JOURNAL OF TEXTILE RESEARCH ›› 2017, Vol. 38 ›› Issue (06): 157-162.doi: 10.13475/j.fzxb.20170202906

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Antibacterial modification of polyester nanofibrous membranes by electron beam irradiation technique

  

  • Received:2017-02-22 Revised:2017-03-02 Online:2017-06-15 Published:2017-06-16

Abstract:

In order to perpare an efficient antibacterial biomaterials, an innovative N-halamine monomer contatining quaternary ammonium group was synthesized and grafted onto the poly(3-hydroxybutyrate-co-4-hydroxybutyrate) (P(3HB-4HB)) and poly(butylene adipate-co-terephthalate) (PBAT) nanofiberus membranes that were generated by electrospinning, and finally the grafted nanofibrous membranes were chloridized with sodium hypochlorite to obtain antibacterial nanofibrous membranes. The influence of the composition of P(3HB-4HB) and PBAT on surface morphologies of membranes and the influence of the irradiation dose and the concentration of monomer on the oxidative chlorine were studied. The UV light stability and the storage stability of the antibacterial nanofibrous membranes were also investigated. The results show that the P(3HB-4HB) / PBAT antibacterial nanofibrous membranes can kill both S. aureus and E. coli within 5 min, showing powerful antibacterial performance, realize the covalent bonding effect between N-halamine antibacterials and chemical inert materials, and have great potential in fields of food packaging and biomedicines. 

Key words: biodegradable, edectron beam, N-halamine, quaternary ammonium salt, antibacteria

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