of reactive species generated in catalytic oxidation processes: a review[J]. Journal of Hazardous Materials, 2021. DOI:10.1016/j.jhazmat.2020.124436.
[22] FAN Jinhong, QIN Hehe, JIANG Simin. Mn-doped g-C3N4 composite to activate peroxymonosulfate for acetaminophen degradation: the role of superoxide anion and singlet oxygen[J]. Chemical Engineering Journal, 2019, 359: 723-732.
doi: 10.1016/j.cej.2018.11.165
[23] DONG Yudan, ZHANG Liangqing, ZHOU Peng, et al. Natural cellulose supported carbon nanotubes and Fe3O4NPs as the efficient peroxydisulfate activator for the removal of bisphenol A: an enhanced non-radical oxidation process[J]. Journal of Hazardous Materials, 2022. DOI:10.1016/j.jhazmat.2021.127054.
[24] YU Yuqing, TAN Peng, HUANG Xinjue, et al. Homogeneous activation of peroxymonosulfate using a low-dosage cross-bridged cyclam manganese (II) complex for organic pollutant degradation via a nonradical pathway[J]. Journal of Hazardous Materials, 2020. DOI:10.1016/j.jhazmat.2020.122560.
[25] GUO Dongli, YAO Yuan, YOU Shijie, et al. Ultrafast degradation of micropollutants in water via electro-periodate activation catalyzed by nanoconfined Fe2O3[J]. Applied Catalysis B: Environmental, 2022. DOI:10.1016/japcatb2022.121289.
[1] YANG Liang, KONG Hanhan, LI Weilin, QI Xiaofen, ZHANG Tianyun, WANG Xuemei, LI Wenquan. Preparation of zeolitic imidazolate framework-8 and its adsorption performance on Congo Red [J]. Journal of Textile Research, 2024, 45(07): 140-149.
[2] ZHANG Shiyu, YAO Yiting, DONG Chenshan, ZHANG Ruquan, YANG Hongjun, GU Shaojin, HUANG Jingjing, DU Jiehao. Metal-organic frameworks/polypropylene fiber-based composite for rapid degradation of chemical warfare agent simulants [J]. Journal of Textile Research, 2024, 45(06): 134-141.
[3] ZHENG Kang, GONG Wenli, BAO Jie, LIU Lin. Preparation and dynamic adsorption properties of amphoteric cellulose porous hydrogel spheres [J]. Journal of Textile Research, 2024, 45(05): 102-112.
[4] LU Yaoyao, YE Juntao, RUAN Chengxiang, LOU Jin. Preparation and photocatalytic performance of titanium dioxide/porous carbon nanofibers composite material [J]. Journal of Textile Research, 2024, 45(04): 67-75.
[5] ZHU Weiwei, SHU Wei, GU Wenjuan. Effects of loading different polar drugs on structure and properties of viscose fabrics [J]. Journal of Textile Research, 2024, 45(04): 136-141.
[6] ZHANG Yongfang, GUO Hong, SHI Sheng, YAN Zhifeng, HOU Wensheng. Degradation of polyester/cotton blended fabrics in hydrothermal system [J]. Journal of Textile Research, 2024, 45(04): 160-168.
[7] LI Fang, ZHANG Yili, WANG Man, MENG Xiangzhou, SHEN Chensi. Acute toxic effects of antimony contaminants on green algae and cyanobacteria [J]. Journal of Textile Research, 2024, 45(04): 169-179.
[8] CHEN Rongxuan, SUN Hui, YU Bin. Preparation and photocatalytic properties of N-TiO2/ polypropylene melt-blown nonwovens [J]. Journal of Textile Research, 2024, 45(03): 137-147.
[9] YANG Zhichao, LIU Shuqiang, WU Gaihong, JIA Lu, ZHANG Man, LI Fu, LI Huimin. Research progress in absorbable surgical sutures [J]. Journal of Textile Research, 2024, 45(01): 230-239.
[10] WANG Peng, SHEN Jiakun, LU Yinhui, SHENG Hongmei, WANG Zongqian, LI Changlong. Preparation and photocatalytic properties of g-C3N4/MXene/Ag3PO4/polyacrylonitrile composite nanofiber membranes [J]. Journal of Textile Research, 2023, 44(12): 10-16.
[11] ZHANG Yongfang, FEI Pengfei, YAN Zhifeng, WANG Shuhua, GUO Hong. Research progress of hydrothermal degradation of waste cellulose textiles [J]. Journal of Textile Research, 2023, 44(12): 216-224.
[12] HUANG Biao, ZHENG Li'na, QIN Yan, CHENG Yujun, LI Chengcai, ZHU Hailin, LIU Guojin. Preparation of porous TiO2 particles and their adsorption for ionic dyes [J]. Journal of Textile Research, 2023, 44(11): 167-175.
[13] LI Jingzi, LOU Mengmeng, HUANG Shiyan, LI Fang. Recycling treatment of dyeing wastewater by metal organic framework/graphene composite membrane based on photothermal utilization [J]. Journal of Textile Research, 2023, 44(09): 116-123.
[14] LI Hongying, XU Yi, YANG Fan, REN Ruipeng, ZHOU Quan, WU Lijie, LÜ Yongkang. Preparation of three-dimensional ping-pong chrysanthemum-like CdS/BiOBr composite and its application on photocatalytic degradation of Rhodamine B [J]. Journal of Textile Research, 2023, 44(09): 124-133.
[15] LIU Qixia, ZHANG Tianhao, JI Tao, GE Jianlong, SHAN Haoru. Preparation of zirconium-based organic framework material/activated carbon fiber composites and their degradation properties [J]. Journal of Textile Research, 2023, 44(09): 134-143.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd